Conductive film and method for producing conductive film
A conductive film, conductive layer technology, applied in chemical instruments and methods, cable/conductor manufacturing, conductive materials dispersed in non-conductive inorganic materials, etc. Problems such as the amount of conductive materials used, to achieve the effect of excellent resistance value stability and excellent cost
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Embodiment 1
[0086]
[0087] As the binder resin, using -SO 3 Na-based polyester resin aqueous dispersion. This polyester aqueous dispersion was prepared so that the solid content concentration might be 5 mass % using PES resin A-647GEX by Takamatsu Oil Co., Ltd. Hereinafter, this polyester aqueous dispersion is referred to as a PES resin aqueous solution.
[0088] Methanol (MeOH) and 2-propanol (IPA) were prepared in order to mix with water as the dispersion medium of the above-mentioned silver nanowire dispersion liquid to prepare a mixed dispersion medium of water+alcohol.
[0089] The above-mentioned silver nanowire dispersion liquid using water as a dispersion medium and a 5 mass % aqueous solution of the above-mentioned PES resin were put into a container with a lid, various solvents were added, and the lid was closed, and then mixed by a mixing rotor. In this case, the mixed composition of the solvent was set to a mass ratio of water:MeOH:IPA=72:18:10. In addition, the mixing a...
Embodiment 2
[0109] The difference from Example 1 is that silver nanowires are applied so that the wet film thickness is about 10 μm. Except this point, it carried out similarly to Example 1. The results are shown in Table 1. It was confirmed that the occupied area of silver nanowires (AgNW) in the obtained conductive film was 3.75%, and the surface resistance value was 1.8×10 3 Ω / □, the variation in surface resistance value is less than 7%, and the conductive film has uniform conductivity. In addition, it was confirmed that the total light transmittance was higher than 91.2%, the haze was less than 0.48%, and the transparency was extremely excellent.
Embodiment 3
[0111] The point of difference from Example 1 is the point of using the silver nanowire ink as a water solvent. Except this point, it carried out similarly to Example 1. The results are shown in Table 1. Compared with Example 1 in which the mixed solvent of water and alcohol was used, the deviation of the surface resistance value was slightly larger than 15%, but it was such that there was no problem in use.
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