Compound of general formula and application thereof

A compound of general formula and selected technology, applied in the field of organic electroluminescence devices, can solve the problems of unbalanced horizontal and vertical mobility, poor pixel crosstalk, etc.

Pending Publication Date: 2019-09-10
BEIJING ETERNAL MATERIAL TECH +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] However, when this material is applied in the production line, due to its uneven horizontal and vertica

Method used

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  • Compound of general formula and application thereof
  • Compound of general formula and application thereof
  • Compound of general formula and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Example Embodiment

[0059] Example 1

[0060] Synthesis of compound 1

[0061]

[0062] Synthesis of Intermediate 1-1;

[0063] Under the protection of nitrogen, add the raw material carbazole (30g, 180mmol, 1eq), 1-(4-bromophenyl)-4-chlorobiphenyl into a 500mL four-neck flask equipped with mechanical stirring and a 500mL four-neck flask with condenser. (61.4g, 180mmol, 1eq), tris(dibenzylidene indeneacetone) dipalladium (5.0g, 5.4mmol, 3%eq), tri-tert-butylphosphine tetrafluoroborate (3.1g, 10.8mmol, 6 %Eq), sodium tert-butoxide (26g, 270mmol, 1.5eq), 300mL of toluene at 80°C for 24h. After cooling to room temperature, 250 mL of water was added directly, the aqueous phase was extracted three times with 200 mL of dichloromethane, and the organic phases were combined and concentrated to obtain a crude product. The crude product was boiled and washed in petroleum ether and filtered to obtain 27 g of white powder.

[0064] Synthesis of compound 1;

[0065] Under nitrogen protection, add 1-1 (27g, 63mmol, ...

Example Embodiment

[0070] Implementation

[0071] The organic light emitting diode includes a first electrode and a second electrode on a substrate, and an organic material located between the electrodes. The first electrode and the second electrode include a hole transport layer, a light emitting layer, and an electron transport layer.

[0072] The substrate uses the substrate used in organic light-emitting displays, such as glass, polymer materials, and glass and polymer materials with TFT components.

[0073] The anode material can be transparent conductive materials such as indium tin oxide (ITO), indium zinc oxide (IZO), tin dioxide (SnO2), zinc oxide (ZnO), or metal materials such as silver and its alloys, aluminum and its alloys , It can also be organic conductive materials such as PEDOT, and the multilayer structure of the above materials.

[0074] The cathode is magnesium-silver mixture, LiF / Al, ITO and other metals, metal mixtures, oxides

[0075] The device may also include hole injection laye...

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Abstract

The invention discloses a general formula compound with the following structure, wherein R1 is selected from C6-C30 aryl or fused ring aryl, C3-C30 heterocyclic aryl or fused ring heteroaryl; R2 and R3 are independently selected from hydrogen, C1-C12 alkyl, C1-C8 alkoxy, C6-C30 aryl or fused ring aryl, C3-C30 heterocyclic aryl or fused ring heteroaryl; M and n are each independently selected fromintegers of 1 to 4; L is selected from single bonds, or C1-C12 alkyl, C1-C8 alkoxy, C5-C30 arylene, C3-C30 heterocyclic arylene; Ar1 and Ar2 are independently selected from C6-C30 aryl or fused ring aryl respectively; Ar3 and Ar4 are independently selected from C6-C30 aryl or fused ring aryl, C3-C30 heterocyclic aryl or fused ring heteroaryl respectively. The invention also protects the organic electroluminescent device adopting the general formula compound. When the compound is used as a hole transport material in an OLED light emitting layer, the compound exhibits excellent device performance and stability.

Description

technical field [0001] The invention relates to the field of organic electroluminescent materials, in particular to a novel general formula compound and an organic electroluminescent device using the general formula compound. Background technique [0002] Organic light-emitting diodes (Organic Light-Emitting Diodes, OLEDs) are also known as organic electro-laser displays and organic light-emitting semiconductors. It was discovered in the laboratory by Chinese-American professor Ching W.Tang in 1979. OLED display technology has the advantages of self-illumination, wide viewing angle, high contrast, low power consumption, and fast response speed. However, as a high-end display, the price will be more expensive than LCD TVs. Among them, OLED itself has the inherent characteristics of using organic thin film and applying voltage to the device composed of it to emit light. Therefore, the development of suitable organic thin film materials has always been the research focus of t...

Claims

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Application Information

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IPC IPC(8): C07D209/86C07D409/12C07D409/14C07D209/56C07D209/88H01L51/50H01L51/54
CPCC07D209/86C07D409/12C07D409/14C07D209/56C07D209/88H10K85/626H10K85/615H10K85/6576H10K85/6572H10K50/11
Inventor 张松杜倩任雪艳
Owner BEIJING ETERNAL MATERIAL TECH
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