Chiral silicon dioxide fiber-reinforced foamed polypropylene composite material

A foamed polypropylene and silicon dioxide technology, applied in the field of polypropylene materials, can solve the problems that the reinforcement effect needs to be further improved and the mechanical properties are not high, so as to achieve good reinforcement effects, improve mechanical properties, and improve mechanical properties.

Active Publication Date: 2019-10-08
SUZHOU RUNJIA ENGINEER PLASTIC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the mechanical properties of injection-molded foamed polypropylene products are often not high, and reinforcement is required; fiber (such as glass fiber, carbon fiber, silica fiber) reinforcement materials are usually added to improve its mechanical properties, but the reinforcement effect remains to be seen. Further improve

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0015] The invention provides a chiral silica fiber reinforced foamed polypropylene composite material, which is composed of: polypropylene resin 65wt%, talcum powder 12wt%, chiral silica fiber 10wt%, surfactant solution 8wt% , microcellular foaming agent 2.5wt%, xylitol microcapsules 1.5wt%, primary antioxidant 0.5wt%, secondary antioxidant 0.5wt%.

[0016] Wherein: the flow rate of the polypropylene resin under a load of 2.16kg is 45-60g / min at a temperature of 230°C.

[0017] Chiral silica fibers have a length of 3.0-8.0µm and a diameter of 50-80nm; the surfactant solution is an aqueous solution of linear alkylbenzene sulfonate with a concentration of 70-80wt%; the chiral silica fibers are active on the surface Under the action of the aqueous solution of the agent, through the hydrogen bond between molecules, chiral induction occurs, which reduces the orientation of polypropylene molecular segments and arranges them regularly, thereby improving the mechanical properties of ...

Embodiment 2

[0023] The invention provides a chiral silica fiber reinforced foamed polypropylene composite material, which is composed of: polypropylene resin 70wt%, talcum powder 9wt%, chiral silica fiber 8wt%, surfactant solution 5wt% , microporous foaming agent 4wt%, meso-erythritol microcapsules 3wt%, primary antioxidant 0.75wt%, secondary antioxidant 0.25wt%.

[0024] Wherein: meso-erythritol is a medium-temperature phase-change material with a phase transition temperature of 118-124°C; the properties of the other materials used are the same as in Example 1; the preparation method of the material is the same as in Example 1.

Embodiment 3

[0026] The invention provides a chiral silica fiber reinforced foamed polypropylene composite material, which is composed of: 60wt% polypropylene resin, 16wt% talcum powder, 15wt% chiral silica fiber, and 3wt% surfactant solution , microcellular foaming agent 2wt%, xylitol microcapsules 2wt%, primary antioxidant 1wt%, auxiliary antioxidant 1wt%.

[0027] Wherein: the properties of the materials used and the preparation method of the materials are the same as in Example 1.

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Abstract

The invention relates to a chiral silicon dioxide fiber-reinforced foamed polypropylene composite material which comprises a polypropylene resin, talcum powder, a chiral silicon dioxide fiber, a surfactant solution, a micro-pore foaming agent and a phase-change material microcapsule and an aid, wherein the surfactant solution is a linear sodium alkyl benzene sulfonate solution. Due to adoption ofthe chiral silicon dioxide fiber, the mechanical properties of the material can be improved; the chiral silicon dioxide fiber has chiral induction under the action of hydrogen bonds among molecules, orientation of polypropylene molecular chain fragments can be reduced, the polypropylene molecular chain fragments can be regularly arranged, and thus the mechanical properties of a polypropylene injection molding finished product can be improved; meanwhile, due to a chiral spiral structure of the chiral silicon dioxide fiber, and through chiral spiral induction on polypropylene, winding of molecular chains can be intensified, and the mechanical properties of the polypropylene injection molding finished product can be further improved; and due to adoption of the chiral silicon dioxide fiber, mechanical properties of a polypropylene material and an injection molding part thereof can be effectively improved.

Description

technical field [0001] The invention relates to the field of polypropylene materials, in particular to a chiral silica fiber reinforced foamed polypropylene composite material. Background technique [0002] In recent years, polypropylene foam injection molding technology has attracted more and more attention. This technology refers to the use of polypropylene material as the matrix, through the injection molding process, under the action of gas internal pressure, the middle layer of the product is densely covered with closed micropores with a size ranging from ten to tens of microns, and there are dense skin structures on both sides; thus To achieve the purpose of material saving and weight reduction. This technology can be divided into physical method and chemical method; the chemical method refers to adding a certain amount of foaming agent to polypropylene. After the injection molding is completed, the part material expands under the action of the foaming agent to form a...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/12C08K13/06C08K9/10C08K3/34C08K7/10C08J9/08
CPCC08J9/08C08J9/0066C08J9/0076C08J2323/12C08K13/06C08K9/10C08K3/34C08K7/10C08K2201/011C08J2203/02
Inventor 汪理文李庆贵牛国增郑帅余君沈安平翁永华
Owner SUZHOU RUNJIA ENGINEER PLASTIC
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