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Seawater-based fracturing fluid cross-linking agent, fracturing fluid and preparation method thereof

A technology of cross-linking agent and seawater, applied in the field of oil field fracturing fluid, can solve the problems of poor performance of cross-linking agent, high residue content and high viscosity, achieve optimal pH value buffering capacity, good temperature resistance performance, and small reservoir damage Effect

Inactive Publication Date: 2019-10-25
DAGANG OIL FIELD GRP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The existing seawater-based modified guar gum fracturing fluid crosslinking agent has poor performance, and it is necessary to (1) increase the amount of thickener (more than 0.65%); (2) add a large amount of temperature-resistant enhancer and oxygen scavenger; (3) ) Add a pH regulator containing hydroxide ions or carbonate ions to improve the high temperature resistance of the fracturing fluid
This will inevitably cause the viscosity in the fracturing fluid base tank to be too high, and it will be difficult to pump during construction, and it will not be possible to achieve large displacement and continuous mixing construction; Calcium and magnesium ions form precipitates, which seriously pollute reservoir matrix permeability and fracture support zones; there are many types of chemical additives, which are not conducive to marine environmental protection

Method used

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  • Seawater-based fracturing fluid cross-linking agent, fracturing fluid and preparation method thereof

Examples

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Effect test

Embodiment 1

[0016] Example 1: The preparation method of the seawater-based fracturing fluid crosslinking agent, at room temperature, under stirring conditions, add 60kg of clean water, 35kg of triethanolamine borate, and 15kg of glycerin to the reaction kettle to fully mix; add 8kg to the mixture Boric acid, stir to make it fully react and dissolve to form a uniform solution to make a crosslinking agent. The triethanolamine borate is industrial grade. The boric acid has a content of 99%, industrial grade. The glycerin has a content of 99%, industrial grade. Same below.

Embodiment 2

[0017] Example 2: The preparation method of the seawater-based fracturing fluid crosslinking agent, at room temperature, under stirring conditions, add 40kg of clean water, 25kg of triethanolamine borate, and 10kg of glycerin to the reaction kettle and mix thoroughly in proportion; in the mixed solution Add 5kg of boric acid, stir to make it fully react and dissolve to form a uniform solution, and make a crosslinking agent.

Embodiment 3

[0018] Example 3: The preparation method of the seawater-based fracturing fluid crosslinking agent, at room temperature, under stirring conditions, add 50kg of clean water, 30kg of triethanolamine borate, and 15kg of glycerin to the reaction kettle and mix thoroughly in proportion; in the mixed solution Add 8kg of boric acid and stir to make it fully react and dissolve to form a uniform solution to make a crosslinking agent.

[0019] Embodiment 3 is the best embodiment, and it will be explained by taking Embodiment 3 as an example.

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Abstract

The invention belongs to the field of oil field fracturing fluid, in particular to a seawater-based fracturing fluid cross-linking agent and a fracturing fluid and a preparation method thereof. The seawater-based fracturing fluid cross-linking agent comprises the following raw materials in parts by weight: 40-60 parts of water, 25-35 parts of alcoholamine borate, 10-15 parts of polyol, and 5-8 parts of boric acid. The seawater-based fracturing fluid cross-linking agent solves the problems of high dosage of modified guar gum (0.65%), high residue content, easy precipitation with calcium and magnesium ions, stratum pollution, discontinuous mixing and poor economic benefit existing in the prior art. The seawater-based fracturing fluid formed by the invention has the advantages of low use concentration of modified guar gum (0.4%-0.5%), no need to add additives such as temperature stabilizer and deoxidizer, good temperature resistance at 140 DEG C and easy to break gum; no alkaline pH regulator is needed, no calcium and magnesium ions are precipitated, the fracturing fluid has the characteristics of little damage to the reservoir and high cleanliness. Direct continuous mixing can be realized.

Description

Technical field [0001] The invention belongs to the field of oilfield fracturing fluids, and specifically relates to a seawater-based fracturing fluid crosslinking agent, fracturing fluid and a preparation method. Background technique [0002] Seawater-based fracturing fluid is one of the main technical means to realize the efficient exploration and development of marine low-permeability oil and gas reservoirs and improve the effect of fracturing reformation. The existing seawater-based modified guar gum fracturing fluid crosslinking agent has poor performance, and it is necessary to (1) increase the amount of thickener (over 0.65%); (2) add a large amount of temperature-resistant enhancers and oxygen scavengers; (3) ) Adding a pH regulator containing hydroxide ions or carbonate ions to improve the high temperature resistance of the fracturing fluid. This will inevitably cause too high viscosity in the fracturing fluid base tank, difficult to pump during construction, and unable...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K8/68
CPCC09K8/602C09K8/605C09K8/685C09K8/887C09K8/90
Inventor 陈紫薇付大其赵玉东李晓娟闫阳构晓婷赵冬华何光晶
Owner DAGANG OIL FIELD GRP
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