A low-cost rh decarburization and dephosphorization method

A low-cost, decarburization technology, applied in the metallurgical field, can solve the problems of large cost input, high equipment requirements, and high production costs, and achieve the effects of increasing slag consumption, high equipment requirements, and high production costs.

Active Publication Date: 2021-07-27
ZENITH STEEL GROUP CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Pre-dephosphorization in the ladle or torpedo car, the temperature drop of molten iron is large, and oxygen blowing is required to supplement the temperature drop, and the volume of the ladle or torpedo car is small, the reaction is slow, and the dephosphorization efficiency is low; dephosphorization by double slag method increases converter smelting Cycle time and slag consumption reduce converter operation rate; adding dephosphorization agent and blowing oxygen dephosphorization in RH furnace vacuum chamber not only requires high equipment but also high production cost
Patent CN200810012366.5 Process method for producing ultra-low phosphorus steel by refining and dephosphorizing molten steel outside the furnace. Deoxidation is not performed when tapping the converter, and dephosphorization is performed by adding a dephosphorization flux. Deep dephosphorization is performed by adding composite spheres in RH, and the dephosphorization is carried out after dephosphorization. For slag removal, since compound spheres need to be added for dephosphorization during RH treatment, the requirements for equipment are relatively high, and the cost investment is large; patent CN200810035042.3 is a multi-functional vacuum refining process that not only needs to add a specific dephosphorization agent during RH dephosphorization Dephosphorization, and desulfurization and deoxidation operation after dephosphorization, if the dephosphorization slag is not removed, it is easy to cause the phosphorus in the slag to return to the molten steel, so it is difficult to achieve a better dephosphorization effect

Method used

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  • A low-cost rh decarburization and dephosphorization method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] (1) Converter tapping C: 0.04%, P: 0.011%, tapping temperature 1635°C, adding 800kg lime + 400kg slagging agent from tapping 1 / 2 to the end of tapping, without adding alloy and deoxidizer.

[0027] (2) After tapping with argon flow rate of 800Nl / min and stirring for 3 minutes, the slag on the surface of the molten steel is melted and has good fluidity.

[0028] (3) The molten steel is hoisted to the RH treatment position, the temperature is 1591°C, the oxygen is determined to be 638ppm with an oxygen meter, the ladle is lifted to the RH treatment tank, the vacuum pump system is turned on for vacuum treatment, the molten steel in the vacuum chamber starts to circulate, and the vacuum degree is 12KPa at the beginning , the tail gas is all CO 2 , oxygen in molten steel starts to react with carbon and phosphorus, and with the CO in the tail gas 2 decrease and CO gradually increased, indicating that the carbon-oxygen reaction rate gradually increased, and at the same time t...

Embodiment 2

[0032] Converter tapping C: 0.05%, P: 0.010%, tapping temperature 1640°C, argon gas flow rate 700Nl / min and stirring for 4min after tapping, molten steel was hoisted to the RH treatment position, temperature 1598°C, and oxygen was determined by an oxygen meter 562ppm, RH cycle treatment for 7min, CO tail gas concentration in the vacuum chamber 0.3%, and maintain a stable state, temperature measurement is 1549°C, oxygen meter is 335ppm, molten steel sampling: C is 0.003%, P is 0.004%. null. All the other operations are the same as in Example 1.

Embodiment 3

[0034] Converter tapping C: 0.03%, P: 0.012%, tapping temperature 1646°C, argon gas flow rate 900Nl / min and stirring for 2min after tapping, molten steel was hoisted to RH treatment position, temperature 1593°C, oxygen was determined by oxygen meter 657ppm, RH cycle treatment for 6min, CO tail gas concentration in the vacuum chamber was 0.4%, and maintained a stable state, the temperature measurement was 1561°C, the oxygen was 396ppm by the oxygen meter, molten steel sampling: C was 0.005%, P was 0.007%, and the broken null. All the other operations are the same as in Example 1.

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Abstract

The invention discloses a low-cost RH decarburization and dephosphorization method. The specific steps are as follows: during the tapping process of the converter, no alloy or deoxidizer is added, only slag is added; the molten steel is hoisted to the RH vacuum treatment position, and the ladle is lifted to the RH treatment tank; turn on the vacuum pump for vacuum treatment; the concentration of CO tail gas in the vacuum chamber is less than 0.5%, and carry out emptying; the molten steel is hoisted to the slag removal position to remove dephosphorization slag; the molten steel is hoisted to the LF furnace for slagging, heating, and adjustment Element. Compared with the prior art, the beneficial effect of the present invention is: under the premise that RH does not need to add slag material and oxygen blowing, the smelting C is lower than 0.01 by using the oxygen in molten steel, the slag material added in tapping and the temperature condition of molten steel to RH. %, P less than 0.008% ultra-low carbon, low phosphorus steel.

Description

technical field [0001] The invention belongs to the field of metallurgy and relates to a low-cost RH decarburization and dephosphorization method. Background technique [0002] As the main raw material for the production of deep drawing and ultra-deep drawing cold-rolled substrates, ultra-low carbon steel is widely used in industries such as automobiles, home appliances, and precision welded pipes. Phosphorus in steel significantly reduces the toughness of steel, improves the cold brittleness of steel, and is easy to segregate, affecting the local structure uniformity of steel, thereby affecting the mechanical properties of steel. At present, the production of low-phosphorus steel generally adopts pre-dephosphorization in ladle or torpedo car, double-slag dephosphorization in converter, or adding dephosphorization agent and oxygen injection in RH furnace vacuum chamber for dephosphorization. Pre-dephosphorization in the ladle or torpedo car, the temperature drop of molten i...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C21C7/10C21C7/068C21C7/064
CPCC21C7/064C21C7/068C21C7/10
Inventor 屠兴圹周淼苏振伟张盛华
Owner ZENITH STEEL GROUP CORP
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