A kind of cast CPE heat-sealing easy-tear cover film and preparation method thereof
An easy-tear cap and casting technology, which is applied in the direction of chemical instruments and methods, synthetic resin layered products, layered products, etc. NY/MPET material film compounding and other issues, to achieve the effect of improving bonding strength and easy tearing performance, improving easy peeling and tearing performance, bending strength and impact strength
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preparation example 1
[0050] Preparation Example 1: (1) Add 1.4 kg of isophorone diisocyanate to 1 kg of polyether 210, and pass through nitrogen, react at 75 ° C for 2 hours, add 0.3 kg of dimethylol propionic acid and 0.1 kg of dilauric acid diisocyanate Butyl tin, add 1.8kg 1,4-butanediol, 0.8kg trimethylolpropane and 3kg acetone, stir for 1h, cool down to 70°C, add 2kg polydimethylsiloxane and 1.8kg triethylamine, stir for 15min , add 5kg of deionized water, disperse for 30min, and distill under reduced pressure to remove acetone to obtain PU emulsion;
[0051] (1) Mix 1kg PU emulsion, 0.3kg emulsifier, and 3kg water, add 0.5kg initiator AIBN BA solution, stir, polymerize at 80°C for 3h, heat up to 90°C, react for 1h, cool down to room temperature, and discharge , to prepare modified water-based polyurethane.
preparation example 2
[0052] Preparation Example 2: (1) Add 1.9kg of isophorone diisocyanate to 2kg of polyether 210, and pass through nitrogen, react at 78°C for 1.8h, add 0.5kg of dimethylol propionic acid and 0.3kg of dilauric acid Dibutyltin, add 2.2kg 1,4-butanediol, 0.9kg trimethylolpropane and 4kg acetone, stir for 1.3h, cool down to 70°C, add 2.5kg polydimethylsiloxane and 2.1kg triethylamine , stirred for 18 minutes, added 8kg of deionized water, dispersed for 30 minutes, decompressed distillation to remove acetone, and obtained PU emulsion;
[0053] (1) Mix 2kg PU emulsion, 0.4kg emulsifier, and 4kg water, add 0.6kg initiator AIBN BA solution, stir, polymerize at 83°C for 2.8h, heat up to 90°C, react for 1.3h, and cool down to room temperature, Discharging to obtain modified water-based polyurethane.
preparation example 3
[0054] Preparation Example 3: (1) Add 2.4kg of isophorone diisocyanate to 3kg of polyether 210, and pass through nitrogen, react at 80°C for 1.5h, add 0.8kg of dimethylol propionic acid and 0.5kg of dilauric acid Dibutyltin, add 2.6kg 1,4-butanediol, 1.1kg trimethylolpropane and 5kg acetone, stir for 1.5h, cool down to 70°C, add 3kg polydimethylsiloxane and 2.4kg triethylamine, Stir for 20 minutes, add 10kg of deionized water, disperse for 30 minutes, and distill under reduced pressure to remove acetone to obtain PU emulsion;
[0055] (1) Mix 3kg PU emulsion, 0.5kg emulsifier, and 5kg water, add 0.7kg initiator AIBN BA solution, stir, polymerize at 85°C for 2.5h, heat up to 90°C, react for 1.5h, and cool down to room temperature, Discharging to obtain modified water-based polyurethane.
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