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High-thermal-conductivity polyetheretherketone electromagnetic shielding composite material and preparation method thereof

A polyether ether ketone and electromagnetic shielding technology, which is applied in shielding materials, magnetic field/electric field shielding, electrical components, etc., can solve the problems of difficult dispersion of filler agglomeration, small increase in thermal conductivity, and excessive filling volume, etc.

Active Publication Date: 2020-01-10
JILIN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] In order to solve the above disadvantages and deficiencies, the present invention provides a high thermal conductivity polyetheretherketone electromagnetic shielding composite material and its preparation method. Specifically, the high thermal conductivity polyetheretherketone composite material is prepared by using a special structure of thermal conductive filler to construct a thermal network, which solves the problem of Problems such as filler agglomeration is not easy to disperse, filling amount is too large, thermal conductivity is small, etc.

Method used

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  • High-thermal-conductivity polyetheretherketone electromagnetic shielding composite material and preparation method thereof
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  • High-thermal-conductivity polyetheretherketone electromagnetic shielding composite material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] 1. Preparation of spherical core-shell structure high thermal conductivity filler

[0023] In this embodiment, a spherical core-shell structure high thermal conductivity filler with a particle size of 1.0 mm and a sulfonation degree of 40% is used. The specific operation is:

[0024] Dissolve 4,4'-difluorobenzophenone into 98wt.% concentrated sulfuric acid, and the mass ratio of 4,4'-difluorobenzophenone to concentrated sulfuric acid is 1:10. The reaction system was kept stirring at 100° C. for 10 h. The reaction was cooled to room temperature, and the reaction solution was poured into a large amount of ice water to cool. Then NaCl was added to the reaction solution until precipitation occurred, the product was filtered, washed repeatedly with deionized water until neutral, and dried to obtain 4,4'-difluoro-3,3'-disulfonic acid benzophenone.

[0025] Add 4,4'-difluorobenzophenone, 4,4'-difluoro-3,3'-disulfonic acid benzophenone, Hydroquinone and potassium carbonate,...

Embodiment 2

[0040] 1. Preparation of polyetheretherketone composites

[0041] In this embodiment, a spherical core-shell structure high thermal conductivity filler with a particle size of 2.0 mm and a sulfonation degree of 40% is used. The specific operation of the nucleophilic substitution reaction and the drying method is the same as in Example 1. The difference is that the sulfonated polyether ether ketone is cut using a spherical mold with a particle size of 2.0 mm to obtain spherical sulfonated polyether ether ketone particles with a particle size of 2.0 mm. Weigh the mass, and the mass of 100 spherical particles is 4.528g.

[0042] The electrostatic field treatment is the same as in Example 1. Weigh the mass, and the mass of 100 spherical core-shell structure high thermal conductivity fillers is 8.906g. Through calculation, the graphite adsorption mass of 100 core-shell structure high thermal conductivity fillers is 4.378g, with an average of 0.0438g graphite per adsorbed graphit...

Embodiment 3

[0048] 1. Preparation of polyetheretherketone composites

[0049] In this embodiment, a spherical core-shell structure high thermal conductivity filler with a particle size of 3.0 mm and a sulfonation degree of 40% is used. The specific operation of the nucleophilic substitution reaction and the drying method is the same as in Example 1. The difference is that the sulfonated polyether ether ketone is cut using a spherical die with a particle size of 3.0 mm to obtain spherical particles with a particle size of 3.0 mm. Weigh the mass, and the mass of 50 spherical particles is 7.643g.

[0050] The electrostatic field treatment is the same as in Example 1. Weigh the mass, and the mass of 50 spherical core-shell structure high thermal conductivity fillers is 13.857g. Through calculation, the graphite adsorption mass of 50 core-shell structure high thermal conductivity fillers is 6.214g, with an average of 0.124g graphite per adsorbed graphite, and the mass fraction of graphite o...

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Abstract

The invention discloses a high-thermal-conductivity polyetheretherketone electromagnetic shielding composite material and a preparation method thereof, and belongs to the technical field of high-performance composite materials. The composite material is prepared by uniformly mixing 10-50 wt% of a spherical core-shell structure high-thermal-conductivity filler, 5-10 wt% of a carbon fiber, and the balance of polyetheretherketone according to the mass sum of 100% under certain processing conditions. Experimental results show that the product has an arc-shaped shell, and is a thermal-conducting graphite shell obtained by stripping off the spherical core-shell filler under a liquid nitrogen condition, and so that the high-thermal-conductivity filler with the core-shell structure is successfullyintroduced into the polyetheretherketone composite material. It is also proved that the filler shell still keeps the original distribution state no matter under a high-temperature or freezing condition, so that the production of the high-thermal-conductivity electromagnetic shielding material by constructing filler distribution of a special structure is achieved. The problems of agglomeration, poor dispersivity, too large filling amount and small heat conductivity increasing amplitude of fillers are solved.

Description

technical field [0001] The invention belongs to the technical field of high-performance composite materials, and in particular relates to a high thermal conductivity polyetheretherketone electromagnetic shielding composite material and a preparation method thereof. Background technique [0002] Polymer materials have been gradually used in various fields by virtue of their advantages such as light weight, good chemical stability, and high mechanical strength. However, as a polymer material, its own molecular structure makes the propagation efficiency of phonon vibrations in it extremely low, so most materials have heat insulation and no electromagnetic shielding performance, which makes polymer materials unable to be used in some fields . For example, electronic components, electromagnetic shielding partitions and other fields. To address the above requirements, polymer materials need to be further modified into composite materials. [0003] As one of the most commonly us...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L61/16C08K7/06C08K9/12C08K3/04H05K9/00
CPCC08L61/16C08L2205/025H05K9/009C08K9/12C08K3/04C08K7/06
Inventor 牟建新赵轩李澍陈瑞吴焓何青霞
Owner JILIN UNIV
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