Raw material film, stretched optical film manufacturing method, and stretched optical film
A technology of optical film and original material film, which is applied in the direction of optical elements, flat products, polarizing elements, etc., and can solve the problems of cracking of polarizing film, high cost, cracking of polarizing film, etc.
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[0131] The raw material film, the stretched optical film, and the manufacturing method of the stretched optical film of this invention are not limited to the said embodiment. For example, although the case where a stretched optical film is a polarizing film was mainly demonstrated as a stretched optical film and its manufacturing method, a stretched optical film is not limited to a polarizing film. For example, stretched optical films other than polarizing films, such as retardation films, are also within the scope of the present invention, and can be produced by a production method including a step of stretching the original film of the present invention. The manufacturing method of the retardation film which is one Embodiment of this invention can be performed using a conventionally well-known method except stretching the original film of this invention.
Embodiment
[0133] The following examples illustrate the present invention concretely, but the present invention is not limited to these examples at all. In addition, each evaluation method employed in the following examples and comparative examples is as follows.
[0134] [Glass transition temperature of resin pellets]
[0135] After dissolving the original film obtained in each of the following Examples or Comparative Examples in water, it was filtered with a filter capable of trapping resin particles (“MF-Millipore Menbrunn Filter VSWP” from Merck, pore size: 0.025 μm) , and dry the trap (resin particles). Thereafter, the resin pellets were heat-treated at 100° C., thereby collecting a resin film formed of only the resin pellets. The glass transition temperature of the resin film was calculated|required using DSC ("Q2000" of TA Instruments company). Let this be the glass transition temperature of the resin particle.
[0136] [Swelling degree of original film]
[0137] About 1.5 g ...
manufacture example 1
[0168] [Manufacture Example 1] Manufacture of resin pellet A
[0169] Into a dry 0.5 L pressure-resistant polymerization tank, 0.20 g of potassium persulfate as a polymerization initiator, 36.0 g of a reactive emulsifier "JS-20" of Sanyo Chemical Industry Co., Ltd., and 300 g of ion-exchanged water were charged. This was deoxidized by bubbling nitrogen gas for 30 minutes to obtain a starting emulsion. Next, after raising the temperature of the initial emulsion to 60° C. while stirring, 45.0 g of n-butyl acrylate, 0.45 g of allyl methacrylate and trihydroxyl acrylate degassed were added continuously at a rate of 1.0 ml / min. A mixed solution of 0.23 g of methylpropane trimethacrylate.
[0170] Thereafter, when it was confirmed that the conversion rate of each monomer calculated by the method described later exceeded 95% by mass, 5.6 g of degassed dicyclopentanyl methacrylate was continuously added at a rate of 1.0 ml / min. After the above-mentioned addition, it was confirmed th...
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Abstract
Description
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