Flame-retardant heat-conducting nano composite material and preparation method and application thereof

A nanocomposite material and composite material technology are applied in the field of flame-retardant and thermally conductive nanocomposite materials and their preparation, which can solve the problems of poor thermal conductivity of battery shells, poor thermal conductivity of plastics, hidden safety hazards, etc., and achieve good flame retardant effect and excellent processing. performance effect

Inactive Publication Date: 2020-04-10
SUZHOU HSM TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although the plastic outer casing brings greater convenience to the design and promotion of batteries, the thermal conductivity of the plastic itself is poor.
The battery will generate a lot of heat during the charging and discharging process, resulting in a relatively complex environment for the entire battery, and there will also be certain safety hazards
[0003] At present, there are many reports on the application of flame-retardant polypropylene to battery shell patents, but there are still defects such as unsatisfactory flame-retardant effect, poor mechanical properties, and failure to take into account the heat dissipation performance of the battery.
[0004] Chinese patent CN102453280 A discloses a power battery shell material based on polypropylene material and its preparation method. The flame retardancy and mechanical properties have been improved, but the thermal conductivity of the battery shell is poor, and the battery is generated during charging and discharging. Heat may cause other hazards

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] A flame-retardant and heat-conducting nano-composite material. The raw materials are composed of the following parts by mass: 30 parts of polypropylene resin, 10 parts of glass fiber, 5 parts of heat-conducting powder, 15 parts of flame retardant, 0.5 parts of nano-scale flame-retardant and heat-conducting accelerator, and even 0.5 part of joint agent, 5 parts of toughening agent, 0.5 part of compatibilizer, 0.1 part of antioxidant, and 0.1 part of lubricant.

[0031] Among them, the above-mentioned polypropylene is selected from homopolypropylene with a melt index of 50g / 10min under the test condition of 230°C / 2.16kg; the length of the glass fiber is 10mm; the heat-conducting powder is boron nitride; the flame retardant is coke Piperazine phosphate and melamine polyphosphate, the mass ratio of the two added is 2:1; the nano-flame retardant thermal conductivity accelerator is organic montmorillonite; the coupling agent is γ-aminopropyltriethoxysilane; the toughening The...

Embodiment 2

[0034] A flame-retardant and heat-conducting nano-composite material. The raw materials are composed of the following parts by mass: 30 parts of polypropylene resin, 10 parts of glass fiber, 5 parts of heat-conducting powder, 15 parts of flame retardant, 0.5 parts of nano-scale flame-retardant and heat-conducting accelerator, and even 0.5 part of joint agent, 5 parts of toughening agent, 0.5 part of compatibilizer, 0.1 part of antioxidant, and 0.1 part of lubricant.

[0035] Among them, the above-mentioned polypropylene is selected from homopolypropylene with a melt index of 50g / 10min under the test condition of 230°C / 2.16kg; the length of the glass fiber is 10mm; the heat-conducting powder is boron nitride; the flame retardant is ten A mixture of brominated diphenylethane and antimony trioxide, the mass ratio of the two added is 3:1; the nano-flame retardant thermal conductivity accelerator is organic montmorillonite; the coupling agent is γ-aminopropyltriethoxysilane; The to...

Embodiment 3

[0039] A flame-retardant and heat-conducting nano-composite material. The raw materials are composed of the following parts by mass: 30 parts of polypropylene resin, 10 parts of glass fiber, 5 parts of heat-conducting powder, 15 parts of flame retardant, 0.5 parts of nano-scale flame-retardant and heat-conducting accelerator, and even 0.5 part of joint agent, 5 parts of toughening agent, 0.5 part of compatibilizer, 0.1 part of antioxidant, and 0.1 part of lubricant.

[0040] Among them, the above-mentioned polypropylene is selected from homopolypropylene with a melt index of 70g / 10min under the test condition of 230°C / 2.16kg; the length of the glass fiber is 10mm; the heat-conducting powder is boron nitride; the flame retardant is coke Piperazine phosphate and melamine polyphosphate, the mass ratio of the two added is 2:1; the nano-flame retardant thermal conductivity accelerator is carbon nanotubes; the coupling agent is γ-aminopropyltriethoxysilane; the toughening agent It i...

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Abstract

The invention discloses a flame-retardant heat-conducting nano composite material and a preparation method and application thereof. Raw materials of the nano composite material include, by mass, 30-70parts of polypropylene resin, 10-40 parts of glass fibers, 5-35 parts of heat conducting powder, 15-45 parts of a flame retardant, 0.5-10 parts of a nano flame retardant thermal conductivity accelerator, 0.5-3 parts of a coupling agent, 5-15 parts of a toughening agent, 0.5-5 parts of a compatibilizer, 0.1-1 parts of an antioxidant and 0.1-1 part of a lubricant. According to the nano composite material, the heat conducting powder, the flame retardant and the nano flame retardant thermal conductivity accelerator are optimized to ensure heat conductivity, flame retardance and mechanical performance of the material when applied in battery outer shells. The compatibilizer and a dispersant are optimized to ensure dispersion of various additives in the resin. The resin with high fluidity is selected so that excellent processing performance is provided, and precise preparation of a complex battery outer shell structure and effective bonding with a battery module can be ensured.

Description

technical field [0001] The invention relates to the technical field of modified composite materials, in particular to a flame-retardant and heat-conducting nano-composite material and its preparation method and application. Background technique [0002] At present, there are battery casings with various base materials on the market, including steel casings, aluminum casings and plastic casings. Among the plastic casings, battery casings based on polypropylene account for a large part. Although the plastic outer casing brings greater convenience to the design and promotion of batteries, the thermal conductivity of plastic itself is poor. The battery will generate a lot of heat during the charging and discharging process, resulting in a relatively complex environment for the entire battery, and there will also be certain potential safety hazards. [0003] At present, there are many reports on the application of flame-retardant polypropylene to battery shell patents, but there...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/12C08L51/06C08K13/06C08K7/14C08K3/38C08K5/3462C08K5/3492C08K3/34C08K13/04C08K5/03C08K3/22C08K3/04
CPCC08L23/12C08L2205/03C08L2201/02C08L2203/20C08K2201/011C08K2003/385C08K2201/004C08L51/06C08K13/06C08K7/14C08K3/38C08K5/3462C08K5/34928C08K3/346C08K5/03C08K3/2279C08K13/04C08K3/041
Inventor 何明山台启龙
Owner SUZHOU HSM TECH CO LTD
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