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Hydrogenation decolorization method of petroleum resin

A petroleum resin and decolorization technology, which is applied in the field of petroleum resin production, can solve the problems of unreasonable hydrogenation decolorization method, affecting the normal use of resin, poor resin decolorization effect, etc., and achieves good decolorization effect, thorough reaction and improved efficiency.

Inactive Publication Date: 2020-04-17
南京雪郎化工科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] At present, the hydrogenation and decolorization method of petroleum resin is unreasonable, resulting in poor decolorization effect of the resin, which affects the normal use of the resin. At the same time, the resin is not post-treated after the hydrogenation decolorization, so that the resin contains more reactions. The additives brought in during the process, the product purity is low, which brings a lot of trouble to the user

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] A method for hydrogenation decolorization of petroleum resin, comprising the following steps:

[0026] (1) Put the petroleum resin into the dissolution kettle, then add the organic solvent, adjust the rotation speed to 100-200r / min to dissolve, dissolve the solution for 1.5-2h, then add the solution to the impurity removal reactor, remove the colloid, and then process the solution Preheating;

[0027] (2) Inject the preheated solution in the above step (1) into a hydrogenation fixed-bed reactor, cover the surface of the solution with a layer of catalyst A, raise the temperature to 240-280°C, and then pass in hydrogen for one hydrogenation Hydrogen decolorization reaction, stop feeding hydrogen after reacting for 3-4h;

[0028] (3) Pump the solution that has undergone the first reaction in the above step (2) into the second-stage hydrogenation fixed-bed reactor, cover the surface of the solution with a layer of catalyst B, raise the temperature to 280-320°C, and then in...

Embodiment 2

[0033] A method for hydrogenation decolorization of petroleum resin, comprising the following steps:

[0034] (1) Put the petroleum resin into the dissolution kettle, then add the organic solvent, adjust the rotation speed to 100-200r / min to dissolve, dissolve the solution for 1.5-2h, then add the solution to the impurity removal reactor, remove the colloid, and then process the solution Preheating;

[0035] (2) Inject the preheated solution in the above step (1) into a hydrogenation fixed-bed reactor, cover the surface of the solution with a layer of catalyst A, raise the temperature to 240-280°C, and then pass in hydrogen for one hydrogenation Hydrogen decolorization reaction, stop feeding hydrogen after reacting for 3-4h;

[0036] (3) Pump the solution that has undergone the first reaction in the above step (2) into the second-stage hydrogenation fixed-bed reactor, cover the surface of the solution with a layer of catalyst B, raise the temperature to 280-320°C, and then in...

Embodiment 3

[0041] A method for hydrogenation decolorization of petroleum resin, comprising the following steps:

[0042] (1) Put the petroleum resin into the dissolution kettle, then add the organic solvent, adjust the rotation speed to 100-200r / min to dissolve, dissolve the solution for 1.5-2h, then add the solution to the impurity removal reactor, remove the colloid, and then process the solution Preheating;

[0043] (2) Inject the preheated solution in the above step (1) into a hydrogenation fixed-bed reactor, cover the surface of the solution with a layer of catalyst A, raise the temperature to 240-280°C, and then pass in hydrogen for one hydrogenation Hydrogen decolorization reaction, stop feeding hydrogen after reacting for 3-4h;

[0044] (3) Pump the solution that has undergone the first reaction in the above step (2) into the second-stage hydrogenation fixed-bed reactor, cover the surface of the solution with a layer of catalyst B, raise the temperature to 280-320°C, and then in...

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PUM

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Abstract

The invention provides a hydrogenation decolorization method of a petroleum resin, and relates to the technical field of petroleum resin production. The method comprises the following steps: dissolving, impurity removal, preheating, hydrogenation decolorization, alkali washing, water washing, distillation and steam stripping. According to the invention, a petroleum resin is subjected to two hydrogenation decolorization reactions, and is catalyzed to different degrees with two different catalysts, so that the petroleum resin completely reacts, and the decoloration effect is good; and the petroleum resin after the reaction is subjected to multiple post-treatments to effectively remove the additive in the product, so that the product is high in purity and convenient to use.

Description

technical field [0001] The invention relates to the technical field of petroleum resin production, in particular to a method for hydrogenation and decolorization of petroleum resin. Background technique [0002] Petroleum resin is named for its source of petroleum derivatives. It has the characteristics of low price, low acid value, good miscibility, low melting point, water resistance, ethanol resistance and chemical resistance, chemical stability to acid and alkali, and adjustable viscosity. and good thermal stability. Petroleum resins are generally not used alone, but as accelerators, regulators, modifiers and other resins, and can be widely used in various industries and fields such as rubber, adhesives, coatings, papermaking, and inks. [0003] The appearance of traditional petroleum resin is yellowish or brown, which limits its application to a large extent. After hydrogenation modification, the saturation degree of the resin has been significantly improved, the resi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F8/04C08F240/00
CPCC08F8/04C08F240/00
Inventor 李云政张磊
Owner 南京雪郎化工科技有限公司