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A Method for Improving Interlayer Bonding Strength of Winding Formed Carbon/Carbon Composite Materials

A technology of interlayer bonding strength and carbon composite materials, which is applied in the field of improving the interlayer bonding strength of winding carbon/carbon composite materials, which can solve the problem of limited interlayer reinforcement effect and difficulty in significantly improving the interaction between the long fiber layer and the short fiber layer, etc. problems, achieve the effect of improving corrosion resistance, ensuring bonding strength, and simple process

Active Publication Date: 2022-03-04
XIAN CHAOMA SCI TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This technology achieves interlayer reinforcement by interlacing multiple layers of long fiber layers and short fiber layers. It can be seen from the principle that it is difficult to significantly improve the interaction between long fiber layers and short fiber layers only by simply laying alternately. limited

Method used

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  • A Method for Improving Interlayer Bonding Strength of Winding Formed Carbon/Carbon Composite Materials
  • A Method for Improving Interlayer Bonding Strength of Winding Formed Carbon/Carbon Composite Materials
  • A Method for Improving Interlayer Bonding Strength of Winding Formed Carbon/Carbon Composite Materials

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0039] This embodiment includes the following steps:

[0040] Step 1. Mandrel preparation: Determine the design density of the target product carbon / carbon composite material crucible to be 1.40g / cm 3 , the wall thickness is 18mm, the height is 400mm, the inner diameter of the straight section is 660mm, and the hoop tensile strength index is not less than 100MPa. Select No. 45 steel to process and manufacture the mandrel and assemble it, and clean the outer surface of the mandrel after assembly, and then Lay release cloth and brush release agent on the outer surface of the mandrel after cleaning, lay the graphite paper that brushes phenolic resin again to laying thickness and be 5mm; The profile of described mandrel is consistent with two target products The shape of the carbon / carbon composite crucible is similar after splicing. The outer diameter of the straight section of the mandrel is 650mm. The length of the mandrel is more than twice the height of the target product car...

Embodiment 2

[0050] The difference between this embodiment and Example 1 is: the design density of the target product charcoal / charcoal crucible side in step 1 is 1.65g / cm 3 , the bonding strength between layers is not less than 20MPa, the hoop tensile strength index is not less than 150MPa, the material of the core mold is electrode graphite, the outer diameter of the core mold is 600mm, and the carbon felt impregnated with furfurone resin is laid until the laying thickness is 30mm ; In step 2, the 24K polyacrylonitrile-based carbon fiber impregnated with furfurone resin ethanol solution is used for semi-dry winding, and the winding mode is alternate winding of hoop and spiral, wherein the angle of hoop winding is 89 °, and the angle of helical winding 85°, the net tire is laid after every 5 layers of winding, and the net tire surface density is 300g / cm 3 , and then use an acupuncture machine for acupuncture treatment under the mandrel rotation state, the acupuncture depth is 10mm, the ac...

Embodiment 3

[0053] The difference between this embodiment and embodiment 1 is: the design density of target product charcoal / charcoal crucible side in step 1 is 1.35g / cm 3 , the bonding strength between layers is not less than 12MPa, the hoop tensile strength index is not less than 60MPa, the material of the mandrel is electrode graphite, the outer diameter of the mandrel is 630mm, and the soft heat-resistant material laid on the mandrel is carbon fiber mesh The laying thickness of the tire is 15mm; in step 2, 1.5K viscose-based carbon fibers are used for hoop and spiral winding alternately, wherein the angle of hoop winding is 85°, the angle of helical winding is 20°, and the viscose-based carbon fiber Before winding, the carbon fiber is fully immersed in the ethanol solution of phenolic resin for wet winding. After every 8 times of alternating hoop and spiral winding, the mesh tire is laid and resin powder is sprayed. The mesh tread surface density is 160g / cm 3 , and then use an acupunc...

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Abstract

The invention discloses a method for improving the bonding strength between layers of winding carbon / carbon composite materials. 2. Wind the continuous carbon fiber pre-impregnated with resin on the mandrel laying the soft heat-resistant material to form a fiber layer with glue, lay the net tire and needle punch, and form winding-needle punching on the mandrel 3. Remove the soft heat-resistant material after solidifying and demoulding the winding-acupuncture parts to obtain a cured part; 4. Carbonize the cured part to obtain a carbonized part; 5. Perform high-temperature purification treatment on the carbonized part; The carbonized parts after the purification treatment are processed by machine to obtain a winding carbon / carbon composite material. In the present invention, by laying the mesh tire in the rubberized fiber layer and introducing carbon fiber in the radial direction in combination with acupuncture treatment, the winding process forming-dense integration is realized, and the interlayer bonding strength of the winding carbon / carbon composite material is improved. .

Description

technical field [0001] The invention belongs to the technical field of composite material preparation, and in particular relates to a method for improving the bonding strength between layers of winding-molded carbon / carbon composite materials. Background technique [0002] Composite winding molding technology has become an important process for composite material processing. Winding molding can give full play to the nature of the component materials of composite materials, and the laying direction of fiber reinforced materials is accurate, with high fiber volume content and good strength performance. Therefore, the application of winding molding to prepare carbon / carbon composite products can maintain the quality of continuous fiber laying and is conducive to improving the hoop tensile properties of products. However, the winding carbon / carbon composite products are only bonded by the matrix material between the fiber reinforced materials. During the preparation and applicat...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B29C70/32B29C70/38B29C70/54
CPCB29C70/32B29C70/38B29C70/54
Inventor 赵松程皓党瑞萍彭志刚张灵玉代丽娜张永辉
Owner XIAN CHAOMA SCI TECH