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Cross-linked environment-friendly flame-retardant reinforced polyamide-based composite material and preparation method thereof

A polyamide-based, composite material technology, applied in the field of polymer materials, can solve the problems of high cost of flame-retardant glass fiber reinforced nylon, flame-retardant glass fiber reinforced semi-aromatic nylon, and high requirements for flame retardants, and achieves improved weld line strength, The effect of reducing the risk of damage

Inactive Publication Date: 2020-06-26
河北旭阳能源有限公司 +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The purpose of the present invention is to provide a cross-linked environmentally friendly flame-retardant reinforced polyamide-based composite material and its preparation method to solve the existing technical defects in the preparation of flame-retardant glass fiber reinforced nylon and the cost of flame-retardant glass fiber reinforced semi-aromatic nylon Due to technical defects such as high and high requirements for flame retardants, the cross-linked environmentally friendly flame-retardant reinforced polyamide-based composite material of the present invention has excellent flame-retardant properties, heat-resistant properties and physical and mechanical properties, and excellent comprehensive properties

Method used

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  • Cross-linked environment-friendly flame-retardant reinforced polyamide-based composite material and preparation method thereof
  • Cross-linked environment-friendly flame-retardant reinforced polyamide-based composite material and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0043] A cross-linked environment-friendly flame-retardant reinforced polyamide-based composite material, comprising: 52 parts by weight of nylon 66 (PA66), 30 parts by weight of glass fiber, 5 parts by weight of a compatibilizer (maleic anhydride graft copolymer), and a flame retardant 10 parts by weight of aluminum diethyl hypophosphite, 1 part by weight of main crosslinking agent, 1 part by weight of auxiliary crosslinking agent, 0.2 part by weight of antioxidant (model 1098), 0.5 part by weight of coupling agent (KH570), lubricant ( Silicone masterbatch) 0.3 parts by weight.

[0044] The preparation method of the above-mentioned cross-linked environmentally friendly flame-retardant reinforced polyamide-based composite material, the steps are as follows:

[0045] 1) Put the formulated amount of glass fiber and coupling agent into a high-speed mixer, set the speed at 500r / min, and stay for 5 minutes to fully mix and disperse each component.

[0046] 2) Put the formula amoun...

Embodiment 2

[0053] A cross-linked environment-friendly flame-retardant reinforced polyamide-based composite material, comprising: 47 parts by weight of nylon 66 (PA66), 30 parts by weight of glass fiber, 5 parts by weight of a compatibilizer (maleic anhydride graft copolymer), and a flame retardant 15 parts by weight of aluminum diethyl hypophosphite, 1 part by weight of main crosslinking agent, 1 part by weight of auxiliary crosslinking agent, 0.2 part by weight of antioxidant (model 1098), 0.5 part by weight of coupling agent (KH570), lubricant ( Silicone masterbatch) 0.3 parts by weight.

[0054] Its preparation method is identical with the preparation method of embodiment 1.

Embodiment 3

[0056] A cross-linked environment-friendly flame-retardant reinforced polyamide-based composite material, comprising: 47 parts by weight of nylon 66 (PA66), 30 parts by weight of glass fiber, 5 parts by weight of a compatibilizer (maleic anhydride graft copolymer), and a flame retardant 15 parts by weight of melamine cyanurate, 1 part by weight of main crosslinking agent, 1 part by weight of auxiliary crosslinking agent, 0.2 part by weight of antioxidant (model 1098), 0.5 part by weight of coupling agent (KH570), lubricant (silicon Ketone masterbatch) 0.3 parts by weight.

[0057] Its preparation method is identical with the preparation method of embodiment 1.

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Abstract

The invention discloses a cross-linked environment-friendly flame-retardant reinforced polyamide-based composite material and a preparation method thereof. The material comprises, by weight, 20 to 80parts of aliphatic polyamide, 10-40 parts of glass fibers, 10 to 20 parts of a flame retardant, 0.5 to 10 parts of a main cross-linking agent, 0.5 to 10 parts of an auxiliary cross-linking agent, 0.5to 10 parts of a compatilizer, 0.1 to 0.3 part of a coupling agent, 0.1 to 0.3 part of a lubricating agent and 0.1 to 0.3 part of an antioxidant. The mechanical properties and thermal properties, especially the thermal deformation temperature, of the cross-linked environment-friendly flame-retardant reinforced polyamide-based composite material prepared from the raw materials are integrally improved by 30% or above; the mechanical property and the thermal property, especially the thermal deformation temperature, are integrally improved by 15% or above, the strength of the weld line is improvedby adopting the preparation method, and the risk of damage caused by cracks in the use process of the material is reduced to a great extent.

Description

technical field [0001] The invention belongs to the technical field of polymer materials, and relates to the technical field of preparation of a cross-linked environmentally friendly flame-retardant reinforced polyamide-based composite material, in particular to a cross-linked environmentally friendly flame-retardant reinforced polyamide-based composite material and a preparation method thereof. Background technique [0002] Polyamide (commonly known as: nylon) is one of the five major engineering plastics. It has excellent physical and mechanical properties such as high strength, high modulus, corrosion resistance, and low temperature resistance. It is currently widely used in the fields of automobiles, home appliances, and electronic appliances. In the field of electronics and electrical appliances, the flame retardancy of nylon is relatively good, and it is generally required to add flame retardants to achieve the flame retardancy of nylon. Especially in some special fiel...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L77/06C08L83/04C08K13/04C08K7/14C08K5/20C08K5/5419C08K5/5313C08K5/3492C08J5/04
CPCC08J5/043C08J2377/06C08J2483/04C08K5/20C08K5/34928C08K5/5313C08K5/5419C08K7/14C08K13/04
Inventor 王国利党伟荣陈西波王伟尹天长周文涛王秀彪杨克明
Owner 河北旭阳能源有限公司
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