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Etching solution and preparation method thereof

A technology of etching solution and metal corrosion inhibitor, which is applied in the direction of chemical instruments and methods, surface etching compositions, etc., can solve the problem of difficult to ensure the effective etching of metal oxide film layers, increase the number of MASK used, and solve the problem of metal oxide film The problem of layer residue and other problems can be reduced to achieve the effect of reducing the number of photomasks used, good etching stability, and reducing material costs.

Active Publication Date: 2020-06-26
CHENGDU ZHONGDIAN PANDA DISPLAY TECH CO LTD
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  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Taking metal oxide-TFT as an example, when etching the source and drain electrodes, different etching solutions are selected to etch the SD layer and the metal oxide film layer step by step, which undoubtedly increases the number of MASKs used, and it is difficult to achieve cost reduction. reduce
If only one of the etching solutions is used to etch the SD layer and the metal oxide film layer synchronously, for example, the SD layer and the metal oxide film layer are etched synchronously using the etching solution for etching the SD layer, then it is difficult to ensure Effective etching of the metal oxide film layer will not only have a metal oxide film layer residue, but also make the etching profile uncontrollable, which will affect the performance of the semiconductor device

Method used

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  • Etching solution and preparation method thereof
  • Etching solution and preparation method thereof
  • Etching solution and preparation method thereof

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preparation example Construction

[0082] The second aspect of the present invention is to provide the preparation method of the aforementioned etching solution, comprising: mixing and stirring hydrogen peroxide, inorganic acid, hydrogen peroxide stabilizer, pH regulator, complexing agent, metal corrosion inhibitor, and water to obtain the etching solution of the present invention. Etching liquid.

[0083] Wherein, the mass percent content of each component in the etching solution is the same as that described above, and will not be repeated here.

[0084] Specifically, hydrogen peroxide can be mixed with water first, and then inorganic acid, hydrogen peroxide stabilizer, pH regulator, complexing agent, and metal corrosion inhibitor can be added respectively to the mixing system. The order of adding the pH regulator, complexing agent and metal corrosion inhibitor is not limited.

[0085] The preparation method of the etching solution of the present invention has relatively low technological difficulty, and can...

Embodiment 1

[0090] The etching solution of this embodiment comprises the following components according to mass percentage:

[0091] Hydrogen peroxide: 13.0%

[0092] Inorganic acid: 0.10% hydrofluoric acid, 2.60% nitric acid

[0093] Hydrogen peroxide stabilizer: phenylurea 0.10%, glycolic acid 0.80%

[0094] pH regulator: triethanolamine 1.20%, 2-hydroxybutanediamine 1.0%

[0095] Complexing agent: malic acid 1.50%, succinic acid 2.0%

[0096] Metal corrosion inhibitor: 5-aminotetrazole 0.05%

[0097] Water: 77.65%

[0098] The above components were mixed and stirred while maintaining the system temperature at 32° C. to obtain the etching solution of this embodiment.

Embodiment 2

[0100] The etching solution of this embodiment comprises the following components according to mass percentage:

[0101] Hydrogen peroxide: 13.0%

[0102] Inorganic acid: 0.10% hydrofluoric acid, 2.60% nitric acid

[0103] Hydrogen peroxide stabilizer: phenylurea 0.10%, glycolic acid 0.80%

[0104] pH regulator: Triethanolamine 2.0%

[0105] Complexing agent: malic acid 2.80%

[0106] Metal corrosion inhibitor: 5-aminotetrazole 0.05%

[0107] Water: 78.55%

[0108] The above components were mixed and stirred while maintaining the system temperature at 32° C. to obtain the etching solution of this embodiment.

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Abstract

The invention provides an etching solution and a preparation method thereof. The etching solution comprises, by mass, 1-20% of hydrogen peroxide, 0.01-5% of an inorganic acid, 0.01-5% of a hydrogen peroxide stabilizer, 1-10% of a pH regulator, 1-10% of a complexing agent, 0.01-2% of a metal corrosion inhibitor, and the balance of water, wherein the inorganic acid at least comprises a fluorine compound. The etching solution can realize etching of source and drain metal electrodes and a metal oxide film layer at the same time, the use number of photomasks is reduced under the condition that theperformance of a semiconductor device is not influenced, the material cost is reduced, and the technological process is simplified.

Description

technical field [0001] The invention relates to an etching solution and a preparation method thereof, and belongs to the technical field of etching. Background technique [0002] With the flat panel display industry becoming increasingly saturated, various panel companies focus on developing new processes to reduce production costs, such as shortening the panel production process and reducing raw material consumption. The TFT process with the highest cost has become a key node for enterprises to reduce costs and increase efficiency. The most significant measure is to reduce the number of MASKs used. [0003] Taking metal oxide-TFT as an example, when etching the source and drain electrodes, different etching solutions are used to etch the SD layer and the metal oxide film layer step by step, which undoubtedly increases the number of MASKs used, and it is difficult to achieve cost reduction. reduce. If only one of the etching solutions is used to etch the SD layer and the m...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K13/08C23F1/18C23F1/26
CPCC09K13/08C23F1/18C23F1/26
Inventor 李广圣蒋雷黄学勇叶宁刘翔赵亚雄
Owner CHENGDU ZHONGDIAN PANDA DISPLAY TECH CO LTD
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