Etching solution and preparation method thereof
A technology of etching solution and metal corrosion inhibitor, which is applied in the direction of chemical instruments and methods, surface etching compositions, etc., can solve the problem of difficult to ensure the effective etching of metal oxide film layers, increase the number of MASK used, and solve the problem of metal oxide film The problem of layer residue and other problems can be reduced to achieve the effect of reducing the number of photomasks used, good etching stability, and reducing material costs.
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[0082] The second aspect of the present invention is to provide the preparation method of the aforementioned etching solution, comprising: mixing and stirring hydrogen peroxide, inorganic acid, hydrogen peroxide stabilizer, pH regulator, complexing agent, metal corrosion inhibitor, and water to obtain the etching solution of the present invention. Etching liquid.
[0083] Wherein, the mass percent content of each component in the etching solution is the same as that described above, and will not be repeated here.
[0084] Specifically, hydrogen peroxide can be mixed with water first, and then inorganic acid, hydrogen peroxide stabilizer, pH regulator, complexing agent, and metal corrosion inhibitor can be added respectively to the mixing system. The order of adding the pH regulator, complexing agent and metal corrosion inhibitor is not limited.
[0085] The preparation method of the etching solution of the present invention has relatively low technological difficulty, and can...
Embodiment 1
[0090] The etching solution of this embodiment comprises the following components according to mass percentage:
[0091] Hydrogen peroxide: 13.0%
[0092] Inorganic acid: 0.10% hydrofluoric acid, 2.60% nitric acid
[0093] Hydrogen peroxide stabilizer: phenylurea 0.10%, glycolic acid 0.80%
[0094] pH regulator: triethanolamine 1.20%, 2-hydroxybutanediamine 1.0%
[0095] Complexing agent: malic acid 1.50%, succinic acid 2.0%
[0096] Metal corrosion inhibitor: 5-aminotetrazole 0.05%
[0097] Water: 77.65%
[0098] The above components were mixed and stirred while maintaining the system temperature at 32° C. to obtain the etching solution of this embodiment.
Embodiment 2
[0100] The etching solution of this embodiment comprises the following components according to mass percentage:
[0101] Hydrogen peroxide: 13.0%
[0102] Inorganic acid: 0.10% hydrofluoric acid, 2.60% nitric acid
[0103] Hydrogen peroxide stabilizer: phenylurea 0.10%, glycolic acid 0.80%
[0104] pH regulator: Triethanolamine 2.0%
[0105] Complexing agent: malic acid 2.80%
[0106] Metal corrosion inhibitor: 5-aminotetrazole 0.05%
[0107] Water: 78.55%
[0108] The above components were mixed and stirred while maintaining the system temperature at 32° C. to obtain the etching solution of this embodiment.
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