A kind of etching solution and preparation method thereof
A technology of etching solution and metal corrosion inhibitor, which is applied in the direction of chemical instruments and methods, surface etching compositions, etc., can solve problems such as cost reduction that is difficult to achieve, metal oxide film residue, and performance impact of semiconductor devices. Achieve the effects of environmental friendliness, good etching stability, and guaranteed electrical characteristics
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[0082] The second aspect of the present invention is to provide the preparation method of the aforementioned etching solution, comprising: mixing and stirring hydrogen peroxide, inorganic acid, hydrogen peroxide stabilizer, pH regulator, complexing agent, metal corrosion inhibitor, and water to obtain the etching solution of the present invention. Etching liquid.
[0083] Wherein, the mass percent content of each component in the etching solution is the same as that described above, and will not be repeated here.
[0084] Specifically, hydrogen peroxide can be mixed with water first, and then inorganic acid, hydrogen peroxide stabilizer, pH regulator, complexing agent, and metal corrosion inhibitor can be added respectively to the mixing system. The order of adding the pH regulator, complexing agent and metal corrosion inhibitor is not limited.
[0085] The preparation method of the etching solution of the present invention has relatively low technological difficulty, and can...
Embodiment 1
[0090] The etching solution of this embodiment comprises the following components according to mass percentage:
[0091] Hydrogen peroxide: 13.0%
[0092] Inorganic acid: 0.10% hydrofluoric acid, 2.60% nitric acid
[0093] Hydrogen peroxide stabilizer: phenylurea 0.10%, glycolic acid 0.80%
[0094] pH regulator: triethanolamine 1.20%, 2-hydroxybutanediamine 1.0%
[0095] Complexing agent: malic acid 1.50%, succinic acid 2.0%
[0096] Metal corrosion inhibitor: 5-aminotetrazole 0.05%
[0097] Water: 77.65%
[0098] The above components were mixed and stirred while maintaining the system temperature at 32° C. to obtain the etching solution of this embodiment.
Embodiment 2
[0100] The etching solution of this embodiment comprises the following components according to mass percentage:
[0101] Hydrogen peroxide: 13.0%
[0102] Inorganic acid: 0.10% hydrofluoric acid, 2.60% nitric acid
[0103] Hydrogen peroxide stabilizer: phenylurea 0.10%, glycolic acid 0.80%
[0104] pH regulator: Triethanolamine 2.0%
[0105] Complexing agent: malic acid 2.80%
[0106] Metal corrosion inhibitor: 5-aminotetrazole 0.05%
[0107] Water: 78.55%
[0108] The above components were mixed and stirred while maintaining the system temperature at 32° C. to obtain the etching solution of this embodiment.
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