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Continuous electric heating rotary furnace and process for preparing lithium manganate through rotary furnace

A rotary furnace and continuous technology, which is applied in the field of continuous electric heating rotary furnace, can solve the problems of limited production efficiency of production enterprises, poor performance of heating and heat preservation, and insufficient heat preservation structure, and achieve shortening of calcination time, heating and heat preservation. Effects of performance improvement and energy consumption reduction

Active Publication Date: 2020-07-17
福建省云智新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Lithium manganate is one of the more promising lithium-ion cathode materials. At present, most of the mass production of commercial lithium manganate uses lithium manganate raw materials for high-temperature calcination. However, the existing calcination furnace insulation structure is not tight enough, and the performance of heating and heat preservation Poor, the reaction time for the lithium manganate calcination process is usually more than 20 hours, which greatly limits the production efficiency of the production enterprise, and the resource utilization rate is also low

Method used

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  • Continuous electric heating rotary furnace and process for preparing lithium manganate through rotary furnace
  • Continuous electric heating rotary furnace and process for preparing lithium manganate through rotary furnace
  • Continuous electric heating rotary furnace and process for preparing lithium manganate through rotary furnace

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Embodiment 1

[0080] This embodiment provides a continuous electric heating rotary furnace, such as Figure 1-3 Shown, including:

[0081] The furnace tube part 1 (specifically, the furnace tube part 1 is arranged on the furnace bottom beam 6) has a furnace heating zone inside, and the furnace tube part 1 as a whole is at a certain angle with the horizontal plane to allow the furnace tube part 1 to enter The material end is higher than the discharge end; the furnace heating is divided into several temperature zones (in a specific embodiment, from the front end to the back end of the furnace tube part 1 is divided into 9 temperature zones, and finally a slow cooling Zone), each of the temperature zones is independently controlled and heated, and the heat insulation layer of the furnace tube section 1 is made of high-temperature ceramic fiber material; the furnace roof of the furnace tube section 1 adopts a multi-section integrated block structure, and each section of the furnace roof is integrat...

Embodiment 2

[0148] This embodiment provides a method for calcining lithium manganate. The lithium manganate precursor is placed in the electric rotary furnace provided in Example 1, air is introduced at a flow rate of 30L / min, and the rotation speed of the furnace tube is controlled to 2 revolutions / Hours, heat the furnace temperature to 150 degrees in 15 minutes, calcine at 150 degrees for 60 minutes, then use 45 minutes to increase the temperature in the furnace from 150 degrees to 600 degrees, then keep the temperature at 600 degrees for 90 minutes, and then use 14 minutes to The temperature in the furnace is increased from 600 degrees to 740 degrees, and it is calcined at 740 degrees for 300 minutes. After the calcination is completed, the temperature is naturally cooled to room temperature to obtain a commercial lithium manganate product.

Embodiment 3

[0150] This embodiment provides a method for calcining lithium manganate. The lithium manganate precursor is placed in the electric rotary furnace provided in Example 1, air is introduced at a flow rate of 40L / min, and the rotation speed of the furnace tube is controlled at 6 rpm. Hours, heat the furnace temperature to 150 degrees in 10 minutes, calcine at 150 degrees for 40 minutes, then use 30 minutes to increase the temperature in the furnace from 150 degrees to 600 degrees, then keep the temperature at 600 degrees for 60 minutes, and then take 9 minutes to The temperature in the furnace is increased from 600 degrees to 740 degrees, and it is calcined at 740 degrees for 200 minutes. After the calcination is completed, the temperature is naturally cooled to room temperature to obtain a commercial lithium manganate product.

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Abstract

The invention relates to a continuous electric heating rotary furnace and a process for preparing lithium manganate through the rotary furnace. A hearth heating area is arranged in a furnace tube of the continuous electric heating rotary furnace, and the furnace tube and the horizontal plane overall form a certain angle, so that the feeding end of the furnace tube is higher than the discharging end; the hearth heating area is divided into a plurality of temperature areas, each temperature area achieves independent temperature control heating, and a heat insulation layer of the furnace tube ismade from a high-temperature ceramic fiber material; and multiple sections of overall combined block structures are adopted by the furnace top of the furnace tube, and clearances between all the furnace top overall combined blocks are stuffed and sealed through alumina silicate fiber blankets. Compared with a traditional electric heating rotary furnace, the continuous electric heating rotary furnace is additionally provided with more heat insulation structures, and the temperature raising and heat insulation performance in the furnace are greatly improved. According to the process for preparing the lithium manganate, the calcining time of an existing lithium manganate process can be greatly shortened and is controlled within 10 hours, the production efficiency of a production enterprise can be improved, and energy consumption can be reduced.

Description

Technical field [0001] The application belongs to the technical field of rotary kilns, and in particular relates to a continuous electric heating rotary kiln. Background technique [0002] Rotary kiln is a thermal equipment for heat treatment of bulk powder or particles. In recent years, with the continuous development of science and technology, it has been widely promoted and used in the chemical, metallurgy, cement, refractory, non-metallic mining and other industries. [0003] Lithium manganate is one of the more promising lithium ion cathode materials. At present, most of the mass production of commercial lithium manganate uses lithium manganate raw materials for high-temperature calcination, but the existing calcining furnace is not tight enough to heat up and has the performance of heat preservation. Inferior, the reaction time of the lithium manganate calcination process is usually greater than 20 hours, which greatly limits the production efficiency of the production enterp...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): F27B7/10F27B7/24F27B7/26F27B7/32F27B7/34F27B7/42F27D17/00
CPCF27B7/10F27B7/24F27B7/34F27B7/42F27B7/26F27B7/3205F27D17/008
Inventor 于伟
Owner 福建省云智新材料科技有限公司
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