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Method for recycling return sand in soda ash production

A technology of returning sand and soda ash, which is applied in the field of recycling sand returning in soda ash production, can solve problems such as powdering environmental pollution, affecting kiln ventilation, and increasing the cost of soda ash, achieving high economic value, avoiding waste of resources, and great environmental protection meaning effect

Inactive Publication Date: 2020-07-28
山东海天生物化工有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] At present, the quicklime CaO manufacturing process in the production process of soda ash (sodium carbonate) is affected by factors such as limestone (calcium carbonate) particle size, calcination temperature, calcination time, ventilation uniformity, and impurity nodules. 3 It cannot be completely decomposed, which eventually leads to a large amount of solid waste returning sand after the digestion of quicklime CaO (a soda ash plant with a scale of 1 million tons of soda ash per year can produce about 300 tons of returning sand with a size of 10mm<particle size<40mm)
Due to the small particle size of this part of the returned sand, it is easy to burst when heated, and it contains a large amount of carbon nuclei, magnesium-aluminum-silicon-ferrosilicon compounds, and tumor slag, which leads to the uncontrollable coke ratio of raw materials, seriously affects the kiln ventilation, and the temperature is out of control. Large-scale nodulation, currently All major soda ash plants have adopted fixed-point stacking or dam-building for the returned sand of this particle size. However, these two methods not only do not generate any income, but require a transportation fee of about 6-8 yuan per ton, with 1 million tons Calculated on the scale of soda ash, if the above-mentioned returned sand is converted into raw material limestone at 100 yuan / ton, then about 10 million yuan will be wasted throughout the year! Especially in recent years, the price of limestone has been rising continuously, which has caused the cost of soda ash to continue to increase. In addition, the low activity and slow pulverization of the returned sand have caused huge pollution to the environment.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] A method for recycling sand returned in soda ash production, comprising the following steps:

[0018] (1) Extract the returned sand with a particle size of 20mm-40mm with a rotary sieve, then place it in the jig machine and remove the coke core after treatment, and the obtained returned sand is for subsequent use;

[0019] (2) select the crushed stone with a particle size of 20-40mm for subsequent use;

[0020] (3) Mix the spare sand returned in step (1), crushed stone in step (2) and anthracite with a particle size of 10-40mm according to the ratio of mass ratio 605:230:43, and then put the above materials into the kiln furnace , the ventilation volume of the ignition stage is changed from 200m 3 / h increased to 5000m 3 / h, enter the calcination stage after the anthracite is ignited, and the ventilation volume in the calcination stage is controlled at 10000m 3 / h, the temperature in the calcination zone is controlled at 810°C, after 8 hours of calcination, the produ...

Embodiment 2

[0022] A method for recycling sand returned in soda ash production, comprising the following steps:

[0023] (1) Extract the returned sand with a particle size of 20mm-40mm with a rotary sieve, then place it in the jig machine and remove the coke core after treatment, and the obtained returned sand is for subsequent use;

[0024] (2) select the crushed stone with a particle size of 20-40mm for subsequent use;

[0025] (3) Mix the spare sand returned in step (1), crushed stone in step (2) and anthracite with a particle size of 10-40mm according to the ratio of mass ratio 620:250:47, and then put the above materials into the kiln furnace , the ventilation volume of the ignition stage is changed from 200m 3 / h increased to 5000m 3 / h, enter the calcination stage after the anthracite is ignited, and the ventilation volume in the calcination stage is controlled at 11000m 3 / h, the temperature in the calcination zone is controlled at 820°C, and after 9 hours of calcination, the p...

Embodiment 3

[0027] A method for recycling sand returned in soda ash production, comprising the following steps:

[0028] (1) Extract the returned sand with a particle size of 20mm-40mm with a rotary sieve, then place it in the jig machine and remove the coke core after treatment, and the obtained returned sand is for subsequent use;

[0029] (2) select the crushed stone with a particle size of 20-40mm for subsequent use;

[0030] (3) Mix the spare sand returned in step (1), crushed stone in step (2) and anthracite with a particle size of 10-40mm according to the ratio of mass ratio 650:270:50, and then put the above materials into the kiln furnace , the ventilation volume of the ignition stage is changed from 200m 3 / h increased to 5000m 3 / h, and enter the calcination stage after the anthracite is ignited. The ventilation rate of the calcination stage is controlled at 12000m3 / h, and the temperature of the calcination zone is controlled at 830°C. After 10 hours of calcination, the produ...

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PUM

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Abstract

The invention relates to the technical field of soda ash production, in particular to a method for recycling return sand in soda ash production, which comprises the following steps of: mixing the return sand and gravels, feeding the mixture into a kiln, and calcining the mixture to obtain quick lime. Return sand can be recycled to obtain raw materials for the soda ash preparation process, so thatresource waste is eliminated, profits are increased, environmental pollution is reduced, and huge economic benefits are increased for enterprises.

Description

technical field [0001] The invention relates to the technical field of soda ash production, in particular to a method for recycling sand returned in soda ash production. Background technique [0002] At present, the quicklime CaO manufacturing process in the production process of soda ash (sodium carbonate) is affected by factors such as limestone (calcium carbonate) particle size, calcination temperature, calcination time, ventilation uniformity, and impurity nodules. 3 It cannot be completely decomposed, which eventually leads to a large amount of solid waste returning to sand after the digestion of quicklime CaO (a soda ash plant with a scale of 1 million tons of soda ash per year can produce about 300 tons of returning sand with a particle size of 10mm<40mm per day). Due to the small particle size of this part of the returned sand, it is easy to burst when heated, and it contains a large amount of carbon nuclei, magnesium-aluminum-silicon-ferrosilicon compounds, and t...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B2/02C04B2/10
CPCC04B2/02C04B2/10
Inventor 马海滨张元德胡玉霆
Owner 山东海天生物化工有限公司
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