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Concrete corrosion inhibitor

The technology of concrete rust inhibitor and air-entraining agent is applied in the field of concrete rust inhibitor, which can solve the problems of poor workability of concrete and fast slump loss, and achieve the effect of good rust inhibitor effect.

Active Publication Date: 2020-07-31
广西科达新材料集团有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The purpose of the present invention is to provide a concrete rust inhibitor to solve the technical problems that the rust inhibitor has poor workability to concrete and the slump loss of concrete is fast after the rust inhibitor is added in the prior art.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] A concrete rust inhibitor, in mass percent, is composed of the following components: 45% sodium nitrite, 45% benzotriazole, 5% tetrakis hydroxymethyl phosphorus sulfate, 10% polycarboxylate superplasticizer , rosin thermal polymer air-entraining agent 0.05%, pentasodium phosphate 6%, and the balance is sodium monofluorophosphate.

[0025] Described concrete rust inhibitor, preparation method comprises the following steps:

[0026] S1: Mix sodium nitrite, benzotriazole and water, heat up to 235°C, add rosin thermopolymer air-entraining agent and pentasodium phosphate, stir evenly and keep the temperature for 3 hours, cool to room temperature, and obtain solution A;

[0027] S2: Add tetrakis hydroxymethyl phosphine sulfate, polycarboxylate superplasticizer, and sodium monofluorophosphate to solution A, stir and dissolve, and leave the solution for 40 minutes to obtain concrete rust inhibitor.

[0028] The amount of water added is 350% of the mixed mass of sodium nitrite ...

Embodiment 2

[0030] A concrete rust inhibitor, in mass percentage, is composed of the following components: 30% sodium nitrite, 30% benzotriazole, 3% tetrakis hydroxymethyl phosphorus sulfate, 5% polycarboxylate superplasticizer , rosin thermal polymer air-entraining agent 0.02%, pentasodium phosphate 2%, and the balance is calcium monofluorophosphate.

[0031] Described concrete rust inhibitor, preparation method comprises the following steps:

[0032] S1: Mix sodium nitrite, benzotriazole and water, heat up to 25°C, add rosin thermopolymer air-entraining agent and pentasodium phosphate, stir evenly and keep the temperature for 1 hour, cool to room temperature, and obtain solution A;

[0033] S2: Add tetrakis hydroxymethyl phosphine sulfate, polycarboxylate superplasticizer, and sodium monofluorophosphate to solution A, stir and dissolve, and leave the solution for 15 minutes to obtain a concrete rust inhibitor.

[0034] The amount of water added is 200% of the mixed mass of sodium nitri...

Embodiment 3

[0036] A concrete rust inhibitor, in mass percentage, is composed of the following components: 38% sodium nitrite, 38% benzotriazole, 3.9% tetrakis hydroxymethyl phosphorus sulfate, 7.2% polycarboxylate superplasticizer , rosin thermal polymer air-entraining agent 0.03%, pentasodium phosphate 4.1%, and the balance is potassium monofluorophosphate.

[0037] Described concrete rust inhibitor, preparation method comprises the following steps:

[0038] S1: Mix sodium nitrite, benzotriazole and water, heat up to 32°C, add rosin thermopolymer air-entraining agent and pentasodium phosphate, stir evenly and keep the temperature for 1.9h, cool to room temperature, and obtain solution A;

[0039] S2: Add tetrakis hydroxymethyl phosphine sulfate, polycarboxylate superplasticizer, and sodium monofluorophosphate to solution A, stir and dissolve, and leave the solution for 33 minutes to obtain a concrete rust inhibitor.

[0040] The amount of water added is 260% of the mass of sodium nitri...

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Abstract

The invention discloses a concrete corrosion inhibitor, and belongs to the field of building materials. The concrete corrosion inhibitor is prepared from the following components in percentage by mass: 30 to 45 percent of a nitrite, 30 to 45 percent of benzotriazole, 3 to 5 percent of tetrakis hydroxymethyl phosphonium sulfate, 5 to 10 percent of polycarboxylate superplasticizer, 0.02 to 0.05 percent of an air entraining agent, 2 to 6 percent of pentasodium phosphate and the balance of sodium monofluorophosphate. The preparation method of the concrete corrosion inhibitor comprises the following steps: mixing sodium nitrite, benzotriazole and water, heating to 25-35 DEG C, adding the air entraining agent and pentasodium phosphate, uniformly stirring, keeping the temperature for 1-3 hours, cooling to room temperature, adding tetrakis (hydroxymethyl) phosphonium sulfate, the polycarboxylate superplasticizer and sodium monofluorophosphate, stirring, dissolving, and standing a solution for15-40 minutes to obtain the concrete corrosion inhibitor. The concrete corrosion inhibitor prepared by the invention can effectively improve the workability of concrete, slow down slump loss and enhance the corrosion inhibition performance, has long corrosion inhibition duration, and is suitable for coastal ports, salt pans and salinized soil areas.

Description

technical field [0001] The invention relates to the field of building materials, in particular to a concrete rust inhibitor. Background technique [0002] Coastal ports, salt pans and saline soil areas usually contain a large amount of sulfate and chloride salts, which have a serious corrosion effect on concrete and steel bars, causing serious damage to reinforced concrete structures in this area, and the expected life of the structure cannot be reached. Therefore, the durability of reinforced concrete structures in the above-mentioned erosion areas has become a worldwide concern. [0003] Existing traditional methods use sulfate-resistant cement, or mix a certain amount of mineral admixtures in concrete. Sulfate-resistant cement, however, is in limited supply and expensive. More importantly, sulfate-resistant cement has poor ability to prevent corrosion of steel bars caused by chloride salts, which seriously affects the durability of reinforced concrete structures in erod...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B24/34C04B103/61
CPCC04B40/0039C04B2103/61C04B22/085C04B24/129C04B24/003C04B22/16C04B24/34C04B2103/302
Inventor 周武
Owner 广西科达新材料集团有限公司
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