The invention discloses a
cerium ion coordinated terpyridyl anticorrosive
flame-retardant difunctional filler as well as a preparation method and application thereof. The
structural formula of the
cerium ion coordinated terpyridyl anticorrosive
flame-retardant difunctional filler is # imgabs0. The
corrosion-resistant
flame-retardant EP material has
corrosion-resistant and flame-retardant dual-functional characteristics, and the
toughness of EP is improved by using a
siloxane skeleton structure as a connecting agent; dOPO contains
phosphorus, a
phosphorus compound can be decomposed at high temperature to generate
phosphorus oxides, the oxides can form a protective layer in flame, interaction between
oxygen and combustible materials is reduced, and
combustion reaction is slowed down or inhibited;
pyridine can adsorb
metal ions in a corrosive environment, so that an anti-
corrosion effect is achieved; meanwhile, N atoms on a
pyridine ring can generate N2 in the
combustion process, so that the concentration of
oxygen in the gas can be reduced, and an important role is played in the
intumescent flame retardant process; ce < 3 + > and
pyridine are coordinated to form a coordination compound, a compact adsorption film is formed on the surface of a matrix, and corrosion protection is provided; meanwhile, various micromolecular monomers can be combined to form a long-chain chelate, so that the performance of the filler is further improved.