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Method for precipitating nickel with alkaline step by step

A technology of alkali precipitation and lye solution, applied in the field of metallurgy, can solve problems such as increasing the water treatment capacity, and achieve the effects of speeding up the reaction speed, improving the utilization rate and high efficiency

Active Publication Date: 2020-07-31
河北中科同创道格赛尔新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] In CN201410025042.0, although slurry with good sedimentation and filtration performance can also be obtained, the precipitant uses 0.7-1.4% sodium hydroxide solution, which will inevitably increase the water treatment capacity significantly

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0015] Under stirring, 20% sodium hydroxide was continuously pumped into the nickel-containing solution, the reaction temperature was 10℃, the reaction time was 30 minutes, and the pH of the nickel-containing solution was adjusted to 5.5; further, under stirring, 10 % Sodium bicarbonate was continuously pumped into the above-mentioned nickel-containing solution with pH adjusted once, the reaction temperature was 30℃, the reaction time was 30 minutes, and the pH of the nickel-containing solution was adjusted to 6.5; further, under stirring, 10 % Sodium carbonate is continuously pumped into the above-mentioned nickel-containing solution with secondary pH adjustment, the reaction temperature is 30℃, the reaction time is 30 minutes, and the pH of the nickel-containing solution is adjusted to 7.5; finally, under stirring, the 5% The sodium hydroxide of the sodium hydroxide was continuously pumped into the above-mentioned nickel-containing solution whose pH was adjusted three times, t...

Embodiment 2

[0017] Under stirring, 50% potassium hydroxide was continuously pumped into the nickel-containing solution, the reaction temperature was 80°C, the reaction time was 30 minutes, and the pH of the nickel-containing solution was adjusted to 5.5; further, under stirring, 30 % Potassium bicarbonate was continuously pumped into the above-mentioned nickel-containing solution with pH adjusted once, the reaction temperature was 30℃, the reaction time was 30 minutes, and the pH of the nickel-containing solution was adjusted to 6.5; further, under stirring, 1 % Potassium carbonate was continuously pumped into the above-mentioned nickel-containing solution with secondary pH adjustment, the reaction temperature was 30℃, the reaction time was 30 minutes, and the pH of the nickel-containing solution was adjusted to 7.2; finally, under stirring, the continuous pump The pH of the nickel-containing solution is adjusted to 8.2 by adding it into the above-mentioned nickel-containing solution whose ...

Embodiment 3

[0019] Under stirring, 5% ammonium hydroxide was continuously pumped into the nickel-containing solution, the reaction temperature was 30°C, the reaction time was 30 minutes, and the pH of the nickel-containing solution was adjusted to 6.0; further, under stirring, 1 % Ammonium bicarbonate was continuously pumped into the above-mentioned nickel-containing solution with the pH adjusted once, the reaction temperature was 30°C, the reaction time was 30 minutes, and the pH of the nickel-containing solution was adjusted to 6.5; further, under stirring, 30 % Ammonium carbonate was continuously pumped into the above-mentioned nickel-containing solution with secondary pH adjustment, the reaction temperature was 40℃, the reaction time was 30 minutes, and the pH of the nickel-containing solution was adjusted to 7.0; finally, under stirring, 10% The ammonium hydroxide was continuously pumped into the above-mentioned nickel-containing solution whose pH was adjusted three times, the reaction...

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PUM

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Abstract

The invention discloses a method for precipitating nickel with alkaline step by step. The method comprises the following step of mixing nickel-containing solution with different alkali liquid to be subjected to step-by-step nickel precipitation treatment so as to obtain nickel product precipitation with high sedimentation separation and filtration performance. The process has the characteristics of being short in process, short in time, high in efficiency and low in cost and the like.

Description

Technical field [0001] The present invention belongs to the technical field of metallurgy. Specifically, the present invention relates to a method for stepwise alkali precipitation of nickel. Background technique [0002] At present, the main precipitation agents for recovering nickel from laterite ore acid leaching solution are sodium hydroxide, calcium oxide, magnesium oxide, sulfide, etc. The precipitation principle of sodium hydroxide is simple, the operation is simple, and the raw materials of the precipitation agent are easy to purchase. It is more commonly used as a nickel sink. However, due to its strong alkalinity, if the concentration is high during the actual industrial operation, it is easy to form a local alkali excess, which will lead to problems such as small precipitation particle size, sedimentation, and poor filtration performance, which increases the processing time and reduces production efficiency; If the alkali concentration is low, the volume of the lye co...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22B3/44C22B23/00
CPCC22B3/44C22B23/0461Y02P10/20
Inventor 曲景奎余志辉沈晓博吕彩霞
Owner 河北中科同创道格赛尔新材料科技有限公司