A dyeing composition for short-process dyeing
A composition and yellow technology, applied in the field of dyeing compositions for short-process dyeing, can solve the problems of poor color fastness, insufficient alkali resistance, insufficient oxidation resistance and stability, etc.
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[0042] Add 4.9 g of 2,4-diaminotoluene, 7.4 g of 2,4-dinitrofluorobenzene, 20 g of N,N-diisopropylethylamine and 120 mL of absolute ethanol into a three-necked flask, and heat to reflux for 24 hours. After the reaction, cool to room temperature, filter; wash with distilled water for 3 times, and dry to obtain 10.6 g of orange-yellow solid (the yield of this step is 92%), that is, the compound of formula (II-1).
[0043]
[0044] Add the compound of formula (II-1) and appropriate amount of water into another three-necked flask, and stir at room temperature for 1 h. Add ice to cool down to 0-5°C, add 14.3g of 30wt% hydrochloric acid under heat preservation conditions, and stir well for 2h. At 0-5°C, 12.1 g of a 25 wt % sodium nitrite solution was continuously added dropwise, and after the dropwise addition was completed, the mixture was incubated for 4 hours. Add sulfamic acid to remove excess sodium nitrite, use starch potassium iodide test paper to detect that it does not ...
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