Preparation method of biomass water treatment environment functional material

A technology of biomass materials and functional materials, which is applied in the field of preparation of environmental functional materials for biomass water treatment, can solve the problems of low mechanical strength of biomass activated carbon, uneven distribution of magnetic particles, high carbon wear rate, etc., and achieve good recyclability Good stability, uniform distribution, and low carbon loss

Inactive Publication Date: 2020-08-18
HENAN NORMAL UNIV
View PDF3 Cites 2 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] At present, the magnetic modification of biomass activated carbon is mainly through compounding magnetic particles and magnetic fluids with activated carbon, but the distribution of magnetic particles in activated carbon is not uniform, and the problem of low mechanical strength of biomass activated carbon itself, in the process of water flow , the carbon wear rate is high, and the tiny carbon debris will be suspended in the treated water body with the fluid through the filter device, causing secondary pollution. The detached debris is often not loaded with magnetic particles, so it cannot be recovered by applying a magnetic field.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] A preparation method of a biomass water treatment environmental functional material provided in this embodiment comprises the following steps:

[0023] S1. Pulverize the grapefruit peel, immerse in the mixed solution of iron salt solution and zirconium salt solution, and perform ultrasonic treatment. The power of ultrasonic treatment is 0.9kW / m 3 , the frequency is 150kHz, after soaking for 5h, filter to obtain pretreated biomass material;

[0024] Wherein, iron salt solution is 0.5mol / L ferric chloride, and zirconium salt solution solution is 0.5mol / L zirconium nitrate, and described mixed solution is by volume ratio 2: 0.5 mixed.

[0025] S2. Add NaOH solution to the pretreated biomass material. The amount of NaOH solution added is 3 times the volume of the pretreated biomass material. It is shaken every 15 minutes. After soaking for 60 minutes, centrifuge, wash, and dry. The drying temperature is 100°C, and control the moisture content to 10%;

[0026] S3, compres...

Embodiment 2

[0028] A preparation method of a biomass water treatment environmental functional material provided in this embodiment comprises the following steps:

[0029] S1. Crush the coconut shell, immerse in the mixed solution of iron salt solution and zirconium salt solution, and perform ultrasonic treatment. The power of ultrasonic treatment is 0.9kW / m 3 , the frequency is 150kHz, after fully impregnated, filtered to obtain pretreated biomass material;

[0030] Wherein, iron salt solution is 0.5mol / L ferric chloride, and zirconium salt solution solution is 0.5mol / L zirconium nitrate, and described mixed solution is by volume ratio 2: 0.5 mixed

[0031] S2. Add NaOH solution to the pretreated biomass material. The amount of NaOH solution added is 3 times the volume of the pretreated biomass material, shake once every 20min, soak for 120min, centrifuge, wash, dry, and the drying temperature is 100°C, and control the moisture content to 15%;

[0032] S3, compress the material after d...

Embodiment 3

[0035] A preparation method of a biomass water treatment environmental functional material provided in this embodiment comprises the following steps:

[0036] S1. Pulverize the grapefruit peel, immerse in the mixed solution of iron salt solution and zirconium salt solution, and perform ultrasonic treatment. The power of ultrasonic treatment is 0.9kW / m 3 , the frequency is 150kHz, after fully impregnated, filtered to obtain pretreated biomass material;

[0037] Wherein, iron salt solution is 0.5mol / L ferric chloride, and zirconium salt solution solution is 0.5mol / L zirconium nitrate, and described mixed solution is by volume ratio 2: 0.5 mixed.

[0038] S2, add NaOH solution to the pretreated biomass material, the addition of NaOH solution is 4 times the volume of the pretreated biomass material, shake once every 20min, after soaking for 120min, centrifuge, wash, dry, and the drying temperature is 100°C, and control the moisture content to 10%;

[0039] S3, compress the mate...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
Particle sizeaaaaaaaaaa
Particle sizeaaaaaaaaaa
Login to view more

Abstract

The invention discloses a preparation method of a biomass water treatment environment functional material, and belongs to the technical field of water treatment materials. The preparation method comprises the following steps: crushing a biomass material, dipping the crushed biomass material in a mixed solution formed by mixing an iron salt solution and a zirconium salt solution, carrying out ultrasonic treatment, and completely impregnating and filtering the mixture to obtain a pretreated biomass material; adding a NaOH solution into the pretreated biomass material, wherein the adding amount of the NaOH solution is 3-4 times the volume of the pretreated biomass material, performing vibration once every 10-20 min, soaking the material for 60-120 min, carrying out centrifuging, cleaning anddrying treatment until the water content is controlled to be 8%-15%; and S3, compressing the material dried in the step S2 into spheres with the density of 0.8-1.5 g / cm3, putting the spheres into a high-temperature carbonization furnace, introducing argon for protection, heating the material to 450-800 DEG C at the speed of 5-10 DEG C / min, carrying out heat preservation carbonization for 2-3 hours, and naturally cooling the product to room temperature to obtain the spherical biomass-based magnetic activated carbon. The preparation method is simple in process and low in energy consumption, andthe prepared charcoal-based magnetic activator has good recoverability and stability.

Description

technical field [0001] The invention relates to the technical field of water treatment materials, in particular to a preparation method of biomass water treatment environmental functional materials. Background technique [0002] Biomass refers to various organisms produced through photosynthesis using the atmosphere, water, land, etc., that is, all living organic substances that can grow are collectively referred to as biomass. It includes plants, animals and microorganisms. Biomass is a renewable resource with a huge amount and a wide variety. The common ones are woody and herbaceous plants, such as agricultural processing residues, forestry processing residues, aquatic plants, energy plants, etc. Most biomass is rich in carbon elements , is a cheap raw material for the preparation of various carbon materials. [0003] Biomass is pyrolyzed at high temperature under anoxic conditions to form biochar, which has good adsorption and catalytic properties. Biomass activated car...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
IPC IPC(8): C02F1/00C02F1/28C02F1/48B01J20/20B01J20/28B01J20/30B01J20/32
CPCB01J20/20B01J20/28009B01J20/3078B01J20/3214B01J20/3236B01J2220/485B01J2220/4881C02F1/00C02F1/288C02F1/488
Inventor 黎想黎鹏贾炎秦杨
Owner HENAN NORMAL UNIV
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products