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Method for treating chemical nickel plating waste liquid through iron-based catalyst

An electroless nickel plating and catalyst technology, which is applied in chemical instruments and methods, physical/chemical process catalysts, precipitation treatment, etc., can solve the problems of complex process and high cost, and achieve the effect of simple process, low operating cost and convenient waste residue treatment

Active Publication Date: 2020-08-25
SOUTH CHINA INST OF ENVIRONMENTAL SCI MEP +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In the prior art, the treatment process of electroless nickel plating waste liquid has the problems of complicated process and high cost

Method used

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  • Method for treating chemical nickel plating waste liquid through iron-based catalyst
  • Method for treating chemical nickel plating waste liquid through iron-based catalyst

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] Embodiment 1: a kind of method of processing electroless nickel plating waste liquid by iron series catalyst, specifically comprises:

[0030] Step 1: Preparation of carrier

[0031] a. Separately crush diatomite, fly ash, perlite, phyllite, and biological straw, and pass through a 200-mesh sieve; wherein, the biological straw is specifically rice straw;

[0032] b. According to parts by weight, 45 parts of diatomite, 20 parts of fly ash, 15 parts of perlite, 13 parts of phyllite, and 8 parts of biological straw are put into the mixing equipment to obtain mixed raw materials, and then add the volume of mixed raw materials The ratio of 1:5 deionized water is fully stirred to obtain the mixed aggregate;

[0033] c. Then the mixed aggregate is aged for 30 hours; the specific aging steps are: control the temperature at 35°C, control the ventilation rate at 15L / min, and pass air into it for oxidation for 3h; control the temperature at 30°C, and age for 5h; then control Agi...

Embodiment 2

[0040] Embodiment 2: different from embodiment 1: a kind of method of processing electroless nickel plating waste liquid by iron series catalyst, specifically comprises:

[0041] Step 1: Preparation of carrier

[0042] a. Diatomite, fly ash, perlite, phyllite, and biological straw are respectively crushed and passed through a 200-mesh sieve; wherein, the biological straw is specifically wheat straw;

[0043] b. According to parts by weight, 50 parts of diatomite, 25 parts of fly ash, 20 parts of perlite, 18 parts of phyllite, and 11 parts of biological straw are put into the mixing equipment to obtain mixed raw materials, and then add the volume of mixed raw materials The deionized water with a ratio of 1:7 is fully stirred to obtain the mixed aggregate;

[0044] c. Then, the mixed aggregate is aged for 30 hours; the specific aging steps are: control the temperature at 40°C, control the ventilation rate at 16L / min and pass air in for oxidation for 3h; control the temperature ...

Embodiment 3

[0051] Embodiment 3: different from embodiment 1: a kind of method of processing electroless nickel plating waste liquid by iron series catalyst, specifically comprises:

[0052] Step 1: Preparation of carrier

[0053] a. Diatomite, fly ash, perlite, phyllite, and biological straw are respectively crushed and passed through a 200-mesh sieve; wherein, the biological straw is specifically corn stalk;

[0054] b. According to parts by weight, 60 parts of diatomite, 30 parts of fly ash, 25 parts of perlite, 20 parts of phyllite, and 12 parts of biological straw are put into the mixing equipment to obtain mixed raw materials, and then add the volume of mixed raw materials The deionized water with a ratio of 1:8 is fully stirred to obtain the mixed aggregate;

[0055] c. Then, the mixed aggregate is aged for 36 hours; the specific aging steps are: control the temperature at 45°C, control the ventilation rate at 18L / min and pass air into it for oxidation for 3h; control the temperat...

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Abstract

The invention provides a method for treating chemical nickel plating waste liquid through an iron-based catalyst. The method specifically comprises the following steps: (1) preparation of a carrier: mixing diatomite, fly ash, perlite, phyllite and biological straw to prepare ceramsite sand for later use; (2) preparation of an iron-based catalyst: mixing and reacting macromolecular polymeric ferricsalt with an alkaline aqueous solution, then carrying out magnetization treatment, then loading on ceramsite sand in a spraying manner, and drying to obtain the iron-based catalyst; (3) chemical nickel plating waste liquid treatment: adding CaO, an iron-based catalyst, NaOH and a polymeric flocculant into the chemical nickel plating waste liquid for treatment, and then discharging the chemical nickel plating waste liquid; the method has the advantages of simple process and low operation cost in the aspect of treating the nickel plating waste liquid.

Description

technical field [0001] The invention relates to the technical field of waste liquid treatment, in particular to a method for treating waste liquid of electroless nickel plating with an iron-based catalyst. Background technique [0002] Electroless plating, also known as electroless plating, is a new type of metal surface treatment technology. This technology has attracted increasing attention because of its simple process, energy saving and environmental protection. Electroless plating is used in a wide range, and the gold plating layer is uniform and decorative. In terms of protection performance, it can improve the corrosion resistance and service life of the product; in terms of functionality, it can improve the wear resistance, electrical conductivity, lubrication performance and other special functions of the workpiece, so it has become a development of surface treatment technology in the world. The real discovery of electroless nickel plating technology and its applic...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F9/04B01J23/745C02F101/20C02F103/16
CPCC02F9/00B01J23/745C02F2103/16C02F1/66C02F1/62C02F1/56C02F2001/007C02F2101/20Y02W10/37
Inventor 杜建伟贺框黄宁唐娜雷伟香石杰胡小英张明杨李铭珊关伟
Owner SOUTH CHINA INST OF ENVIRONMENTAL SCI MEP