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Water-controlling and scale-inhibiting coated proppant and preparation method thereof

A technology of proppant and water control agent, which is applied in the direction of chemical instruments and methods, earthwork drilling, drilling composition, etc., which can solve the problems of easy to be flattened, low long-term conductivity of filled cracks, and the function of film-coated proppant A single problem, to achieve the effect of reducing the degree of reduction

Inactive Publication Date: 2020-09-04
SOUTHWEST PETROLEUM UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

For example, in order to ensure the compressive strength of the membrane proppant, it is necessary to ensure the content of resin in the coating layer, thus reducing the content of other functional additives, making the function of the membrane proppant relatively single
On the other hand, although the existing film-coated proppant has better compressive strength than the traditional proppant, it is easy to be crushed under the action of long-term closure pressure, so that the long-term conductivity of the fracture filling is also limited to a certain extent. reduction of

Method used

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  • Water-controlling and scale-inhibiting coated proppant and preparation method thereof
  • Water-controlling and scale-inhibiting coated proppant and preparation method thereof
  • Water-controlling and scale-inhibiting coated proppant and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] The preparation process of a film-coated proppant for controlling water and scaling is as follows:

[0030] (1) Weigh 30 / 50 purpose porous proppant (bulk density 1.15g / cm 3 , apparent density 2.07g / cm 3 ) 2100g, phenolic resin 360g, triethylenetetramine 120g, dibutyl phthalate 120g, vinyl chloropropyl triethoxysilane 180g, aminotrimethylene phosphonic acid 60g, polyacrylamide 60g;

[0031] (2) dissolving aminotrimethylene phosphonic acid in water to form a solution, soaking a 30 / 50 mesh porous proppant therein for 36 hours and then drying;

[0032] (3) Polyacrylamide is dissolved in 420g of absolute ethanol to form a pore-forming solution;

[0033] (4) Heat the phenolic resin to a molten state at 250° C., add triethylenetetramine, dibutyl phthalate, and vinyl chloride propyl triethoxysilane, and stir evenly to form a resin mixture;

[0034] (5) The porous proppant after drying is blown into the fluidized bed by air to form a fluidized bed;

[0035] (5) Spray the por...

Embodiment 2

[0038] The preparation process of a film-coated proppant for controlling water and scaling is as follows:

[0039] (1) Weigh 30 / 50 purpose porous proppant (bulk density 1.15g / cm 3 , apparent density 2.07g / cm 3 ) 1860g, phenolic resin 450g, triethylenetetramine 150g, dibutyl phthalate 150g, vinyl chloropropyl triethoxysilane 210g, aminotrimethylene phosphonic acid 90g, polyacrylamide 90g;

[0040] (2) dissolving aminotrimethylene phosphonic acid in water to form a solution, soaking a 30 / 50 mesh porous proppant therein for 36 hours and then drying;

[0041] (3) Polyacrylamide is dissolved in 630g of absolute ethanol to form a pore-forming solution;

[0042] (4) Heat the phenolic resin to a molten state at 250° C., add triethylenetetramine, dibutyl phthalate, and vinyl chloride propyl triethoxysilane, and stir evenly to form a resin mixture;

[0043] (5) The porous proppant after drying is blown into the fluidized bed by air to form a fluidized bed;

[0044] (5) Spray the por...

Embodiment 3

[0047] The preparation process of a film-coated proppant for controlling water and scaling is as follows:

[0048] (1) Weigh 30 / 50 purpose porous proppant (bulk density 1.15g / cm 3 , apparent density 2.07g / cm 3 ) 2100g, epoxy resin 360g, tetraethylenepentamine 120g, dimethyl phthalate 120g, aminopropylmethyldimethoxysilane 180g, diethylenetriaminepentamethylenephosphonic acid 60g, polyepoxy Ethane 60g;

[0049] (2) Diethylenetriaminepentamethylenephosphonic acid is dissolved in water to form a solution, and a 30 / 50 mesh porous proppant is soaked in it for 36h and then dried;

[0050] (3) dissolving polyethylene oxide in 420g absolute ethanol to form a pore-forming solution;

[0051] (4) Heat the phenolic resin to a molten state at 250° C., add tetraethylenepentamine, dimethyl phthalate, and aminopropylmethyldimethoxysilane, and stir to form a resin mixture;

[0052] (5) The porous proppant after drying is blown into the fluidized bed by air to form a fluidized bed;

[0053] ...

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Abstract

The invention discloses a water-controlling and scale-inhibiting coated proppant and a preparation method thereof. The water-controlling and scale-inhibiting coated proppant is prepared from the following components in percentage by mass: 60 to 80% of an aggregate, 5 to 15% of resin, 1 to 5% of a curing agent, 1 to 5% of a plasticizer, 4 to 8% of a water-controlling agent, 1 to 3% of a scale inhibitor and 1 to 3% of a pore-forming agent. The water-controlling and scale-inhibiting coated proppant is relatively low in density and easy for fracturing construction; the water control agent in the coating layer is oleophylic and hydrophobic, so that the purposes of controlling water and increasing oil can be achieved; the scale inhibitor in the water-controlling and scale-inhibiting coated proppant can play a role in formation water production to prevent formation of inorganic scale; in the later period of production, a pore throat structure in the coated porous proppant can provide a flowing channel for formation fluid, and the reduction degree of long-term flow conductivity of a filling crack under the action of closing pressure can be effectively reduced; meanwhile, the coated proppant also has a sand prevention function.

Description

technical field [0001] The invention relates to the technical field of oil and gas field development, in particular to a film-coated proppant for controlling water and scale and a preparation method thereof. Background technique [0002] In the field of oil and gas field development, the stimulation method of fracturing is often used for low-permeability and ultra-low-permeability reservoirs, that is, the high-pressure pump set is used to squeeze the fracturing fluid into the formation with a displacement exceeding the limit fluid absorption speed of the formation. Artificial fractures are formed and filled with proppant to form a channel with high conductivity for oil and gas entering the well. [0003] At present, the widely used proppants are quartz sand and ceramsite. Although the two have wide sources and low cost, their density is high, and they are easy to cause sand plugging during fracturing construction, which brings a series of construction problems. On the other...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K8/80
CPCC09K8/805
Inventor 罗志锋吴林赵立强张楠林杨磊姚志广贾宇成邓艺平
Owner SOUTHWEST PETROLEUM UNIV
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