Viscosity-adjustable thermosetting artificial board starch adhesive and preparation method thereof
A starch adhesive and wood-based panel technology, applied in adhesives, grafted polymer adhesives, manufacturing tools, etc., can solve the problems of unstable reaction system, high viscosity of adhesives, uneven reaction, etc., to reduce homopolymerization rate, Effect of improving thermosetting properties and expanding market application fields
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Embodiment 1
[0045] Formula (mass / g):
[0046]
[0047] Process flow:
[0048] (1) Starch and water are made into starch milk with a mass ratio of 30% on a dry basis of starch, and stirred evenly;
[0049] (2) Adjust the temperature of starch milk to 60°C at a rate of 2°C / min, dilute 8.6g of 12mol / L concentrated hydrochloric acid solution to 0.5mol / L, add it to starch milk for acid hydrolysis, acid hydrolysis for 1.5h, and then add 10mol / L sodium hydroxide solution to adjust the pH to 4;
[0050] (3) Adjust the temperature of the acid-hydrolyzed starch milk to 75°C at a rate of 1°C / min, and pregelatinize for 20 minutes;
[0051] (4) get 0.51g initiator and be dissolved in 40g water and make initiator solution, get and account for initiator solution gross mass 15% initiator solution and emulsifier and grafting monomer mix, make seed emulsion, step (3) After cooling the system to 70°C, drop the seed emulsion into the reaction system after pregelatinization in step (3) within 10 minutes...
Embodiment 2
[0057] Formula (mass / g):
[0058]
[0059]
[0060] Process flow:
[0061] (1) Starch and water are made into starch milk with a mass ratio of 30% on a dry basis of starch, and stirred evenly;
[0062] (2) Adjust the temperature of the starch milk to 60°C, dilute 8.6g of 12mol / L concentrated hydrochloric acid solution to 0.5mol / L, add it to the starch milk for acid hydrolysis, acid hydrolyze for 1.5h, and then add 10mol / L sodium hydroxide solution Adjust the pH to 4;
[0063] (3) Adjust the temperature of the acid-hydrolyzed starch milk to 85°C at a rate of 1°C / min, and pregelatinize for 20 minutes;
[0064] (4) get 0.51g initiator to be dissolved in 40g water and make initiator solution, get and account for initiator solution gross mass 10% initiator solution and emulsifier and grafting monomer mix, make seed emulsion, wait for step (3 ) system was cooled to 70°C, within 10 minutes, the seed emulsion was added to the reaction system after pregelatinization in step (3...
Embodiment 3
[0070] Formula (mass / g):
[0071]
[0072]
[0073] Process flow:
[0074] (1) Starch and water are made into starch milk with a mass ratio of 30% on a dry basis of starch, and stirred evenly;
[0075] (2) Adjust the temperature of starch milk to 60°C at a rate of 2°C / min, dilute 8.6g of 12mol / L concentrated hydrochloric acid solution to 0.5mol / L, add it to starch milk for acid hydrolysis, acid hydrolysis for 1.5h, and then add 10mol / L sodium hydroxide solution to adjust the pH to 4;
[0076] (3) Adjust the temperature of the acid-hydrolyzed starch milk to 90°C at a rate of 1°C / min, and pregelatinize for 20 minutes;
[0077] (4) get 0.51g initiator and be dissolved in 40g water and make initiator solution, get and account for initiator solution gross mass 15% initiator solution and emulsifier and grafting monomer mix, make seed emulsion, step (3) After cooling the system to 70°C, drop the seed emulsion into the reaction system after pregelatinization in step (3) withi...
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