co 2 Iron-based catalyst, preparation method and application of hydrogenation ethanol
An iron-based catalyst and ethanol production technology, which is applied in the direction of catalyst activation/preparation, hydroxyl compound preparation, metal/metal oxide/metal hydroxide catalyst, etc., can solve the problems of low ethanol selectivity and large output, and achieve Efficient conversion of CO2, the effect of relieving environmental pressure
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Embodiment 1
[0038] a CO 2 The preparation method of the iron-based catalyst of hydrogenation ethanol, comprises the steps:
[0039] 1) dissolving the auxiliary salt lithium citrate into solvent water to obtain an aqueous solution of lithium citrate;
[0040] 2) Lithium citrate aqueous solution impregnated into Fe 3 o 4 On the catalyst powder, after stirring evenly, dry at 120°C for 12 hours to obtain the catalyst;
[0041] 3) The catalyst is compressed at 10MPa, and then granulated to 20-40 mesh to obtain the catalyst;
[0042] 4) Load 0.5 g of catalyst, and first reduce it with synthesis gas. The specific reduction conditions are 300°C and the gas velocity is 4500h -1 (V / V), the reduction time is 10 h, and after the reduction is completed, the catalyst is lowered to room temperature with nitrogen to obtain the product. Fe in the product 5 C 2 / Fe 2 C / Fe 3 The ratio of C is finally adjusted to 20 / 8 / 4.
[0043] Efficient catalytic conversion of CO 2 Experimental conditions: fixe...
Embodiment 2
[0046] a CO 2 The preparation method of the iron-based catalyst of hydrogenation ethanol, comprises the steps:
[0047] 1) dissolving the auxiliary salt trisodium citrate into solvent water to obtain an aqueous solution of trisodium citrate;
[0048] 2) Immerse trisodium citrate aqueous solution into Fe 3 o 4 On the catalyst powder, after stirring evenly, dry at 120°C for 12 hours to obtain the catalyst;
[0049] 3) The catalyst is compressed at 10MPa, and then granulated to 20-40 mesh to obtain the catalyst;
[0050] 4) Load 0.5 g of catalyst, and first reduce it with synthesis gas. The specific reduction conditions are 300°C and the gas velocity is 4500h -1 (V / V), the reduction time is 10 h, and after the reduction is completed, the catalyst is lowered to room temperature with nitrogen to obtain the product.
[0051] Efficient catalytic conversion of CO 2 Experimental conditions: fixed bed reactor, temperature 300°C, pressure 3MPa, mixed gas H 2 / CO 2 =3, gas velocit...
Embodiment 3
[0055] a CO 2 The preparation method of the iron-based catalyst of hydrogenation ethanol, comprises the steps:
[0056] 1) dissolving the auxiliary salt tripotassium citrate into solvent water to obtain tripotassium citrate aqueous solution;
[0057] 2) Immerse tripotassium citrate aqueous solution into Fe 3 o 4 On the catalyst powder, after stirring evenly, dry at 120°C for 12 hours to obtain the catalyst;
[0058] 3) The catalyst is compressed at 10MPa, and then granulated to 20-40 mesh to obtain the catalyst;
[0059] 4) Load 0.5 g of catalyst, and first reduce it with synthesis gas. The specific reduction conditions are 300°C and the gas velocity is 4500h -1 (V / V), the reduction time is 10 h, and after the reduction is completed, the catalyst is lowered to room temperature with nitrogen to obtain the product.
[0060] Efficient catalytic conversion of CO 2 Experimental conditions: fixed bed reactor, temperature 300°C, pressure 3MPa, mixed gas H 2 / CO 2 =3, gas velo...
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