Metal-supported catalyst, metal-supported catalyst storage method, and alcohol manufacturing method
A technology for supporting metals and manufacturing methods, which is applied in catalyst activation/preparation, metal/metal oxide/metal hydroxide catalysts, organic chemical methods, etc. Treatment and other problems to achieve high activity and selectivity
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Image
Examples
Embodiment 1
[0269] Using a 1 mm cylindrical activated carbon (R1EXTRA manufactured by NORIT Corporation) carrier as a carrier, by the method based on Example 4 of Japanese Patent Laid-Open No. 2001-9277, using ruthenium chloride hydrate, chloroplatinic acid (IV) 6 hydrate material, tin (II) chloride dihydrate, and ruthenium, platinum, and tin were supported on activated carbon to prepare a supported metal product (hereinafter referred to as supported metal product 1). In the method for preparing the supported metal substance 1, the dissolved water of the metal chloride is the same as the pore capacity of the activated carbon used. Regarding the feed amount of the metal chloride, when the feed amount is fully loaded, hydrogen is reduced, and oxidation is stabilized, the content in the supported metal catalyst is 6 mass % of Ru, 3 mass % of Pt, and 7 mass % of Sn. In addition, the amount of ammonium bicarbonate used was 2 times the molar amount of the chlorine element of the metal chloride,...
Embodiment 2
[0279] 297 g of the middle part recovered in Example 1 was oxidatively stabilized under the same conditions as in Example 1 to obtain a 6.2% by mass Ru-3.0% by mass Pt-7.1% by mass Sn / activated carbon supported catalyst. In addition, the chlorine element content in the obtained catalyst was 0.06% by mass. During the oxidation stabilization operation, the temperature inside the catalyst is 60° C. or lower.
[0280] The catalyst is analyzed by the same method as in Example 1. In the powder X-ray diffraction analysis, the half-width of the broad peak at 2θ=43° is 3.36°, and the oxygen absorption is 0.57mmol oxygen / g-catalyst, oxidation The rate is 42%.
[0281] The reactivity of the obtained catalyst was confirmed by the method described above.
[0282] In addition, for the supported metal substance 1 prepared in Example 1, the reference activity was measured by the above-mentioned , and the percentage of catalyst activity relative to the reference activity was calculated. The...
Embodiment 3
[0284] 139 g of the rear portion recovered in Example 1 was oxidatively stabilized under the same conditions as in Example 1, except that the oxidation stabilization time was 73 minutes, to obtain 6.2% by mass Ru-3.0% by mass Pt-7.3% by mass %Sn / activated carbon supported catalyst. In addition, the chlorine element content in the obtained catalyst was 0.07% by mass. During the oxidation stabilization operation, the temperature inside the catalyst is 60° C. or lower.
[0285] The catalyst is analyzed by the same method as in Example 1. In the powder X-ray diffraction analysis, the half-width of the broad peak at 2θ=43° is 3.19°, and the oxygen absorption is 0.62mmol oxygen / g-catalyst, oxidation The rate is 45%.
[0286] The reactivity of the obtained catalyst was confirmed by the method described above.
[0287] In addition, for the supported metal substance 1 prepared in Example 1, the reference activity was measured by the above-mentioned , and the percentage of catalyst a...
PUM
| Property | Measurement | Unit |
|---|---|---|
| particle size | aaaaa | aaaaa |
| particle diameter | aaaaa | aaaaa |
| particle diameter | aaaaa | aaaaa |
Abstract
Description
Claims
Application Information
Login to View More