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TiO2 scattering film material subjected to polymer planarization treatment and preparation method and application of TiO2 scattering film material

A polymer, planarization technology, used in semiconductor/solid-state device manufacturing, electrical components, electrical solid-state devices, etc., can solve problems such as device short-circuit, affect device stability, and increase the surface roughness of scattering films to improve performance, The effect of low manufacturing cost and improved light extraction efficiency

Inactive Publication Date: 2020-10-13
NANJING UNIV OF POSTS & TELECOMM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, the introduction of nanoparticles may lead to an increase in the surface roughness of the scattering film, which in turn affects the device stability and even causes a short circuit in the device.

Method used

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  • TiO2 scattering film material subjected to polymer planarization treatment and preparation method and application of TiO2 scattering film material
  • TiO2 scattering film material subjected to polymer planarization treatment and preparation method and application of TiO2 scattering film material
  • TiO2 scattering film material subjected to polymer planarization treatment and preparation method and application of TiO2 scattering film material

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Experimental program
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Effect test

Embodiment 1

[0033] This embodiment prepares the TiO of polymer planarization treatment 2 Scattering thin film material, and apply it to prepare green FOLED.

[0034] Utilize toluene to dissolve polymethyl methacrylate, and the concentration of the prepared polymer solution is 100mg ml -1 , then 200nm TiO 2 The nanoparticles are dispersed in the polymer solution, in which TiO 2 The concentration ratio of nanoparticles is 0.25wt%;

[0035] Choose polyethylene terephthalate as the substrate, ultrasonically treat the substrate in acetone, ethanol, and deionized water for 15 minutes, blow dry with nitrogen, and place it in an oven at 120°C for drying; after cleaning, polyethylene terephthalate A layer of TiO was spin-coated on the surface of the ester substrate 2 Scattering film, set the rotation speed to 2000rpm, spin time to 60s, and then solidify the film at 120°C for 30min, the prepared TiO 2 The thickness of the scattering film is 0.9 μm; then the polymer solution is spin-coated on T...

Embodiment 2

[0037] This embodiment prepares the TiO of polymer planarization treatment 2 Scattering thin film material, and apply it to prepare green FOLED.

[0038]Utilize toluene to dissolve polymethyl methacrylate, and the concentration of the prepared polymer solution is 100mg ml -1 , then 200nm TiO 2 The nanoparticles are dispersed in the polymer solution, in which TiO 2 The concentration ratio of nanoparticles is 0.50wt%;

[0039] Choose polyethylene terephthalate as the substrate, ultrasonically treat the substrate in acetone, ethanol, and deionized water for 15 minutes, blow dry with nitrogen, and place it in an oven at 120°C for drying; after cleaning, polyethylene terephthalate A layer of TiO was spin-coated on the surface of the ester substrate 2 Scattering film, set the rotation speed to 2000rpm, spin time to 60s, and then solidify the film at 120°C for 30min, the prepared TiO 2 The thickness of the scattering film is 0.9 μm; then the polymer solution is spin-coated on Ti...

Embodiment 3

[0041] This embodiment prepares the TiO of polymer planarization treatment 2 Scattering thin film material, and apply it to prepare green FOLED.

[0042] Utilize toluene to dissolve polymethyl methacrylate, and the concentration of the prepared polymer solution is 100mg ml -1 , then 200nm TiO 2 The nanoparticles are dispersed in the polymer solution, in which TiO 2 The concentration ratio of nanoparticles is 0.75wt%;

[0043] Choose polyethylene terephthalate as the substrate, ultrasonically treat the substrate in acetone, ethanol, and deionized water for 15 minutes, blow dry with nitrogen, and place it in an oven at 120°C for drying; after cleaning, polyethylene terephthalate A layer of TiO was spin-coated on the surface of the ester substrate 2 Scattering film, set the rotation speed to 2000rpm, spin time to 60s, and then solidify the film at 120°C for 30min, the prepared TiO 2 The thickness of the scattering film is 0.9 μm; then the polymer solution is spin-coated on T...

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Abstract

The invention discloses a TiO2 scattering film material subjected to polymer planarization treatment and a preparation method and application of the TiO2 scattering film material. The preparation method comprises the following steps: preparing a polymer solution and a TiO2 nanoparticle-polymer solution, preparing a TiO2 scattering film on a substrate by adopting a solution method, and forming a polymer flat layer on the surface of the TiO2 scattering film by adopting the solution method, thereby obtaining the TiO2 scattering film subjected to polymer planarization treatment. The TiO2 scattering film prepared based on the solution method has the advantages of being simple in preparation process, low in cost, easy to produce in a large area, compatible with flexible devices, capable of improving the light extraction efficiency of monochromatic light and white light FOLEDs and the like, and is suitable for being applied to large-area and low-cost FOLEDs.

Description

technical field [0001] The present invention relates to a kind of TiO 2 Scattering thin film and its preparation method and application, especially related to a polymer planarized TiO 2 Scattering thin film and its preparation method and application. Background technique [0002] Flexible organic light-emitting diodes (FOLEDs) have the characteristics of excellent mechanical flexibility, thinness, self-luminescence, and low power consumption. They are a new generation of display technology applied to flexible displays and wearable devices. At present, the internal quantum efficiency (IQE) of OLED devices has reached 100% by using phosphorescent and thermally activated delayed fluorescent luminescent materials. However, a large amount of light loss occurs inside the OLED device, resulting in an external quantum efficiency (EQE) of only 25%. This loss is due to the refractive index mismatch between the materials used in the various layers of the OLED, about 80% of the light ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01L51/52H01L51/56
CPCH10K50/854H10K71/00
Inventor 刘利会陈定甫谢炬炫陈淑芬黄维
Owner NANJING UNIV OF POSTS & TELECOMM