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A kind of amphiphilic montmorillonite and its preparation method and application

A montmorillonite and amphiphilic technology, applied in the field of oil displacement, can solve problems such as harsh conditions, difficult production, cumbersome industrial production, etc., to maintain temperature and salt resistance, stability and repeatability, and good oil displacement effect Effect

Active Publication Date: 2022-07-15
NINGBO FENGCHENG ADVANCED ENERGY MATERIALS RES INST CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This method uses a physical method to compound various substances together, which is cumbersome for industrial production, and when it is actually used in oil fields, it is prone to chromatographic separation effects, resulting in poor results
[0008] The preparation of nano-displacement agents generally involves grafting nanoparticles with monomers with lipophilic groups, usually requiring multiple steps, complex processes and harsh conditions
The prepared product needs to break the emulsion and separate the oil-water mixture. There are problems such as low product yield, poor separation effect, unstable performance, uncontrollable particle size, high production cost, and difficult production.

Method used

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  • A kind of amphiphilic montmorillonite and its preparation method and application
  • A kind of amphiphilic montmorillonite and its preparation method and application
  • A kind of amphiphilic montmorillonite and its preparation method and application

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0074] Example 1 Preparation of amphiphilic montmorillonite

[0075] Step (1) Weigh 2g of montmorillonite into a 1L beaker containing 900mL of water, and mechanically stir at 500 revolutions for 15min to obtain a montmorillonite dispersion (mixture I) with a particle size of 60nm;

[0076] Step (2) Prepare 80 mL of hydrophilic monomer solution (mixed solution II): Weigh 30 g of hydrophilic monomer acrylamide (2:30 mass ratio to montmorillonite) and dissolve it in 80 mL of deionized water. Stir until completely dissolved;

[0077] Step (3) Prepare 20 mL of initiator solution: Weigh 0.3 g of initiator potassium persulfate (1% of the mass of the hydrophilic monomer) and dissolve it in 20 mL of deionized water;

[0078] Step (4) Put the mixed solution I obtained in step (1) and the mixed solution II obtained in step (2) into a 2L clean two-neck round-bottomed flask, insert a stirring paddle to seal the main bottle mouth, and pass N from the side opening. 2 , exhaust oxygen for 3...

Embodiment 2

[0085] The preparation method is the same as that in Example 1, the only difference is that in step (1), mechanical stirring is carried out at 400 revolutions for 30 minutes to obtain a montmorillonite dispersion with a particle size of 200 nm.

Embodiment 3

[0087] The preparation method is the same as that in Example 1, the only difference is that in step (1), mechanical stirring is carried out at 250 rotation speed for 60 min to obtain a montmorillonite dispersion liquid with a particle size of 300 nm.

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Abstract

The present application discloses an amphiphilic montmorillonite and a preparation method and application thereof. The method comprises: adding a hydrophobic monomer and a surfactant to an aqueous dispersion containing montmorillonite and a hydrophilic monomer to obtain an off-white mixed solution ; Add an initiator to the off-white mixed solution to obtain a reaction solution, and carry out a radical polymerization reaction to the reaction solution to obtain amphiphilic montmorillonite. The method obtains the amphiphilic montmorillonite through the free radical micelle method, avoids the use of organic solvents, not only reduces the cost, but also avoids steps such as demulsification, oil-water separation, etc. The method reduces the production difficulty, improves the product yield, and the product has Amphiphilic performance, stable performance and controllable particle size.

Description

technical field [0001] The application relates to an amphiphilic montmorillonite and a preparation method and application thereof, belonging to the technical field of oil displacement. Background technique [0002] In the past two years, my country has continuously become the world's largest crude oil importer. According to the 2018 Development Report of the Oil and Gas Industry at Home and Abroad, China's foreign dependence on crude oil is as high as 69.8%. "National Oil and Gas Resources Dynamic Evaluation 2010": China's petroleum geological resources are 103.7 billion tons, and low-permeability and low-grade heavy oil resources account for about 2 / 3 of the total oil resources. The recovery rate is only 12-14%. [0003] During the development of water flooding, the hydration, scaling and (clay) expansion of the reservoir rock will result in small pores and low permeability in the reservoir, resulting in the failure of water injection and oil recovery, which seriously aff...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08F292/00C08F220/56C08F220/18C09K8/58C09K8/588
CPCC08F292/00C09K8/58C09K8/588C09K8/882C08F220/56C08F220/1818
Inventor 张静张侃王耀国
Owner NINGBO FENGCHENG ADVANCED ENERGY MATERIALS RES INST CO LTD
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