Sealing composition
A technology for sealing and composition, applied in synthetic resin layered products, other chemical processes, chemical instruments and methods, etc., can solve problems such as weak moisture resistance
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[0197] The present invention will be described in more detail by showing examples below, but the present invention is not limited by these examples. In addition, in the following description, unless otherwise specified, "part" and "%" in the quantity of a component and a copolymerization unit represent "mass part" and "mass %", respectively.
[0198] The raw materials used in Examples and Comparative Examples are as follows,
[0199] (A) Polyolefin resin or polyolefin rubber
[0200] ・065 (manufactured by JSR Corporation): Butyl rubber (isobutylene-isoprene copolymer)
[0201] ・N50SF (manufactured by BASF Corporation): polyisobutylene (number average molecular weight: 400,000)
[0202] ・ER850 (manufactured by Starlight PMC): Glycidyl methacrylate (GMA) modified butyl rubber (epoxy group concentration: 0.64 mmol / g, number average molecular weight: 110,000) in 20% toluene solution
[0203] ・ER641 (manufactured by Starlight PMC): 35% toluene solution of maleic anhydride (MA)-m...
Embodiment 2
[0234] Add 20 parts of Ipzole 100 to 3 parts of butyl rubber (065), stir for 3 hours, disperse 1 part of alkyl aluminum diisopropyl acetoacetate (Aluminum Chelate M) and 20 parts of semi-calcined hydrotalcite ( DHT-4C), a mixture was obtained. To the obtained mixture was added the whole amount of a dissolved product obtained by adding 226.6 parts of toluene to 37 parts of butyl rubber (065) and stirring for 3 hours, and further blended 100 parts of glycidyl methacrylate modified butyl rubber ( ER850, 20% toluene solution), and 86 parts of maleic anhydride modified butyl rubber (ER641, 35% toluene solution), 1 part of antioxidant (Irganox 1010) and 9 parts of toluene, 0.2 parts of amine curing agent (TAP) , and the obtained mixture was uniformly dispersed with a high-speed rotary mixer to obtain a varnish (varnish 2) of the composition.
Embodiment 3
[0236] Instead of butyl rubber (065), use polyisobutylene (Oppanol N50SF), change 20 parts of semi-calcined hydrotalcite (DHT-4C) to 15 parts, and replace 1 part of alkyl aluminum diisopropyl acetoacetate (Aluminum Chelate M) A varnish (varnish 3) of the composition was obtained in the same manner as varnish 2 (Example 2) except that 1 part of diisopropoxybis(ethoxyacetoacetyl)titanium (TC710) was added.
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