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Preparation method and application of hierarchical pore carbon material

A technology of carbon materials and multi-level pores, which is applied in chemical instruments and methods, carbon compounds, refined hydrocarbon oils, etc., can solve problems such as low opening degree, hindrance to applications, environmental and human hazards, and achieve low production costs and improved The effect of energy density and large pore volume

Pending Publication Date: 2020-12-04
GUIZHOU MINZU UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, with the development of society, higher requirements are put forward for its performance. However, most of the existing porous carbon materials are of microporous structure, resulting in a low opening degree, which hinders its further application.
However, most of the existing hierarchical porous carbon materials use harmful and carcinogenic substances such as formaldehyde as raw materials in the synthesis process, which is very harmful to the environment and human body.

Method used

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  • Preparation method and application of hierarchical pore carbon material
  • Preparation method and application of hierarchical pore carbon material
  • Preparation method and application of hierarchical pore carbon material

Examples

Experimental program
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Effect test

Embodiment 1

[0032] Such as Figure 1-5 As shown, the present embodiment provides a method for preparing a hierarchical porous carbon material, including: S1: after boiling, drying and grinding Galla galla to obtain Galla galla powder;

[0033] S2: mix the gallnut powder and water obtained in step S1 according to the mass ratio of 1:20 to obtain gallnut mixed liquid;

[0034] S3: Stir the gallnut mixed liquid obtained in step S2 at 30° C. for 1 hour, then centrifuge and filter to obtain gallnut precipitate;

[0035] S4: Mix the gallnut precipitate and water in step S3 according to the mass ratio of 1:20, then place it at 30° C. and stir for 1 hour to obtain the gallnut mixed solution, repeat 6 times;

[0036] S5: Place the gallnut mixed solution in step S4 in a lyophilized vacuum dryer for drying, mix with 40ml of water, and centrifuge to obtain a dark brown gallnut extract;

[0037] S6: Mix the gallnut extract in step S5 with the triblock polymer F-127 solution, wherein the mass ratio o...

Embodiment 2

[0040] This embodiment provides a method for preparing a hierarchically porous carbon material, including: S1: after boiling, drying and grinding gallnuts, gallnut powder is obtained;

[0041] S2: mix the gallnut powder and water obtained in step S1 according to the mass ratio of 1:20 to obtain gallnut mixed liquid;

[0042] S3: Stir the gallnut mixed liquid obtained in step S2 at 30° C. for 1 hour, then centrifuge and filter to obtain gallnut precipitate;

[0043] S4: Mix the gallnut precipitate and water in step S3 according to the mass ratio of 1:20, then place it at 30° C. and stir for 1 hour to obtain the gallnut mixed solution, repeat 6 times;

[0044] S5: Place the gallnut mixed solution in step S4 in a lyophilized vacuum dryer for drying, and then mix with 40ml of water to obtain a dark brown gallnut extract;

[0045] S6: Mix the Galla gall extract in step S5 with the triblock polymer F-127 solution, wherein the mass ratio of the Gallnut extract solution, F-127, and w...

Embodiment 3

[0048] This embodiment provides a method for preparing a hierarchically porous carbon material, including: S1: after boiling, drying and grinding gallnuts, gallnut powder is obtained;

[0049] S2: mix the gallnut powder and water obtained in step S1 according to the mass ratio of 1:20 to obtain gallnut mixed liquid;

[0050] S3: Stir the gallnut mixed liquid obtained in step S2 at 30° C. for 1 hour, then centrifuge and filter to obtain gallnut precipitate;

[0051] S4: Mix the gallnut precipitate and water in step S3 according to the mass ratio of 1:20, then place it at 30° C. and stir for 1 hour to obtain the gallnut mixed solution, repeat 6 times;

[0052] S5: Place the gallnut mixed solution in step S4 in a lyophilized vacuum dryer for drying, mix with 40ml of water, and centrifuge to obtain a dark brown gallnut extract;

[0053] S6: Mix the Galla gall extract in step S5 with the triblock polymer F-127 solution, wherein the mass ratio of the Gallnut extract solution, F-127...

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Abstract

The invention relates to a preparation method of a hierarchical pore carbon material, and belongs to the technical field of material preparation. The preparation method of the hierarchical pore carbonmaterial comprises the steps: boiling gallnut, drying and grinding to obtain gallnut powder; uniformly mixing the gallnut powder with water to obtain a gallnut precipitate and a gallnut mixed liquid;centrifuging and filtering to obtain the gallnut precipitate; uniformly mixing the gallnut precipitate with water, and stirring at the temperature of 30 DEG C for 1 h to obtain a gallnut mixed solution; drying the gallnut mixed solution, uniformly mixing the gallnut mixed solution with water, and centrifuging to obtain a dark brown gallnut extracting solution; and uniformly mixing the gallnut extracting solution with a triblock polymer F-127 solution, standing and precipitating the mixed solution for 24 h, drying the precipitate at the temperature of 80 DEG C, and carbonizing to obtain the hierarchical pore carbon material prepared from gallnut. The preparation method has the beneficial effects that the carbon material with the hierarchical pore structure and the pore size distribution range of 10-50 nm is produced and obtained by a green and pollution-free manner, and the reduction of resistance during molecular diffusion is better facilitated.

Description

technical field [0001] The invention belongs to the field of material preparation, and in particular relates to a preparation method of a hierarchical porous carbon material. Background technique [0002] Activated carbon is a carbonaceous adsorption material prepared from carbonaceous materials such as coal, forest wood, and fruit shells. It is widely used in gas adsorption, separation, purification, and body purification. However, with the development of society, higher requirements are put forward for its performance. However, most of the existing porous carbon materials are of microporous structure, resulting in a low opening degree, which hinders its further application. However, most of the existing hierarchical porous carbon materials use harmful and carcinogenic substances such as formaldehyde as raw materials in the synthesis process, which is very harmful to the environment and human body. Contents of the invention [0003] In order to solve the above-mentioned ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01B32/318C01B32/342C10G25/00
CPCC10G25/003C01B32/318C01B32/342
Inventor 王戎戎杨吟野罗胜耘郑谦
Owner GUIZHOU MINZU UNIV
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