Fluidized bed device for preparing uranium nitride and using method thereof
A technology of fluidized bed and uranium nitride, which is applied in the field of nuclear engineering, can solve the problems of less research on special equipment, and achieve the effect of thorough tail gas disposal and high reaction yield
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Embodiment 1
[0031] A fluidized bed device for preparing uranium nitride, comprising a gas system 1, a mixing system 2, a low-temperature fluidized bed 3, a high-temperature fluidized bed 4, a tail gas treatment device 5 and an absorption tower 6; the gas system 1 Connect with low temperature fluidized bed 3, high temperature fluidized bed 4 respectively, described mixing system 2 is connected with low temperature fluidized bed 3, described low temperature fluidized bed 3 is connected with high temperature fluidized bed 4, described low temperature fluidized bed 3. The high-temperature fluidized bed 4 is connected to the tail gas treatment device 5 respectively, and the tail gas treatment device 5 is connected to the absorption tower 6 .
[0032] In this embodiment, by controlling the reaction steps in a low-temperature fluidized bed and a high-temperature fluidized bed respectively, the smooth progress of the reaction under different temperature requirements is ensured; the reaction condit...
Embodiment 2
[0046] In order to achieve the above purpose, this embodiment also provides a method for using a fluidized bed device for preparing uranium nitride, comprising the following steps:
[0047] S1, UO 2 with NH 4 HF 2 With a molar ratio of 1:4 to 1:8 or U 3 o 8 with NH 4 HF 2 Put it into a mixing device at a molar ratio of 1:12 to 1:24, mix and grind in the mixing device for 30-60 minutes to obtain ground powder particles;
[0048] S2, feed argon gas into the low-temperature fluidized bed, and wash repeatedly 3 times;
[0049] S3. Transfer the ground powder particles after mixing and grinding to a low-temperature fluidized bed, heat to 20-125°C through the first heating device and the first temperature control sensor, and react for 3-12 hours to obtain a reaction product;
[0050] S4, transfer the reaction product to a high-temperature fluidized bed, and feed Ar and NH 3 , N 2 、H 2 The combined gas mixed gas is heated to 700-1000°C by the second heating device and the se...
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