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High-toughness low-precipitation halogen-free flame-retardant PC/ABS material and preparation method thereof

A technology of ABS material and high toughness, which is applied in the field of polycarbonate materials, can solve the problems that the extruder barrel screw cannot be stably and uniformly dispersed, the flame retardancy of the material, the influence of mechanical properties, and the inconsistent dispersion state of BDP, etc., to achieve improved resistance The effects of fuel precipitation, improved wetting ability, and enhanced interaction

Active Publication Date: 2020-12-22
安庆会通新材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The flame retardant BDP is liquid at room temperature. In a high-temperature processing environment, the viscosity of BDP is too different from that of PC / ABS melt, which leads to the inability to disperse stably and uniformly in the barrel and screw of the extruder, and the dispersion state of BDP is inconsistent, resulting in The flame retardancy and mechanical properties of the material are affected, and in the subsequent processing and molding process, BDP is easy to precipitate from the PC / ABS material

Method used

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  • High-toughness low-precipitation halogen-free flame-retardant PC/ABS material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] A high-toughness, low-precipitation, halogen-free flame-retardant PC / ABS material, including the following raw materials in parts by mass: 76 parts of polycarbonate, 8 parts of acrylonitrile-butadiene-styrene copolymer, and 10 parts of modified BDP flame retardant 6 parts of methyl methacrylate-butadiene-styrene terpolymer, 0.2 part of antioxidant, 0.3 part of internal lubricant, 0.5 part of external lubricant, 0.6 part of anti-dripping agent, 0.5 part of carbon black .

[0029] The preparation method of the modified BDP flame retardant is: add the surface-modified nano-silica with an average particle size of 100nm into the flame retardant BDP and mix evenly, wherein the flame retardant BDP and the surface-modified nano-silica The mass ratio of silicon is 5:1.

[0030] The preparation method of surface-modified nano-silica is as follows: disperse nano-silica in toluene, and disperse for 2.5 hours under 400W ultrasonic conditions to obtain nano-silica suspension; disper...

Embodiment 2

[0035] The difference between Example 2 and Example 1 is only: in the modified BDP flame retardant, the mass ratio of the flame retardant BDP to the surface-modified nano silica is 15:1.

Embodiment 3

[0037] The difference between Example 3 and Example 1 is only: in the modified BDP flame retardant, the mass ratio of the flame retardant BDP to the surface-modified nano silica is 25:1.

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Abstract

A disclosed high-toughness low-precipitation halogen-free flame-retardant PC / ABS material is prepared from the following raw materials in parts by mass: 40 to 80 parts of polycarbonate, 5 to 20 partsof acrylonitrile-butadiene-styrene copolymer, 5 to 30 parts of modified BDP flame retardant, 2 to 20 parts of toughening agent, 0.2 to 1 part of antioxidant, 0.3 to 1 part of internal lubricant, 0.3 to 1 part of external lubricant, 0.3 to 1 part of anti-dripping agent and 0 to 1 part of pigment. The invention also discloses a preparation method of the high-toughness low-precipitation halogen-freeflame-retardant PC / ABS material. According to the invention, the flame-retardant and impact-resistant stability of the PC / ABS material can be effectively improved, and the problem that a flame retardant is separated out in the subsequent molding process can be improved.

Description

technical field [0001] The invention relates to the technical field of polycarbonate materials, in particular to a high-toughness, low-precipitation, halogen-free flame-retardant PC / ABS material and a preparation method thereof. Background technique [0002] PC / ABS material refers to a mixture of polycarbonate and acrylonitrile-butadiene-styrene copolymer, a thermoplastic made of polycarbonate (PC) and polyacrylonitrile (ABS), combining two The excellent characteristics of the material, the formability of the ABS material and the mechanical properties, impact strength, temperature resistance, and ultraviolet (UV) resistance of the PC can be widely used in automotive interior parts, business machines, communication equipment, home appliances and lighting equipment. . [0003] Since most electrical materials have flame retardant requirements, combined with the current international trend of halogen-free flame-retardant materials, higher requirements are put forward for the ha...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L69/00C08L55/02C08L27/18C08L51/04C08K13/06C08K9/04C08K3/36C08K5/523
CPCC08L69/00C08L2201/02C08L2201/22C08L2205/035C08K2201/011C08K2201/003C08L55/02C08L27/18C08L51/04C08K13/06C08K9/04C08K3/36C08K5/523
Inventor 张正李荣群何继辉魏子芳陈贤宏
Owner 安庆会通新材料有限公司
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