Natural-marble-imitated ceramic tile and preparation method thereof

A technology of imitating marble and marble, applied in the field of imitating natural marble tiles and its preparation, can solve the problems of low simulation degree, lack of fine texture and layering and translucency of natural marble, and resistance to wear, etc., so as to avoid direct Wear, maintain integrity, maintain natural effect

Pending Publication Date: 2021-02-02
佛山市金舵陶瓷有限公司
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AI-Extracted Technical Summary

Problems solved by technology

At present, the existing ceramic tiles imitating natural marble products have the following disadvantages: the degree of simulation is not hig...
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Abstract

The invention discloses a natural-marble-imitated ceramic tile and a preparation method thereof. The natural-marble-imitated ceramic tile is prepared from 94-97% of a green body, 1.5-2.5% of ground glaze, 0.1-1% of fancy glaze and 1.5-2.5% of surface glaze, and is prepared by the following steps of putting blank feldspar, crystal color frit, pyrophyllite, white mud and high-alumina stone into a press to be formed, drying an obtained green body, applying the ground glaze to the surface of the green body, printing fancy glaze onto the ground glaze-applied green body, applying surface glaze to the fancy glaze-applied green body, then firing the green body, and polishing a fired semi-finished product to obtain a finished product. The prepared ceramic tile has fine texture similar to that of natural marble and has the layering sense and translucency of natural stone at the same time, patterns and colors are located in the glaze, direct abrasion of patterns and colors of the ceramic tile inthe using process is avoided, the service life of the ceramic tile is prolonged, completeness and natural feeling of the patterns and colors of the tile are kept for a long time, and a more vivid effect is achieved.

Application Domain

Claywares

Technology Topic

Ceramic tilesGreen body +5

Examples

  • Experimental program(3)

Example Embodiment

[0023] Example 1
[0024] The composition of imitation natural marble tile in the present embodiment comprises 94% green body, 2.5% bottom glaze, 1% pattern glaze and 2.5% top glaze, wherein, the weight part composition of green body comprises 30 parts of feldspar, crystal 3 parts of colored frit, 10 parts of pyrophyllite, 25 parts of white clay, and 15 parts of high alumina stone. parts, 15 parts of zirconium silicate, the composition of the weight part of flower glaze includes 30 parts of feldspar, 20 parts of crystal color frit, 5 parts of corundum, 10 parts of kaolin, 10 parts of zinc oxide, 11 parts of wollastonite, 3 parts of barium oxide , 15 parts of quartz, the composition of the surface glaze in parts by weight includes 50 parts of feldspar, 10 parts of quartz, 30 parts of kaolin, 3 parts of zinc oxide, 20 parts of wollastonite, and 10 parts of burnt talc;
[0025] Among them, the mass percentage of crystal color frit is composed of 52-59% silicon dioxide, 18-25% aluminum oxide, 0.1-1.3% iron oxide, 0.1-0.7% titanium dioxide, 1.5-8% calcium oxide, 0.05-0.18% Magnesium oxide, 0.25-3% potassium oxide, 0.18-0.7% sodium oxide, 3-3.5% fluorine oxide, 1.2-3.8% phosphorus oxide, 5-8% boron oxide.
[0026] A kind of production technology of imitation marble tile, comprises the steps:
[0027] (1) Put 30 parts of feldspar, 3 parts of crystal color frit, 10 parts of pyrophyllite, 25 parts of white clay, and 15 parts of pyrophyllite into a press to form a green body;
[0028] (2) drying the green body obtained in step 1, the drying temperature is 180°C, and the drying time is 100min;
[0029] (3) Apply primer to the body surface gained in step 2, the ratio of primer is 1.8g/cm 3 , the amount of glaze is 660g/㎡;
[0030] (4) Apply decal glaze to the green body after applying the base glaze in step 3, and the specific gravity of the decal glaze is 1.6g/cm 3 , the glaze amount is 860g/㎡;
[0031] (5) Apply the printing glaze to the green body after applying the pattern glaze in step 4, and the specific gravity of the surface glaze is 1.85g/cm 3 , the glaze amount is 870g/㎡;
[0032] (6) firing step 5, the firing temperature is 1250°C, and the firing time is 50min;
[0033] (7) Polishing the semi-finished product fired in step 6 to obtain a finished product.
[0034] Further, the molding frequency of the green body in the step 1 is 3.2-3.8 times/min, and the molding pressure is ≥ 280Mpa, and the flow rate in the step 4 is 40-45s when applying the top glaze.

Example Embodiment

[0035] Example 2
[0036] The composition that imitation natural marble tile adopts in the present embodiment comprises
[0037] 94% green body, 2.5% bottom glaze, 1% flower glaze and 2.5% top glaze, wherein the weight of green body consists of 30 parts of feldspar, 3 parts of crystal color frit, 10 parts of pyrophyllite, 25 parts of white clay, 15 parts of high alumina, the composition of the bottom glaze by weight includes 30 parts of feldspar, 10 parts of calcined talc, 30 parts of kaolin, 15 parts of quartz, 20 parts of wollastonite, and 15 parts of zirconium silicate. 30 parts of feldspar, 20 parts of crystal frit, 5 parts of corundum, 10 parts of kaolin, 10 parts of zinc oxide, 11 parts of wollastonite, 3 parts of barium oxide, 15 parts of quartz, and the composition of the surface glaze by weight includes 50 parts of feldspar 10 parts of quartz, 30 parts of kaolin, 3 parts of zinc oxide, 20 parts of wollastonite, 10 parts of burnt talc;
[0038] 95.5% green body, 2% bottom glaze, 0.5% flower glaze and 2% top glaze, wherein the weight of green body consists of 32 parts of feldspar, 4 parts of crystal color frit, 13 parts of pyrophyllite, 30 parts of white mud, 17 parts of high alumina, the composition of the bottom glaze by weight includes 26 parts of feldspar, 8 parts of calcined talc, 25 parts of kaolin, 10 parts of quartz, 15 parts of wollastonite, and 10 parts of zirconium silicate. 27 parts of feldspar, 18 parts of crystal frit, 4 parts of corundum, 9 parts of kaolin, 9 parts of zinc oxide, 10 parts of wollastonite, 2 parts of barium oxide, 12 parts of quartz, and the composition of the surface glaze includes 45 parts by weight of feldspar 7 parts of quartz, 22 parts of kaolin, 2 parts of zinc oxide, 15 parts of wollastonite, and 8 parts of calcined talc.
[0039] Among them, the mass percentage of crystal color frit is composed of 52-59% silicon dioxide, 18-25% aluminum oxide, 0.1-1.3% iron oxide, 0.1-0.7% titanium dioxide, 1.5-8% calcium oxide, 0.05-0.18% Magnesium oxide, 0.25-3% potassium oxide, 0.18-0.7% sodium oxide, 3-3.5% fluorine oxide, 1.2-3.8% phosphorus oxide, 5-8% boron oxide.
[0040] A kind of production technology of imitation marble tile, comprises the steps:
[0041] (1) Put 32 parts of feldspar, 4 parts of crystal color frit, 13 parts of pyrophyllite, 30 parts of white clay, and 17 parts of high alumina into a press for molding to obtain a green body;
[0042] (2) drying the green body obtained in step 1, the drying temperature is 200° C., and the drying time is 80 minutes;
[0043] (3) Apply primer to the body surface obtained in step 2, the ratio of primer is 1.7g/cm 3 , the amount of glaze is 620g/㎡;
[0044] (4) Apply decal glaze to the green body after applying the base glaze in step 3, and the specific gravity of the decal glaze is 1.55g/cm 3 , the glaze amount is 850g/㎡;
[0045] (5) Apply the printed glaze to the green body after applying the floral glaze in step 4, and the specific gravity of the surface glaze is 1.8g/cm 3 , the glaze amount is 860g/㎡;
[0046] (6) Burning the step 5, the firing temperature is 1220°C, and the firing time is 70min;
[0047](7) Polishing the semi-finished product fired in step 6 to obtain a finished product.
[0048] Wherein, the molding frequency of the green body in the step 1 is 3.2-3.8 times/min, and the molding pressure is ≥ 280Mpa, and the flow rate in the step 4 is 40-45s when applying the top glaze.

Example Embodiment

[0049] Example 3
[0050] The composition that imitation natural marble tile adopts in the present embodiment comprises:
[0051] 96.9% green body, 1.5% bottom glaze, 0.1% flower glaze and 1.5% top glaze, wherein, the body consists of 35 parts by weight of feldspar, 5 parts of crystal color frit, 15 parts of pyrophyllite, 35 parts of white clay, 20 parts of high alumina, the composition of the bottom glaze by weight includes 15 parts of feldspar, 5 parts of calcined talc, 15 parts of kaolin, 8 parts of quartz, 10 parts of wollastonite, and 5 parts of zirconium silicate. 25 parts of feldspar, 15 parts of crystal frit, 3 parts of corundum, 7 parts of kaolin, 8 parts of zinc oxide, 8 parts of wollastonite, 1 part of barium oxide, 10 parts of quartz, and the composition of the surface glaze includes 40 parts by weight of feldspar parts, 5 parts of quartz, 15 parts of kaolin, 1 part of zinc oxide, 10 parts of wollastonite, and 5 parts of calcined talc.
[0052] Among them, the mass percentage of crystal color frit is composed of 52-59% silicon dioxide, 18-25% aluminum oxide, 0.1-1.3% iron oxide, 0.1-0.7% titanium dioxide, 1.5-8% calcium oxide, 0.05-0.18% Magnesium oxide, 0.25-3% potassium oxide, 0.18-0.7% sodium oxide, 3-3.5% fluorine oxide, 1.2-3.8% phosphorus oxide, 5-8% boron oxide.
[0053] A kind of production technology of imitation marble tile, comprises the steps:
[0054] (1) Put 32 parts of feldspar, 4 parts of crystal color frit, 13 parts of pyrophyllite, 30 parts of white clay, and 17 parts of high alumina into a press for molding to obtain a green body;
[0055] (2) drying the green body obtained in step 1, the drying temperature is 230° C., and the drying time is 70 minutes;
[0056] (3) Apply primer to the body surface obtained in step 2, the ratio of primer is 1.6g/cm 3 , the amount of glaze is 570g/㎡;
[0057] (4) Apply decal glaze to the green body after applying the base glaze in step 3, and the specific gravity of the decal glaze is 1.5g/cm 3 , the glaze amount is 845g/㎡;
[0058] (5) Apply the printing glaze to the green body after applying the pattern glaze in step 4, and the specific gravity of the surface glaze is 1.75g/cm 3 , the glaze amount is 850g/㎡;
[0059] (6) Burning the step 5, the firing temperature is 1190°C, and the firing time is 90min;
[0060] (7) Polishing the semi-finished product fired in step 6 to obtain a finished product.
[0061] Wherein, the molding frequency of the green body in the step 1 is 3.2-3.8 times/min, and the molding pressure is ≥ 280Mpa, and the flow rate in the step 4 is 40-45s when applying the top glaze.

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