Rubber composition for tire tread, and tire
A technology of rubber composition and tire tread, which is applied in the field of rubber composition for tire tread and tires, can solve the problems of wet grip performance degradation, and achieve the effect of improving initial wet grip performance
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[0102] The present invention will be described based on examples. The present invention is not limited to these Examples.
[0103] Various chemicals used in Examples and Comparative Examples are shown below.
[0104] SBR1: T3830 (S-SBR, styrene content: 33% by mass, vinyl bond amount: 36mol%, oil-extended product containing 37.5 parts by mass of oil content (based on 100 parts by mass of the rubber component)), manufactured by Asahi Kasei Corporation
[0105] SBR2: Modified SBR (S-SBR, styrene content: 25% by mass, vinyl bond amount: 30mol%, weight average molecular weight (Mw) 500,000), manufactured by Production Example 1
[0106] Silica: Nipsil AQ (N 2 SA: 205m 2 / g), manufactured by Tosoh Corporation
[0107] Carbon black: Show Black N220 (ordinary carbon, N 2 SA: 114m 2 / g), manufactured by Cabot Japan
[0108] Aluminum hydroxide: HIGILITE H-43 (average primary particle size: 1μm, N 2 SA: 6.7m 2 / g), manufactured by Showa Denko Co., Ltd.
manufacture example 1
[0127] Production example 1 (manufacture of modified SBR)
[0128] A stainless steel polymerization reactor with an agitator having an internal volume of 30 liters was washed and dried, and the gas inside the polymerization reactor was replaced with dry nitrogen. Then, add 15.3kg industrial hexane (density: 680kg / m 3 ), 912 g of 1,3-butadiene, 288 g of styrene, 9.1 ml of tetrahydrofuran and 6.4 ml of ethylene glycol diethyl ether. Then, a small amount of n-1-butyllithium dissolved in n-hexane solution was added as a scavenger in the polymerization reactor to detoxify the impurities that deactivate the polymerization initiator in advance. n-Butyllithium (n-butyllithium content: 19.2 mmol) dissolved in n-hexane solution was charged into the polymerization reactor to start a polymerization reaction. Polymerization was continued for 3 hours. During the polymerization reaction, adjust the temperature of the polymerization reactor to 65 ° C, stir the solution in the polymerizatio...
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