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A kind of organosilicon packaging material for photovoltaic module and preparation method thereof

A technology for packaging materials and photovoltaic modules, applied in photovoltaic power generation, electrical components, semiconductor devices, etc., can solve problems such as no research on the anti-mildew properties of materials, and differences in the efficiency of components without examining the light transmittance of packaging materials, so as to improve the economic benefits of products. , Good adhesion, high light transmittance

Active Publication Date: 2022-05-27
CHENGDU GUIBAO SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

A photovoltaic organic silicon encapsulant is mentioned in CN103525094A, which is non-corrosive to solar cells and has good air permeability. The efficiency retention rate of components prepared by backplane-encapsulant-battery-encapsulant-panel five-layer encapsulation is higher after aging, but It did not investigate the light transmittance of the packaging material and the difference in component efficiency before and after using the packaging material, nor did it study the anti-mold performance of the material

Method used

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  • A kind of organosilicon packaging material for photovoltaic module and preparation method thereof
  • A kind of organosilicon packaging material for photovoltaic module and preparation method thereof
  • A kind of organosilicon packaging material for photovoltaic module and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] 1. In parts by mass, the vinyl content of 50 parts is 0.2wt%, the phenyl content is 3mmol / g, and the viscosity is the phenyl vinyl silicone oil of 50Pa s (using two kinds of viscosity 5Pa s, 200Pa s) Phenyl vinyl silicone oils of different viscosities are mixed together), 30 parts of phenyl vinyl silicone resin with a vinyl content of 2.5wt% (mixed by 60wt% phenyl vinyl MQ resin and 40wt% phenyl vinyl MDT resin) ), 0.75 part of platinum catalyst was added to the planetary mixer, stirred in vacuum for 1 hour, stirred evenly, removed air bubbles, and obtained component A after filtering impurities.

[0029] 2. 25 parts of phenyl vinyl silicone oil with a vinyl content of 0.2 wt%, a phenyl content of 3 mmol / g, and a viscosity of 50 Pa s (using two different viscosities of phenyl with a viscosity of 5 Pa s and 200 Pa s) Vinyl silicone oil blended together), 15 parts of vinyl content of 2.5wt% phenyl vinyl silicone resin (mixed by 60wt% phenyl vinyl MQ resin, 40wt% phenyl vi...

Embodiment 2

[0032] 1. in parts by mass, 50 parts of vinyl content are 0.15wt%, phenyl content is 5mmol / g, and the viscosity is the phenyl vinyl silicone oil of 100Pa s (using two kinds of viscosity 20Pa s, 110Pa s) Phenyl vinyl silicone oils of different viscosities are mixed with each other), 25 parts of phenyl vinyl silicone resin with a vinyl content of 4wt% (mixed by 30wt% phenyl vinyl MQ resin and 70wt% phenyl vinyl MDT resin) , 1.5 parts of platinum catalyst was added to the planetary mixer, stirred in vacuum for 1 hour, stirred evenly, removed air bubbles, and obtained component A after filtering impurities.

[0033] 2. 25 parts of phenyl vinyl silicone oil with a vinyl content of 0.2 wt%, a phenyl content of 3 mmol / g, and a viscosity of 50 Pa s (using two different viscosities of phenyl with a viscosity of 5 Pa s and 200 Pa s) Vinyl silicone oil blended together), 10 parts of vinyl content of 2.5wt% phenyl vinyl silicone resin (mixed by 60wt% phenyl vinyl MQ resin, 40wt% phenyl vi...

Embodiment 3

[0036]1. In parts by mass, 50 parts of vinyl content are 0.6wt%, phenyl content is 6mmol / g, and the viscosity is the phenyl vinyl silicone oil of 150Pa s (using two kinds of viscosity 5Pa s, 200Pa s) Phenyl vinyl silicone oils of different viscosities are mixed with each other), 20 parts of phenyl vinyl silicone resin with a vinyl content of 2.1 wt% (mixed by 20 wt % phenyl vinyl MQ resin and 80 wt % phenyl vinyl MDT resin) ), add 3 parts of platinum catalyst into the planetary mixer, stir in vacuum for 1 hour, stir evenly, remove air bubbles, and obtain component A after filtering impurities.

[0037] 2. 25 parts of phenyl vinyl silicone oil with a vinyl content of 0.15 wt %, a phenyl content of 2 mmol / g and a viscosity of 50 Pa s (using two different viscosities of phenyl with a viscosity of 20 Pa s and 100 Pa s) Vinyl silicone oil blended together), 10 parts of vinyl content of 2.1wt% phenyl vinyl silicone resin (mixed by 20wt% phenyl vinyl MQ resin, 80wt% phenyl vinyl MDT ...

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Abstract

The invention discloses a silicone encapsulation material for photovoltaic modules and a preparation method thereof, including the preparation of component A and component B, the preparation method of component A: mixing 50 parts of phenyl vinyl silicone oil, 10 to 50 parts of phenyl Vinyl silicone resin, 0.2 to 2 parts of platinum catalyst dispersed evenly, stirred in vacuum to remove air bubbles, and filtered impurities. The preparation method of component B is: 25 parts of phenyl vinyl silicone oil, 10-50 parts of phenyl vinyl silicone resin, 1-5 parts of tackifier, 10-30 parts of cross-linking agent, 0.1-2 parts of inhibitor Disperse evenly, stir in vacuum, remove air bubbles, and filter impurities. Mix the components A and B, and encapsulate in four layers: encapsulant-battery-encapsulant-panel. The light transmittance of the photovoltaic encapsulation material prepared by the present invention is more than or equal to 92%, and the light transmittance retention rate is greater than 97% after damp heat aging and ultraviolet aging for 1000 hours, and has excellent anti-mold performance; no back glass or back plate film is required for encapsulation, and can Reduce packaging costs.

Description

technical field [0001] The invention relates to an organic silicon packaging material for photovoltaic modules, in particular to a two-component addition type organic silicon packaging material for photovoltaic modules and a preparation method thereof. Background technique [0002] At present, solar photovoltaic modules have become one of the widely used forms of power generation. The core of a photovoltaic module is a cell, which itself has a service life of more than 30 years. Therefore, the performance reliability of a solar cell module in a long-term outdoor environment is mainly determined by the packaging of the module. The ideal photovoltaic module encapsulation material should have high transparency, good adhesion, sufficient mechanical deformation and aging resistance. The most commonly used encapsulation material today is ethylene-vinyl acetate copolymer (EVA). However, EVA will be hydrolyzed to form acetic acid in a humid and hot environment, which will cause co...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09J183/07C09J11/06C09J11/08H01L31/048
CPCC09J183/04C09J11/06C09J11/08H01L31/0481C08L2203/206C08L2205/025C08L2205/035C08L83/04C08L83/08C08K5/549Y02E10/50
Inventor 王有治陈相全祝雷黄强陈东张明
Owner CHENGDU GUIBAO SCI & TECH