Composition for aqueous coating liquid containing polymer of n-vinyl carboxylic acid amide
A technology of vinyl carboxylic acid amide and composition, applied in the direction of coatings, devices for coating liquid on the surface, latex paint, etc., can solve the problems of low concentration of thickening and dispersing agents, undisclosed and implied drying, etc., and achieve high The effect of improving hydrophilicity and dryness
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[0106] Below, the present invention is illustrated by example, but the present invention is not interpreted in any way by them.
manufacture example
[0108] Polymerization of N-vinylacetamide
[0109]Nitrogen gas vents, a mixer, a solvent drop dosing device, and a thermometer are installed in four 1-liter capacity detachable flasks, and 550 g of ion-exchanged water is added to the detachable flask, and then 50 g of N-vinyl acetamide (made by Showa Electric Co., Ltd.) is added to it. In this state, while displacing the nitrogen in the dissolved solution, stirring and heating, increasing the starting temperature of the polymerization until 51 ° C, the initiator 2,2'-azo di [N- (carboxyethyl)-2-methylpropamidine] tetrahydrate (hereinafter, VA-057) 0.04 g (total monomer ratio 0.08 mass%) is dissolved in the state of ion exchange water undergoing nitrogen degassing treatment 10 g. In this state, the polymerization reaction is carried out for 4 hours, and then, the internal temperature is raised until 80 °C and maintained for 1 hour, and then the sample is taken, and the residual monomer is determined by the HPLC method, and the re...
Embodiment 1~16
[0137] The polymer aqueous solution of 5 mass% N- vinyl acetamide obtained in the manufacturing example, and the 5 mass% concentration aqueous solution of the substance shown in Table 1 as a polysaccharide at 25 ° C in accordance with the mixing ratio of Table 1 is stirred, homogenized, and the composition of the aqueous coating liquid is modulated. Further in Example 16, after homogenization, alumina was mixed at the ratio of Table 1.
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