Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Easy-to-spray high-rigidity alloy material and preparation method thereof

A technology of alloy materials and acrylonitrile, which is applied in the field of easy-to-spray high-rigid alloy materials and their preparation, can solve problems such as metal assembly gap fluctuations, stress cracking, and structural design restrictions, so as to reduce thermal linear expansion coefficient and improve chemical resistance. Product performance, ease of use and efficient results

Inactive Publication Date: 2021-05-14
ORINKO NEW MATERIAL CO LTD
View PDF3 Cites 1 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, due to the defects in corrosion resistance of PC / ABS alloy materials and the limitation of processing fluidity, in the field of spraying with complex structures, there are still glue shortages in injection molding, paint bite, pinholes, stress cracking, and fluctuations in the gap between metal assemblies, etc. Appearance and use defects
In the application field of replacing steel with plastic, it often shows rigidity defects. In many cases, due to the lack of rigidity of the material, the wall thickness design has to be increased in the structural design stage, which will not only increase the cost but also affect the structure. design creates additional constraints
In addition, it is necessary to consider the risk of the change of the assembly surface difference in the extremely cold and extremely hot environment.
[0003] The PC / PET and PC / PBT alloys that have been widely used have good impact and heat resistance, and excellent chemical resistance, but due to the presence of residual Ti catalysts in the synthesis process of PBT or PET, the addition of too much The transesterification reaction in the production and processing process cannot be completely avoided. For complex structures, there are usually problems such as shear resistance and high temperature silver wires in practical applications. At the same time, there are also defects such as rigidity and dimensional instability, especially when the PET content of PC / PET alloys is high. When it is high, due to the limitation of the crystallization speed and degree, it often shows defects such as drawing die, part collapse and deformation, which seriously affects the normal production and assembly use effect of the product.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Easy-to-spray high-rigidity alloy material and preparation method thereof
  • Easy-to-spray high-rigidity alloy material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] An easy-to-spray high-rigid reinforced alloy material is made of the following raw materials in parts by weight: 34 parts of PC resin pellets, 10 parts of PC resin powder, 10 parts of AS resin, 30 parts of PET resin, 5 parts of toughening agent, glass fiber 10 parts, 0.5 parts of styrene-acrylonitrile-GMA-MMA tetrapolymer, 0.4 parts of antioxidant, 0.3 parts of lubricant, 0.2 parts of transesterification inhibitor, 1 part of black masterbatch. Among them, the PC resin is mixed with pellets and powder at the same time, so as to facilitate the full mixing of fillers and tougheners.

[0031] Among them, the PC resin material is PC 2220R from SABIC; the PC resin powder is PC 2220 from Wanhua; the AS resin is 80HF from LG Yongxing; the PET resin is PET CB602 from Yuanfang Shanghai; the glass fiber is chopped glass fiber from Chongqing International. ECS303H-3; MBS EM500 from LG Chemical is used as the toughening agent; RAS-302 from Huawen Chemical Co., Ltd. is used for the s...

Embodiment 2

[0035] An easy-to-spray high-rigid reinforced alloy material is made of the following raw materials in parts by weight: 36 parts of PC resin pellets, 20 parts of PC resin powder, 5 parts of AS resin, 10 parts of PBT resin, 4 parts of EM500 toughening agent, 14 parts of toughening agent HR-18, 20 parts of talcum powder, 1.5 parts of styrene-acrylonitrile-GMA-MMA tetrapolymer, 0.4 parts of antioxidant, 0.3 parts of lubricant, 0.2 parts of transesterification inhibitor, 1 part of black masterbatch .

[0036] Among them, the PC resin material is PC 2220R from SABIC; the PC resin powder is PC 2220 from Wanhua; the AS resin is D-168 from Zhenjiang Chimei; the PBT resin is 211M from Changchun Chemical; the talcum powder is Mengdu M05SLC; LG Chem’s MBS EM500 and Kumho’s HR-181; the styrene-acrylonitrile-GMA-MMA tetrapolymer uses Huawen Chemical’s RAS-302; the antioxidants are Lianlong’s 1076 and 168; its weight The ratio is 1:1; the lubricant is Italian hair-based pentaerythritol ste...

Embodiment 3

[0045] An easy-to-spray high-rigid reinforced alloy material is made of the following raw materials in parts by weight: 46 parts of PC resin pellets, 10 parts of PC resin powder, 22 parts of AS resin, 5 parts of PBT tree, 3 parts of EM500 toughening agent, HR 3 parts of -181 toughening agent, 10 parts of talcum powder, 1 part of styrene-acrylonitrile-GMA-MMA tetrapolymer, 0.4 parts of antioxidant, 0.2 parts of lubricant, 0.2 parts of transesterification inhibitor, 1 part of black masterbatch share.

[0046] Among them, PC resin pellets are PC 2220R from SABIC; PC resin powder is PC 2220 from Wanhua; AS resin is 80HF from LG Yongxing and PN-108 from Zhenjiang Chimei in a ratio of 1:1; PBT resin is 211M from Changchun Chemical Industry ;Talc powder is selected from Mengdu M05SLC; the toughening agent is selected from MBS EM500 of LG Chemical and HR-181 of Korea Kumho; the styrene-acrylonitrile-GMA-MMA tetrapolymer is selected from Huawen Chemical RAS-302; The lubricant is Lianl...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
glass transition temperatureaaaaaaaaaa
Login to View More

Abstract

The invention discloses an easy-to-spray high-rigidity alloy material and a preparation method thereof, and relates to the technical field of high polymer materials. The alloy material is prepared from the following components in parts by weight: 5 to 30 parts of aromatic polyester, 20 to 70 parts of polycarbonate, 5 to 30 parts of a styrene-acrylonitrile copolymer, 2 to 8 parts of a flexibilizer, 10 to 30 parts of a filler, 0.5 to 2 parts of a heat stabilizer, 1 part of a coloring agent, 0.4 to 1 part of an antioxidant, 0.2 to 0.5 part of a lubricant and 0.1 to 0.5 part of an ester exchange inhibitor. The easy-to-spray high-rigidity alloy composition provided by the invention has the characteristics of high flowability, high rigidity, good dimensional stability, low linear expansion coefficient, corrosion resistance and easy spraying; the alloy material is especially suitable for replacing a metal material to be applied to the field of interior and exterior decoration coating with high strength requirements, such as skylight decoration strips, and also has a good application effect in the field of frameworks with high requirements for material rigidity and dimensional stability.

Description

technical field [0001] The invention belongs to the technical field of polymer materials, and in particular relates to an easy-to-spray high-rigidity alloy material and a preparation method thereof. Background technique [0002] PC / ABS is a mixture of polycarbonate and acrylonitrile-butadiene-styrene copolymer. It takes into account the advantages of both PC and ABS. Compared with ordinary materials, it has excellent mechanical properties and can be widely used in automotive interior and exterior parts. Components, 5G communications, household appliances and other fields. Especially in recent years, with the popularization of automobiles and home appliances, the application of PC / ABS alloy materials in the above fields has been continuously improved, and good results have been achieved. However, due to the defects in corrosion resistance of PC / ABS alloy materials and the limitation of processing fluidity, in the field of spraying with complex structures, there are still glu...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(China)
IPC IPC(8): C08L69/00C08L25/12C08L67/02C08L55/02C08L51/04C08L25/14C08K7/14C08K3/34
CPCC08L69/00C08L2201/08C08L2205/025C08L2205/035C08L2205/02
Inventor 邢道亮金石文听雷何继辉
Owner ORINKO NEW MATERIAL CO LTD
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products