The invention discloses a liquid organic silicon-doped hexagonal boron nitride material and its automatic preparation and industrial application methods. The material is composed of component A composed of vinyl silicone oil, surface-activated hexagonal boron nitride, inhibitor and catalyst, and group B composed of vinyl silicone oil, hydrogen-containing silicone oil and surface-activated hexagonal boron nitride grouped. Its automatic preparation and industrial application method, the steps are as follows: 1) A and B components are automatically transported and mixed, and then enter the precision injection system; 2) At the same time, the silver-plated stone black ene composite metal sheet is automatically transported to the mold setting 3) Then after glue injection, curing, wrapping, slicing, chip sticking, gold wire connection, potting glue potting, it is transformed into components such as LED light source and IC patch. The liquid organic silicon-doped hexagonal boron nitride material prepared by the invention has excellent characteristics such as high and low temperature resistance, high molding efficiency, good sealing performance, and low cost, and can be widely used in various fields of optoelectronic components.