The invention discloses a preparation method of a continuous
graphene nanofiber bundle, and relates to the technical field of
graphene fiber materials. The preparation method comprises the following steps: preparing and preparing a
graphene oxide nanobelt solution, and adding a
plasticizer to obtain a
spinning solution; injecting the
spinning solution into an electrostatic
spinning device, performing near-field electrostatic spinning and air curing, and performing curing forming in a coagulating bath to obtain basic graphene
oxide fibers; a plurality of fibers are assembled into
nanofiber multifilaments in a coagulating bath, and then the
nanofiber multifilaments enter a subsequent multi-stage combined drafting process to prepare a GO
fiber aggregate; the GO
fiber aggregate is immersed in a Lys-Dopa solution for a reaction, and finally the GO fiber aggregate is collected through a twisting process; reducing the collected GO fibers with
hydroiodic acid to obtain reduced graphene fibers, and then performing high-temperature graphitization treatment to obtain a graphene nanofiber bundle product; the graphene fiber preparation process is improved from multiple aspects of
raw material preparation, spinning and drafting, Lys-Dopa bath, twisting and the like, a new
mechanical property improvement scheme is provided, and development of the graphene fiber field in the future is promoted.