High-temperature-resistant antistatic modified polyamide and preparation method thereof
A polyamide and antistatic technology, applied in the field of polyamide, can solve the problems of polyamide material intrinsic performance influence, poor dispersion of glass fiber, toughness, rigidity decrease, etc., and achieve outstanding comprehensive performance, strong heat resistance and mechanical properties Good results
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Embodiment 1
[0042] S1. Mix chlorobenzyltrichlorosilane, anhydrous toluene, and anhydrous pyridine uniformly to obtain a mixed solution, and add dry glass fibers to the mixed solution to obtain glass fiber A;
[0043] S2. Add 30-70 parts of octadecyldimethyl tertiary amine to chloroform and stir to disperse, add 40-65 parts of glass fiber A, and ultrasonically shake at 55-75°C for 1-2 hours to obtain material A ;
[0044] S3. Add 3,4-ethylenedioxythiophene to the sulfonate solution, stir and react at a speed of 300-500r / min for 30-40min under normal pressure, and stir to obtain material B;
[0045] S4. Melt 100-200 parts of polyamide, mix 20-30 parts of material A and 50-70 parts of material B and add them to the polyamide melt, add 0.2-0.9 parts of antioxidant, 3-7 parts of Toughening agent, 0.2-0.4 parts of water, extruded to granulate, stirred and reacted for 2-4 hours to obtain modified polyamide.
[0046] The mass ratio of chlorobenzyltrichlorosilane, anhydrous toluene and anhydrous...
Embodiment 2
[0052] S1. Mix chlorobenzyltrichlorosilane, anhydrous toluene, and anhydrous pyridine uniformly to obtain a mixed solution, and add dry glass fibers to the mixed solution to obtain glass fiber A;
[0053] S2. Add 30-70 parts of octadecyldimethyl tertiary amine to chloroform and stir to disperse, add 40-65 parts of glass fiber A, and ultrasonically shake at 55-75°C for 1-2 hours to obtain material A ;
[0054] S3. Add 3,4-ethylenedioxythiophene to the sulfonate solution, stir and react at a speed of 300-500r / min for 30-40min under normal pressure, and stir to obtain material B;
[0055] S4. Melt 100-200 parts of polyamide, mix 20-30 parts of material A and 50-70 parts of material B and add them to the polyamide melt, add 0.2-0.9 parts of antioxidant, 3-7 parts of Toughening agent, 0.2-0.4 parts of water, extruded to granulate, stirred and reacted for 2-4 hours to obtain modified polyamide.
[0056] The mass ratio of chlorobenzyltrichlorosilane, anhydrous toluene and anhydrous...
Embodiment 3
[0062] S1. Mix chlorobenzyltrichlorosilane, anhydrous toluene, and anhydrous pyridine uniformly to obtain a mixed solution, and add dry glass fibers to the mixed solution to obtain glass fiber A;
[0063] S2. Add 30-70 parts of octadecyldimethyl tertiary amine to chloroform and stir to disperse, add 40-65 parts of glass fiber A, and ultrasonically shake at 55-75°C for 1-2 hours to obtain material A ;
[0064] S3. Add 3,4-ethylenedioxythiophene to the sulfonate solution, stir and react at a speed of 300-500r / min for 30-40min under normal pressure, and stir to obtain material B;
[0065] S4. Melt 100-200 parts of polyamide, mix 20-30 parts of material A and 50-70 parts of material B and add them to the polyamide melt, add 0.2-0.9 parts of antioxidant, 3-7 parts of Toughening agent, 0.2-0.4 parts of water, extruded to granulate, stirred and reacted for 2-4 hours to obtain modified polyamide.
[0066] The mass ratio of chlorobenzyltrichlorosilane, anhydrous toluene and anhydrous...
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