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A nano-precipitate enhanced body-centered cubic fe x crnial 0.5 ti 0.5 high entropy alloy

A technology of nano-precipitate phase and high-entropy alloy, which is applied in the field of nano-precipitation phase strengthening body-centered cubic high-entropy alloy, can solve the problems of high content of transition group, increase the cost of alloy manufacturing, limit practical application, etc. The performance method is simple and effective, and the preparation cost is low

Active Publication Date: 2022-08-09
INST OF METAL RESEARCH - CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In the above studies, the content of Fe element is low and the content of other transition groups is high, which virtually increases the manufacturing cost of the alloy and limits the practical application of nano-precipitated phase-strengthened body-centered cubic high-entropy alloys.

Method used

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  • A nano-precipitate enhanced body-centered cubic fe  <sub>x</sub> crnial  <sub>0.5</sub> ti  <sub>0.5</sub> high entropy alloy
  • A nano-precipitate enhanced body-centered cubic fe  <sub>x</sub> crnial  <sub>0.5</sub> ti  <sub>0.5</sub> high entropy alloy
  • A nano-precipitate enhanced body-centered cubic fe  <sub>x</sub> crnial  <sub>0.5</sub> ti  <sub>0.5</sub> high entropy alloy

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0039] Fe in this example 2 CrNiAl 0.5 Ti 0.5 (molar ratio), namely Fe2 alloy, the raw material adopts sponge Ti of industrial purity, and the purity of other elements is not less than 99.9wt.%. Arrange the raw materials in the order of decreasing melting point from top to bottom, and use a mechanical pump and a molecular pump to pump the pressure in the furnace to 1.0×10 -3 Pa~3.0×10 -3 Pa, high-purity Ar gas was introduced to about 0.05MPa, and the master alloy ingot was prepared by arc melting under the protection of argon gas, and the alloy ingot was repeatedly smelted five times. The alloy plates with width, thickness and length of 10mm, 5mm and 80mm were obtained by casting in a reversing furnace. The alloy plate was cut by wire EDM and fast saw to obtain a compressed pattern with a size of φ2 mm × 4 mm, and the compressed pattern was ground and polished with sandpaper.

[0040] The Fe2 as-cast alloy plate was sliced ​​to a thickness of about 1 mm, and the as-cast s...

Embodiment 2

[0043] Fe in this example 4 CrNiAl 0.5 Ti 0.5 (molar ratio), namely Fe4 alloy, the raw material adopts sponge Ti of industrial purity, and the purity of other elements is not less than 99.9wt.%. Arrange the raw materials in the order of decreasing melting point from top to bottom, and use a mechanical pump and a molecular pump to pump the pressure in the furnace to 1.0×10 -3 Pa~3.0×10 -3 Pa, high-purity Ar gas was introduced to about 0.05MPa, and the master alloy ingot was prepared by arc melting under the protection of argon gas, and the alloy ingot was repeatedly smelted five times. The alloy plates with width, thickness and length of 10mm, 5mm and 80mm were obtained by casting in a reversing furnace. The size of the compressed pattern is φ2mm × 4mm by cutting the alloy plate by wire electric discharge cutting and fast saw, and grinding and polishing the compressed pattern with sandpaper.

[0044] The Fe4 as-cast alloy plate was sliced ​​to a thickness of about 1 mm, an...

Embodiment 3

[0047] Fe in this example 6 CrNiAl 0.5 Ti 0.5 (molar ratio), namely Fe6 alloy, the raw material adopts sponge Ti of industrial purity, and the purity of other elements is not less than 99.9wt.%. Arrange the raw materials in the order of decreasing melting point from top to bottom, and use a mechanical pump and a molecular pump to pump the pressure in the furnace to 1.0×10 -3 Pa~3.0×10 -3 Pa, high-purity Ar gas was introduced to about 0.05MPa, and the master alloy ingot was prepared by arc melting under the protection of argon gas, and the alloy ingot was repeatedly smelted five times. The alloy plates with width, thickness and length of 10mm, 5mm and 80mm were obtained by casting in a reversing furnace. The size of the compressed pattern is φ2mm × 4mm by cutting the alloy plate by wire electric discharge cutting and fast saw, and grinding and polishing the compressed pattern with sandpaper.

[0048] The Fe6 as-cast alloy plate was sliced ​​to a thickness of about 1 mm, an...

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Abstract

The present invention involves nano -analyzed phase -strengthening cubic cubic high -entropy alloys, specifically a nano -analyzed enhanced body heart cube x Crnial 0.5 TI 0.5 High entropy alloys. The range of the alloy is changed in accordance with the following principles: Fe x Crnial 0.5 TI 0.5 (Moorebi), x = 2, 4 or 6. Its performance indicators are: compression and yield strength is 1008MPa to 1260MPa, and the pressure resistance strength is 1791MPa to 2083MPa; the compression strain is higher than 35 %, and even the compression process is not broken. By changing the FE element content, the present invention can obtain a large amount of diffuse and relative content and controllable shape size. 1 Nano analyzes the phase; in addition, by adding the FE element, it is found that the Fe element is found in L2 1 The content of nano -precipitated phase continues to increase, which will affect L2 1 The performance of nano analysis; these two factors lead to FE adding can significantly regulate cubic / spherical nano -analysis of the phase enhancement of the body heart x Crnial 0.5 TI 0.5 The tissue performance of high entropy alloys is of great value for nano -analysis of the development and application of high -entropy alloys in the relevant alloy system and related alloy system.

Description

technical field [0001] The invention relates to the field of nano-precipitated phase strengthening body-centered cubic high-entropy alloys, in particular to a nano-precipitating phase strengthening body-centered cubic Fe alloy x CrNiAl 0.5 Ti 0.5 High-entropy alloys. Background technique [0002] High-entropy alloys are a new class of metal materials formed by alloying a variety of elements in an equiatomic or near-equiatomic ratio. Different from the traditional one-element or binary-based alloy design ideas, the subversive alloy design concept of high-entropy alloys makes them have unique atomic structure characteristics, thus showing many excellent mechanical, physical and chemical properties. But its organizational performance still needs to be improved. It is well known that second-phase strengthening can significantly improve the comprehensive mechanical properties of materials compared with other strengthening methods. In recent years, the precipitation strengthe...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22C30/00
CPCC22C30/00C22C38/06C22C38/50Y02P10/25
Inventor 张龙纪宇张海峰朱正旺张宏伟付华萌李宏王爱民
Owner INST OF METAL RESEARCH - CHINESE ACAD OF SCI