Pressure-sensitive adhesive tape
A pressure-sensitive adhesive, pressure-sensitive adhesive technology, applied in the direction of adhesive type, pressure-sensitive film/sheet, ester copolymer adhesive, etc., can solve problems such as tearing and adhesion reduction
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[0157] Now, the present invention will be specifically described by way of examples. However, the present invention is by no means limited to the Examples. Tests and evaluation methods in Examples and the like are as follows. Unless otherwise specified, the term "part" in the following description means "weight part", and unless otherwise specified, the term "%" in the following description means "wt%".
[0158]
[0159] The weight-average molecular weight is determined from a value in terms of standard polystyrene obtained by gel permeation chromatography (GPC). An apparatus available under the model number "HLC-8320GPC" (column: TSKgel GMH-H(S), manufactured by Tosoh Corporation) was used as the GPC apparatus.
[0160]
[0161] The double-sided pressure-sensitive adhesive tapes obtained in each of Examples and Comparative Examples were cut into a size of 10 mm wide by 50 mm long to manufacture test pieces. The test piece was pulled up and down in each vertical directi...
manufacture example 1
[0172] [Manufacture Example 1]: Manufacture of pressure-sensitive adhesive layer (1)
[0173] 95 parts of butyl acrylate (BA) and 5 parts of acrylic acid (AA) as monomer components, and 233 parts of ethyl acetate as a polymerization solvent were charged into a device including a stirrer, a thermometer, a nitrogen gas introduction tube, a reflux condenser, and a dropping liquid funneled reaction vessel and stirred for 2 hours while introducing nitrogen gas into the vessel. After the oxygen in the polymerization system has been removed as described above, 0.2 parts of 2,2′-azobisisobutyronitrile is added to the mixture as a polymerization initiator, and the whole is subjected to solution polymerization at 60° C. for 8 hours, thereby A solution of an acrylic polymer is provided. The weight average molecular weight of the acrylic polymer was 700,000.
[0174] With respect to 100 parts of the acrylic polymer in the obtained acrylic polymer solution, 20 parts of terpene-phenol res...
manufacture example 2
[0176] [Manufacture Example 2]: Manufacture of pressure-sensitive adhesive layer (2)
[0177] A pressure-sensitive adhesive layer ( 2 ) having a thickness of 80.0 μm was formed in the same manner as in Production Example 1 except that the thickness of the final pressure-sensitive adhesive layer was set to 80.0 μm.
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