Compound for organic electric element, organic electric element using same, and electronic device thereof
A compound and chemical formula technology applied to compounds used in organic electronic components can solve the problems of insufficient realization and achieve the effects of low driving voltage, high heat resistance, and high luminous efficiency
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Synthetic example
[0142] As shown in Reaction Formula 1 below, compounds represented by Chemical Formula 1 (final products) according to the present invention are synthesized by reacting Sub 1 and Sub 2, but are not limited thereto.
[0143] Shown in the following reaction formula 1, X, R 1 、Ar 1 to r 5 , L 1 to L 3 and a are the same as those described above in the section related to Chemical Formula 1. Pd described in the synthesis examples of this specification 2 (dba) 3 For three (dibenzylideneacetone) dipalladium (0).
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[0146] Synthesis example of I.Sub 1
[0147] Sub 1 of Reaction Formula 1 can be synthesized through the reaction scheme of Reaction Formula 2 below, but is not limited thereto.
[0148]
[0149]
[0150] Sub 1-I of Reaction Formula 2 can be synthesized through the following reaction schemes 3 to 4, but is not limited thereto.
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[0155] 1. Synthesis example of Sub 1-1
[0156] (1)Sub 1-I-1 syn...
Embodiment 1
[0276] [Example 1] Red organic electroluminescence element (luminescence auxiliary layer)
[0277] An organic electroluminescent element is manufactured using the compound of the present invention as a material for an emission-assisting layer according to a conventional method. First, 4,4',4"-tris[2-naphthyl(phenyl)amino]triphenylamine (hereinafter referred to as 2-TNATA ) to a thickness of 60nm to form a hole injection layer. Then, on the hole injection layer, vacuum deposit N, N'-bis(1-naphthyl)-N,N'-bisphenyl-(1,1 '-biphenyl)-4,4'-diamine (hereinafter referred to as NPB) to a thickness of 60nm to form a hole transport layer. Subsequently, on the hole transport layer, the compound P-1 of the present invention is vacuum-deposited to After forming the luminescence auxiliary layer with a thickness of 20nm, 4,4'-N,N'-dicarbazole-biphenyl (hereinafter referred to as CBP) was used as the host material on the luminescence auxiliary layer, and bis-(1-phenyl Isoquinolyl) iridium (I...
Embodiment 17
[0278] [Example 2] to [Example 17] Red organic electroluminescence element (luminescence auxiliary layer)
[0279] Organic electroluminescence was produced in the same manner as in Example 1, except that Compounds P-3 to P-98 of the present invention described in Table 5 below were used instead of Compound P-1 of the present invention as the material for the light-emitting auxiliary layer. element.
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