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Combined luminescent material and application thereof

A technology of luminescent materials and fluorescent materials, applied in the field of combined luminescent materials, can solve the problems of low light extraction efficiency of devices, hindering theoretical efficiency of devices, and limiting the promotion of diodes, etc.

Active Publication Date: 2021-08-06
SOUTH CHINA UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, in OLEDs, due to the large gap between the refractive index of the organic layer (n≈1.7-2.0) and the glass substrate (n≈1.5) and air (n≈1.0), when the carrier When recombining in the light-emitting layer and radiating light outward, if the light is incident on the substrate at an angle greater than the critical angle, due to the waveguide mode, the light will be fully emitted at the interface between the glass substrate and the organic layer, and thus be confined in the organic layer. ; Similarly, if the light is emitted from the substrate to the air at an angle greater than the critical angle, due to the substrate mode, the light will be totally reflected at the interface between the glass substrate and the air, causing the light to be confined in the glass substrate; The extraction efficiency is low, which hinders the improvement of the theoretical efficiency of the device
[0004] Therefore, the external quantum efficiency of organic light-emitting diodes is low, and the low efficiency limits the promotion of diode applications.

Method used

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  • Combined luminescent material and application thereof
  • Combined luminescent material and application thereof
  • Combined luminescent material and application thereof

Examples

Experimental program
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Embodiment 1

[0099] This embodiment provides a combined luminescent material, wherein:

[0100] Includes 5 wt% of the object, and 95 wt% of the main material;

[0101] The main material is DSPiroac-TRZ, which is a thermally activated delay fluorescence having a high transition dipole moment, and a single three-line exchange energy is 0.04 eV, and the preparation method is as shown in the formula (1);

[0102] The object material is TPA-AQ, and the preparation method is as shown in equation (8).

Embodiment 2

[0104] This embodiment provides a combined luminescent material, wherein:

[0105] Includes 5 wt% of the object, and 95 wt% of the main material;

[0106] The main material is DSPiros-TRZ, which is a thermally activated delay fluorescence having a high transition dipole moment, and a single three-line exchange energy is 0.05 eV, and the preparation method is as shown in formula (2);

[0107] The object material is the same as the object material used in Example 1.

Embodiment 3

[0109] This embodiment provides a combined luminescent material, wherein:

[0110] Includes 5 wt% of the object, and 95 wt% of the main material;

[0111] The main material is the same as in Example 1;

[0112] The object material is DBXZ-2FDBPZ, and the preparation method is as shown in equation (9).

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Abstract

The invention discloses a combined luminescent material and application thereof, and belongs to the technical field of luminescent materials. The combined luminescent material comprises a host material and a guest material, the transition dipole moment horizontal orientation degree of the host material is greater than 80%; and the guest material is at least one of a thermally activated delayed fluorescent material and a conventional fluorescent material. The host material with the transition dipole moment horizontal orientation degree larger than 80% and the light-emitting guest material are combined, the host material can sensitize the guest material, then the transition dipole moment horizontal orientation degree of the guest material is improved, and after the material is used for a light-emitting diode, the light extraction efficiency and the external quantum efficiency of the diode can be improved.

Description

Technical field [0001] The present invention belongs to the technical field of luminescent materials, and more particularly to a combined luminescent material and its application thereof. Background technique [0002] Organic Light Emitting Diodes (OLED) has high color contrast, fast response speed, low power consumption, no blue-ray harm, and flexible display, has been applied in solid-state lighting and display, and has good application prospects. [0003] The existing organic luminescent materials have: In 1998, Professor, Princeton University, developed phosphorescent materials containing heavy metal atoms, as well as professor of Adachi, Japan, Japan, etc., etc., etc., has developed heat activation delays with smaller single three-line energy gap. Fluorescent material. These materials can effectively utilize the three-line excitons to achieve luminescence, in theory, 100% internal quantum efficiency can be realized, that is, to a large extent, the efficiency of organic light...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C07D401/10C07D495/10C07C225/24C07C221/00C07D413/14C09K11/06C09K11/07H01L51/50H01L51/54
CPCC07D401/10C07D495/10C07C225/24C07C221/00C07D413/14C09K11/06C09K11/07C09K2211/1029C09K2211/1059C09K2211/1037C09K2211/1014C09K2211/1011C09K2211/1033C09K2211/1044H10K85/615H10K85/631H10K85/654H10K85/6572H10K85/657H10K50/121
Inventor 苏仕健李文琪刘坤坤李伟彭晓媚
Owner SOUTH CHINA UNIV OF TECH
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