Low-carbon magnesia carbon brick with oxidation resistance and preparation method thereof
A technology of anti-oxidation performance and carbon-magnesium-carbon bricks, applied in the field of refractory materials, can solve the problems of product structure deterioration, reducing the service life of MgO-C bricks, corroding MgO particles, etc., and achieving high thermal shock stability and anti-oxidation performance. Good, improve antioxidant effect
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[0031] The present invention also provides a method for preparing low-carbon magnesia-carbon bricks with anti-oxidation properties as described in any one of the above, comprising the following preparation steps:
[0032] After dry mixing the fused magnesia, add resin, the speed of adding resin is 15kg / min, then add -196 graphite, mix for 5-10min, add high temperature asphalt, after stirring, finally add metal aluminum powder and ZrB 2 -Cr 7 C 3 Composite materials, after stirring evenly, obtain low-carbon magnesia-carbon brick preparation materials;
[0033] The low-carbon magnesia-carbon brick preparation material is put into the mold, pressed and formed to obtain brick embryos;
[0034] The brick embryos are pushed into a heat treatment kiln for heat treatment to obtain low-carbon magnesia carbon bricks.
[0035] Preferably, during pressing, a 1000T electric screw press is used for pressing; during heat treatment, the temperature inside the heat treatment kiln is 180°C-2...
Embodiment 1
[0039] Preparation of low-carbon magnesia-carbon bricks with excellent oxidation resistance (sample 1):
[0040] In parts by weight, it includes 95 parts of fused magnesia, 1 part of metal aluminum powder, 3 parts of liquid phenolic resin, ZrB 2 -Cr 7 C 3 1 part of composite material, 1 part of high-temperature pitch and 2 parts of -196 graphite.
[0041] 101) According to the parts by weight, after dry mixing the fused magnesia, add liquid phenolic resin, the liquid phenolic resin is added at a rate of 10~15kg / min, then add -196 graphite, mix for 5-10min, add high temperature asphalt, After stirring, finally add metal aluminum powder and ZrB 2 -Cr7 C 3 Composite materials, after stirring evenly, obtain low-carbon magnesia-carbon brick preparation materials;
[0042] 102) The low-carbon magnesia-carbon brick preparation material is put into the mould, pressed and formed, and the brick embryo is obtained;
[0043] 103) Push the brick embryo into a heat treatment kiln for ...
Embodiment 2
[0048] Preparation of low-carbon magnesia-carbon bricks with excellent oxidation resistance (sample 2):
[0049] In parts by weight, it includes 94 parts of fused magnesia, 1 part of metal aluminum powder, 3 parts of liquid phenolic resin, ZrB 2 -Cr 7 C 3 2 parts of composite material, 1 part of high-temperature pitch and 2 parts of -196 graphite.
[0050] 201) According to the number of parts by weight, after dry mixing the fused magnesia, add liquid phenolic resin, the liquid phenolic resin is added at a rate of 10~15kg / min, then add -196 graphite, mix for 5-10min, add high temperature asphalt, After stirring, finally add metal aluminum powder and ZrB 2 -Cr 7 C 3 Composite materials, after stirring evenly, obtain low-carbon magnesia-carbon brick preparation materials;
[0051] 202) The low-carbon magnesia-carbon brick preparation material is put into the mould, pressed and formed to obtain the brick embryo;
[0052] 203) Push the brick embryo into a heat treatment kil...
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