Emulsifier for remote distribution of emulsion matrix and preparation method and application thereof

A latex matrix and emulsifier technology, which is applied in the direction of offensive equipment, non-explosive/non-thermal agent components, explosives, etc., can solve the problems of difficult remote distribution of latex matrix, poor anti-turbulence and pumping performance, and poor fluidity. Good anti-turbulence and pumping performance, good emulsification stability, and good storage stability

Active Publication Date: 2021-10-12
CHINA GEZHOUBA GRP YIPULI CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] At present, the latex matrix prepared by these polymer emulsifiers has good storage stability, but has poor anti-turbulence and pumping performance, and has high dynamic visc

Method used

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  • Emulsifier for remote distribution of emulsion matrix and preparation method and application thereof
  • Emulsifier for remote distribution of emulsion matrix and preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] The raw materials of the emulsifier in this embodiment are: polypropylene succinic anhydride for polyolefin carboxylic anhydride, neopentyl glycol for alcohol, adipic hydrazide for dihydrazide, and 60SN base oil for diluent oil.

[0032] A preparation method for an emulsifier for latex matrix remote distribution, comprising the following steps:

[0033] S1, adding 1mol polypropylene succinic anhydride in the reactor;

[0034] S2, feed ammonia in the reactor;

[0035] S3, add 1.1mol of neopentyl glycol in the reactor, weigh the weight of 60SN base oil so that the quality of 60SN base oil is 0.8 times of 1mol of polypropylene succinic anhydride, then add 60SN base oil, heat up to 120 ℃, keep warm for 2h;

[0036] S4. Heat up to 170°C, add 0.8 mol of adipic hydrazide under ammonia gas, and keep stirring for 4 hours;

[0037] S5. Obtain the finished product after filtering while it is hot.

Embodiment 2

[0039] The raw materials of the emulsifier in this embodiment are: polyisobutylene succinic anhydride for polyolefin carboxylic anhydride, 1,6-hexanediol for alcohol, glutaryl hydrazide for dihydrazide, and 220SN base oil for diluent oil.

[0040] A preparation method for an emulsifier for latex matrix remote distribution, comprising the following steps:

[0041] S1, add 1mol polyisobutylene succinic anhydride in the reactor;

[0042] S2, feed ammonia in the reactor;

[0043] S3, add 1.2mol of 1,6-hexanediol in the reactor, weigh the weight of 220SN base oil so that the quality of 220SN base oil is the same as the quality of 1mol polyisobutylene succinic anhydride, then add 220SN base oil, and heat up Heat to 110°C, keep warm for 3h;

[0044] S4. Heating up to 160°C, adding 0.7 mol of glutaryl hydrazide under ammonia gas, and stirring for 6 hours while insulated;

[0045] S5. Obtain the finished product after filtering while it is hot.

Embodiment 3

[0047] The raw materials of the emulsifier in this embodiment are: polypentene succinic anhydride is selected for polyolefin carboxylic anhydride, trimethylolpropane is selected for alcohol, pimelic hydrazide is selected for dihydrazide, and 150SN base oil is selected for diluent oil.

[0048] A preparation method for an emulsifier for latex matrix remote distribution, comprising the following steps:

[0049] S1, add the polypentene succinic anhydride of 1mol in reactor;

[0050] S2, feed ammonia in the reactor;

[0051] S3, add the trimethylol propane of 1mol in reactor, weigh the weight of 150SN base oil so that the quality of 150SN base oil is 0.5 times of the polypentene succinic anhydride of 1mol, then add 150SN base oil, heat up to 120℃, keep warm for 3h;

[0052] S4. Heat up to 180°C, add 1 mol of pimelic hydrazide under ammonia gas, and keep stirring for 4 hours;

[0053] S5. Obtain the finished product after filtering while it is hot.

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Abstract

The invention discloses an emulsifier for remote distribution of an emulsion matrix and a preparation method and application thereof, the emulsifier comprises polyolefin carboxylic acid anhydride, alcohol or polyoxyethylene alkyl ether, dihydrazide and diluent oil, the molar ratio of the polyolefin carboxylic acid anhydride to the alcohol or polyoxyethylene alkyl ether to the dihydrazide is 1.0: (0.5-1.2): (0.5-1.2), and the mass of the diluent oil is 0.3-1 time that of the polyolefin carboxylic acid anhydride; the preparation method comprises the following steps: S1, adding polyolefin carboxylic acid anhydride into a reaction kettle; s2, introducing protective gas into the reaction kettle; s3, adding alcohol or polyoxyethylene alkyl ether into the reaction kettle, adding diluent oil, heating to 100-120 DEG C, and keeping the temperature for 2-3 hours; s4, adding dihydrazide under a protective gas, increasing the temperature to 160-180 DEG C, and performing heat preservation and stirring for 4-6 h; and s5, filtering while the mixture is hot to obtain filtrate which is an emulsifier finished product; and the emulsion matrix prepared from the prepared emulsifier is good in fluidity, stable in storage, excellent in bumping resistance and pumping resistance, and suitable for remote distribution of the emulsion matrix.

Description

technical field [0001] The invention relates to the technical field of industrial explosive production, in particular to an emulsifier for remote distribution of latex matrix and its preparation method and application. Background technique [0002] As a key component of emulsion explosives, emulsifiers have a significant impact on the quality of the emulsified system, the size of internal phase ions, stability and detonation performance. [0003] The low-molecular-weight emulsifier represented by Span-80 has high emulsification efficiency and low cost, which can satisfy the production of conventional emulsion explosives. However, the emulsion particles form micelles, and the interface forms a film that is not tightly packed. Because the formed film is very thin (thickness about ), there is no elastic frame structure, so the interface film has insufficient elasticity, is easy to age, crack, has poor stability, and has a short shelf life. [0004] In the emulsification syst...

Claims

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Application Information

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IPC IPC(8): C08F10/06C08F10/08C08F10/10C08F10/14C08F8/30C08F8/14C06B23/00
CPCC08F8/30C06B23/009C08F8/14C08F10/06C08F10/10C08F10/14C08F10/08
Inventor 赵华平董云李俊杰
Owner CHINA GEZHOUBA GRP YIPULI CO LTD
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