High-compaction rate type lithium ion battery negative electrode material and preparation method thereof
A technology for lithium-ion batteries and negative electrode materials, applied in battery electrodes, secondary batteries, chemical instruments and methods, etc., can solve the problems of low energy density of lithium-ion batteries, limiting the application of lithium-ion batteries, and low performance of high-current charging and discharging , to achieve the effects of reducing glue consumption, easy quality control, and improving processing performance
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Embodiment 1
[0022] 1) Shaping the petroleum coke through coarse crushing and fine crushing to obtain a fine powder with a D50 particle size of 5 μm;
[0023] 2) mixing the fine powder obtained in step 1) with asphalt according to a ratio of 97:3 to obtain a mixed powder;
[0024] 3) The mixed powder obtained in step 2) is subjected to surface modification treatment in a drum furnace at 650° C. for 8 hours under the protection of a nitrogen atmosphere to obtain secondary particles with a D50 of 13 μm;
[0025] 4) The secondary particles obtained in step 3) were spheroidized in a spheroidizer with a rotating speed of 400r / min for 2 minutes to obtain a spheroidized material with a D50 particle size of 9 μm and D90 / D10=4.3;
[0026] 5) The spheroidized material obtained in step 4) is graphitized at a high temperature of 2600° C. for 20 hours to obtain a lithium ion battery negative electrode material.
Embodiment 2
[0029] 1) The pitch coke is firstly dried, coarsely crushed, finely crushed, and then shaped to obtain a fine powder with a D50 particle size of 10 μm;
[0030] 2) mixing the fine powder obtained in step 1) with asphalt according to a ratio of 95:5 to obtain a mixed powder;
[0031] 3) The mixed powder obtained in step 2) is subjected to surface modification treatment in a drum furnace at 600° C. for 10 h under the protection of a nitrogen atmosphere to obtain secondary particles with a D50 particle size value of 15 μm;
[0032] 4) The secondary particles obtained in step 3) were spheroidized for 4 minutes in a spheroidizer with a rotating speed of 600 r / min, and the D50 particle size value was 12 μm, and D90 / D10=6.1;
[0033] 5) The spheroidized material obtained in step (4) is graphitized at a high temperature of 3000° C. for 28 hours to obtain the lithium ion battery negative electrode material.
Embodiment 3
[0035] This embodiment provides a high compaction rate type lithium-ion battery negative electrode material production method, including the following steps:
[0036] 1) The needle coke is firstly dried, coarsely crushed, and finely crushed, and then shaped to obtain a fine powder with a D50 particle size of 8 μm;
[0037] 2) mixing the fine powder obtained in step 1) with asphalt according to a ratio of 90:10 to obtain a mixed powder;
[0038] 3) The mixed powder obtained in step 2) is subjected to surface modification treatment at 680° C. for 10 h under the protection of a nitrogen atmosphere to obtain secondary particles with a D50 particle size value of 14 μm;
[0039] 4) The secondary particles obtained in step 3) were spheroidized in a spheroidizer with a rotating speed of 800r / min for 5 minutes to obtain a D50 particle size of 10 μm, D90 / D10=5.1;
[0040] 5) The spheroidized material obtained in step 4) is graphitized at a high temperature of 3000° C. for 24 hours to o...
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Abstract
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Application Information
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