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High-wear-resistance and high-water-contact-angle hardened film

A contact angle, hardened film technology, applied in coatings, polyurea/polyurethane coatings, etc., can solve the problems of increased material cost and process cost, high manufacturing cost, low adhesion, etc., and achieves stable solvent-resistant wiping performance, The effect of friction stability and high water contact angle

Active Publication Date: 2022-01-14
NINGBO HUGHSTAR ADVANCED MATERIAL TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In this film, since the adhesion between the primer layer and the AF layer is not high, in order to improve the bonding firmness between the two and ensure the wear resistance, an additional bonding stability layer is added to ensure that the primer layer and the AF layer The firmness of the combination leads to its complicated process, which increases the material cost and process cost, and the manufacturing cost is relatively high

Method used

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  • High-wear-resistance and high-water-contact-angle hardened film

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] Embodiment 1: A kind of high wear-resisting high water contact angle sclerosis film, comprises the transparent base material, primer layer and AF layer that are bonded successively from bottom to top, base coat is coated on transparent base material by primer solution Photocuring is formed, and the AF layer is formed by coating the AF coating solution on the primer layer and thermosetting. The material components of the primer solution are: 38 parts by weight of polyurethane acrylate resin oligomer, 2 parts by weight of Allyl modified terminal allyl phenolic resin, 1 weight part of photoinitiator, 0.5 weight part of leveling agent and 60 weight parts of organic solvent, AF coating solution includes a solid content of 1% of the end group is Silicone modified perfluoropolyether coating solution.

[0020] Among them, the urethane acrylate resin oligomer is aliphatic urethane acrylate with 6 functionalities, and the specific choice is the resin of R0310 from Huizhixing Comp...

Embodiment 2

[0021] Embodiment 2: A kind of high wear-resisting high-water contact angle sclerosis film, comprises the transparent base material, primer layer and AF layer that are laminated successively from bottom to top, and base coat is coated on transparent base material by primer liquid Photocuring is formed, and the AF layer is formed by coating the AF coating solution on the primer layer and thermosetting. The material components of the primer solution are: 42 parts by weight of polyurethane acrylate resin oligomer, 5 parts by weight of Allyl modified terminal allyl phenolic resin, 1.5 parts by weight of photoinitiator, 0.7 parts by weight of leveling agent and 43 parts by weight of organic solvent, the AF coating solution includes a solid content of 1% of the end group is Silicone modified perfluoropolyether coating solution.

[0022] Among them, the urethane acrylate resin oligomer is aliphatic urethane acrylate with 6 functionalities, and the specific choice is the resin of R031...

Embodiment 3

[0023] Embodiment 3: A kind of high wear-resistant high-water contact angle sclerosis film, comprises the transparent base material, base coat and AF layer that are bonded successively from bottom to top, and base coat is coated on transparent base material by primer liquid Photocuring is formed, and the AF layer is formed by coating the AF coating solution on the primer layer and thermosetting. The material components of the primer solution are: 40 parts by weight of polyurethane acrylate resin oligomer, 20 parts by weight of Allyl modified terminal allyl phenolic resin, 2 weight parts photoinitiator, 0.9 weight parts leveling agent and 48 weight parts organic solvents, AF coating solution includes solid content of 1% end group is Silicone modified perfluoropolyether coating solution.

[0024]Among them, the urethane acrylate resin oligomer is aliphatic urethane acrylate with 6 functionalities, and the specific choice is the resin of R0310 from Huizhixing Company; the termina...

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Abstract

The invention discloses a high-wear-resistance and high-water-contact-angle hardened film which comprises a transparent base material, a bottom coating layer and an AF layer which are sequentially attached from bottom to top; the bottom coating layer is formed by coating the transparent base material with a bottom coating solution for light curing, the AF layer is formed by coating the bottom coating layer with an AF coating solution for heat curing, and the bottom coating solution comprises the components in parts by weight: 10 to 50 parts by weight of a polyurethane acrylate resin oligomer with the functionality of 4 to 20 and the molecular weight of 800 to 5000, 2 to 30 parts by weight of allyl-modified terminal allyl phenolic resin with the functionality of 5 to 30 and the molecular weight of 500 to 5000, 0.3 to 3 parts by weight of a flatting agent, 0.5 to 2.5 parts by weight of a photoinitiator, and 30 to 80 parts by weight of an organic solvent; and an AF coating liquid is a perfluoropolyether coating liquid with the solid content of 0.1% to 2% and with an end group modified by siloxane. The high-wear-resistance and high-water-contact-angle hardened film has the advantages of low friction coefficient, high water contact angle, simple process, low manufacturing cost and benefit for mass production.

Description

technical field [0001] The invention relates to a hardened film, in particular to a hardened film with high wear resistance and high water contact angle. Background technique [0002] With the popularization of electronic products such as smart phones, these electronic products have increasingly become an indispensable part of people's daily life. Because of this, people's demand for electronic products has gradually extended from the pure product performance to more stable, faster and more convenient products, and gradually extends to the requirement that the products themselves have waterproof, no fingerprints after touching, and super smooth touch. sexual needs. In particular, the ultra-smooth touch of the electronic screen is the ultimate experience pursued by countless mobile game players. In order to increase consumers' excellent experience and satisfaction with smart phones and other electronic products, the anti-fingerprint (AFAnti-fingerprint) and super smooth eff...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08J7/043C08J7/046C08L67/02C08L1/12C08L69/00C08L23/06C08L23/12C08L79/08C08L33/12C08L75/04C09D175/14C09D161/14
CPCC08J7/043C08J7/046C08J7/042C09D175/14C09D161/14C08J2367/02C08J2301/12C08J2369/00C08J2323/06C08J2323/12C08J2379/08C08J2333/12C08J2375/04C08J2475/14C08J2471/00C08L61/14
Inventor 汪阳邹清清刘楷楷
Owner NINGBO HUGHSTAR ADVANCED MATERIAL TECH
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