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Low-temperature shell-forming high-hardness ceramic flame-retardant polyethylene cable material and preparation method thereof

A ceramicized flame retardant, high-density polyethylene technology, applied in circuits, electrical components, plastic/resin/wax insulators, etc., can solve the problems of large amount of flame retardant, loss of mechanical properties, poor flame retardant performance of PE, etc. , to achieve the effect of reducing processing thickness, excellent mechanical properties, and simple and easy-to-operate preparation methods

Pending Publication Date: 2022-01-21
JIANGSU SHANGSHANG CABLE GRP NEW MATERIAL CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the flame retardancy of PE is poor, and the cables made are easy to burn and cause fires under high pressure, high temperature, discharge and other external conditions, so PE plastics need to be treated with flame retardancy
Although there are many related reports on the flame retardancy of PE plastics, there are still problems such as large amount of flame retardants added and serious loss of mechanical properties.

Method used

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  • Low-temperature shell-forming high-hardness ceramic flame-retardant polyethylene cable material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] The raw material of a low-temperature shell-forming high-hardness vitrified flame-retardant polyethylene cable material includes the following components: 30 parts of high-density polyethylene, 30 parts of linear low-density polyethylene, 20 parts of ethylene-vinyl acetate copolymer, ethylene-octyl 8 parts of vinyl copolymer elastomer, 10 parts of maleic anhydride graft copolymer elastomer, 2 parts of color masterbatch, 60 parts of nano-ceramic shell forming agent, 15 parts of kaolin, 30 parts of aluminum hydroxide, 13 parts of magnesium hydroxide, 25 parts of zinc borate, 5 parts of nano-montmorillonite, 1 part of tetrakis[3-(3,5-di-tert-butyl-4-hydroxyphenyl) propionate] pentaerythritol ester, 2,4-di-tert-butylphenyl ) 1 part of phosphite triester, 1 part of stearic acid and 2 parts of vinyl tris (β-methoxyethoxy) silane.

[0024] The preparation method of the above-mentioned low-temperature shell-forming high-hardness ceramicized flame-retardant polyethylene cable ma...

Embodiment 2

[0028] The raw material of a low-temperature shell-forming high-hardness vitrified flame-retardant polyethylene cable material includes the following components: 40 parts of high-density polyethylene, 20 parts of linear low-density polyethylene, 15 parts of ethylene-vinyl acetate copolymer, ethylene-octyl 15 parts of vinyl copolymer elastomer, 10 parts of maleic anhydride graft copolymer elastomer, 2 parts of color masterbatch, 70 parts of nano-ceramic shell forming agent, 20 parts of kaolin, 20 parts of aluminum hydroxide, 30 parts of magnesium hydroxide, 20 parts of zinc borate, 4 parts of nano-montmorillonite, 1 part of tetrakis[3-(3,5-di-tert-butyl-4-hydroxyphenyl) propionate] pentaerythritol ester, 2,4-di-tert-butylphenyl ) 1 part of phosphite triester, 1 part of stearic acid and 2 parts of vinyl tris (β-methoxyethoxy) silane. The preparation method refers to Example 1.

Embodiment 3

[0030] The raw material of a low-temperature shell-forming high-hardness vitrified flame-retardant polyethylene cable material includes the following components: 40 parts of high-density polyethylene, 20 parts of linear low-density polyethylene, 15 parts of ethylene-vinyl acetate copolymer, ethylene-octyl 15 parts of vinyl copolymer elastomer, 10 parts of maleic anhydride graft copolymer elastomer, 2 parts of color masterbatch, 80 parts of nano-ceramic shell forming agent, 30 parts of kaolin, 15 parts of aluminum hydroxide, 15 parts of magnesium hydroxide, 30 parts of zinc borate, 6 parts of nano-montmorillonite, 1 part of tetrakis[3-(3,5-di-tert-butyl-4-hydroxyphenyl) propionate] pentaerythritol ester, 2,4-di-tert-butylphenyl ) 1 part of phosphite triester, 1 part of stearic acid and 2 parts of vinyl tris (β-methoxyethoxy) silane. The preparation method refers to Example 1. The properties of the materials obtained in each example are shown in Table 1.

[0031] The performan...

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Abstract

The invention discloses a low-temperature shell-forming high-hardness ceramic flame-retardant polyethylene cable material and a preparation method thereof.The low-temperature shell-forming high-hardness ceramic flame-retardant polyethylene cable material is prepared from 30-50 parts of high-density polyethylene, 20-40 parts of linear low-density polyethylene, 10-20 parts of an ethylene-vinyl acetate copolymer, 5-16 parts of an ethylene-octene copolymer elastomer, 8 to 12 parts of a maleic anhydride grafted copolymer elastomer, 1 to 2 parts of a color master batch, 50 to 80 parts of a nano ceramic shell forming agent, 15 to 30 parts of kaolin, 15 to 30 parts of aluminum hydroxide, 10 to 35 parts of magnesium hydroxide, 20 to 30 parts of zinc borate, 3 to 8 parts of nano montmorillonite, 1 to 2 parts of an antioxidant and 0.5 to 1 part of stearic acid. The cable material disclosed by the invention has excellent mechanical property and environmental stress cracking resistance, the processing thickness of a cable outer sheath is greatly reduced, and the material is ensured to form a high-hardness ceramic shell in a combustion process; the material is free of any halogen and heavy metal salt compounds, so that the environment-friendly characteristic of the insulating material is ensured; and the preparation method is simple and easy to operate.

Description

technical field [0001] The invention relates to a low-temperature shell-formed high-hardness ceramic flame-retardant polyethylene cable material and a preparation method thereof, belonging to the technical field of cable materials. Background technique [0002] Polyethylene (PE) has excellent processability, mechanical properties and electrical insulation properties, and is widely used in the cable industry. However, the flame retardancy of PE is poor, and the cables made are easy to burn and cause fire under external conditions such as high pressure, high temperature, and discharge, so PE plastics need to be flame retardant treated. Although there are many related reports on the flame retardancy of PE plastics, there are still problems such as large amount of flame retardants added and serious loss of mechanical properties. Contents of the invention [0003] The invention provides a low-temperature shell-forming high-hardness ceramicized flame-retardant polyethylene cabl...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/06C08L23/08C08K3/34C08K3/22C08K3/38C08K3/00C08K9/10C08K9/06C08K9/04C08K13/06H01B3/44
CPCC08L23/06C08L23/0815H01B3/441C08L2201/02C08L2203/202C08L2207/062C08K2201/011C08K2003/2227C08K2003/2224C08K2003/387C08L23/0853C08K3/346C08K3/22C08K3/38C08K3/00C08K9/10C08K9/06C08K9/04C08K13/06
Inventor 孙佳林刘雄军李斌凌国桢狄洪杰王相文
Owner JIANGSU SHANGSHANG CABLE GRP NEW MATERIAL CO LTD
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