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Preparation method of integrated asymmetric supercapacitor

A supercapacitor, asymmetric technology, used in the manufacture of hybrid/electric double layer capacitors, hybrid capacitor electrolytes, etc., can solve the problems of small voltage window of supercapacitors, easy deformation of super capacitors, etc., and achieve high cost performance, high energy density and power. The effect of density, wide operating voltage

Pending Publication Date: 2022-03-29
HANGZHOU DIANZI UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At the same time, it solves the problem that the voltage window of the integrated supercapacitor is too small and the supercapacitor assembled by the lamination method is easy to deform.

Method used

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  • Preparation method of integrated asymmetric supercapacitor

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Effect test

specific Embodiment approach 1

[0035] Dissolve 1g of polyvinyl alcohol PVA into 10mL of 1mol / L potassium chloride solution, and stir at 95°C for 2 hours, the solution becomes clear and transparent. Add 4g of N-hydroxyethylacrylamide HEAA and 0.078g of photocuring agent Irgacure 2959 into the above solution, and stir until completely dissolved. Dissolve 0.1 g of sodium alginate SA into the above solution at room temperature. The resulting solution was transferred to a mold, and then irradiated with an ultraviolet lamp for 1 hour to obtain a PVA-PHEAA-SA hydrogel electrolyte.

[0036] 0.715 mL of 5 mg / ml graphene oxide GO solution and 0.275 mL of pyrrole Py were added to 10 mL of 0.5 mol / L sulfuric acid solution, and dissolved by ultrasound for 30 minutes. Cut the self-healing PVA-PHEAA-SA hydrogel into a cube with a length, width, and height of 2 cm, 2 cm, and 0.5 cm, put it into the obtained solution, and let it stand for 20 minutes. Dissolve 0.912g of ammonium persulfate into 10mL of 0.5mol / L sulfuric ac...

specific Embodiment approach 2

[0040] Dissolve 1g of polyvinyl alcohol PVA into 10mL of 1mol / L potassium chloride solution, and stir at 95°C for 2 hours, the solution becomes clear and transparent. Add 5g of N-hydroxyethylacrylamide HEAA and 0.097g of photocuring agent Irgacure 2959 into the above solution, and stir until completely dissolved. Dissolve 0.2 g of sodium alginate SA into the above solution at room temperature. The resulting solution was transferred to a mold, and then irradiated with an ultraviolet lamp for 2 hours to obtain a PVA-PHEAA-SA hydrogel electrolyte.

[0041] Add 1.25 mL of 5 mg / ml graphene oxide GO solution and 0.275 mL of pyrrole Py into 10 mL of 0.5 mol / L sulfuric acid solution, and dissolve for 30 minutes using ultrasound. Cut the self-healing PVA-PHEAA-SA hydrogel into a cube with a length, width, and height of 6 cm, 6 cm, and 0.5 cm, put it into the obtained solution, and let it stand for 20 minutes. Dissolve 0.912g of ammonium persulfate into 10mL of 0.5mol / L sulfuric acid ...

specific Embodiment approach 3

[0045] Dissolve 1g of polyvinyl alcohol PVA into 10mL of 1mol / L potassium chloride solution, and stir at 95°C for 2 hours, the solution becomes clear and transparent. Add 8g of N-hydroxyethylacrylamide HEAA and 0.156g of photocuring agent Irgacure 2959 into the above solution, and stir until completely dissolved. Dissolve 0.5 g of sodium alginate SA into the above solution at room temperature. The resulting solution was transferred to a mold, and then irradiated with an ultraviolet lamp for 3 hours to obtain a PVA-PHEAA-SA hydrogel electrolyte.

[0046] Add 2.5 mL of 5 mg / ml graphene oxide GO solution and 0.275 mL of pyrrole Py into 10 mL of 0.5 mol / L sulfuric acid solution, and dissolve for 30 minutes using ultrasound. Cut the self-healing PVA-PHEAA-SA hydrogel into a cube with a length, width, and height of 10 cm, 10 cm, and 0.5 cm, put it into the obtained solution, and let it stand for 20 minutes. Dissolve 0.912g of ammonium persulfate into 10mL of 0.5mol / L sulfuric acid...

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Abstract

The invention discloses a preparation method of an integrated asymmetric supercapacitor, and the method comprises the steps: enabling two integrated supercapacitors with different electrode materials to be cut apart along an electrolyte through the self-healing performance of the electrolyte, and enabling the two supercapacitors with different electrode materials to be connected through the self-healing performance of the electrolyte, and a new asymmetric supercapacitor can be assembled. And meanwhile, the problems that the voltage window of the integrally prepared supercapacitor is small and the supercapacitor assembled by a lamination method is easy to deform are solved. The method has the advantages of simplicity, high efficiency and high cost performance. The material prepared by the method has the characteristics of wider working voltage, higher energy density and power density, foldability, self-healing and the like.

Description

technical field [0001] The invention belongs to the field of supercapacitor new material energy storage, and in particular relates to a preparation method of a flexible integrated asymmetric capacitor. Background technique [0002] In recent years, stretchable and healable electronics have attracted much attention due to their excellent flexibility, high reliability, and stable resistance to deformation. In order to better meet the functional requirements of the above-mentioned electronic devices, it is an urgent need for researchers to develop corresponding energy storage devices with stretchable and repairable properties. Currently, self-healing flexible supercapacitors have been widely studied due to their long-cycle stability, fast charge-discharge, high power density, and self-recovery ability after continuous mechanical deformation or physical damage. [0003] Conventional flexible supercapacitors usually have a layered multilayer structure consisting of a polymer ele...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01G11/86H01G11/56
CPCH01G11/86H01G11/56
Inventor 辛青花凯浩周前林君臧月
Owner HANGZHOU DIANZI UNIV
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