Preparation method of integrated asymmetric supercapacitor
A supercapacitor, asymmetric technology, used in the manufacture of hybrid/electric double layer capacitors, hybrid capacitor electrolytes, etc., can solve the problems of small voltage window of supercapacitors, easy deformation of super capacitors, etc., and achieve high cost performance, high energy density and power. The effect of density, wide operating voltage
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specific Embodiment approach 1
[0035] Dissolve 1g of polyvinyl alcohol PVA into 10mL of 1mol / L potassium chloride solution, and stir at 95°C for 2 hours, the solution becomes clear and transparent. Add 4g of N-hydroxyethylacrylamide HEAA and 0.078g of photocuring agent Irgacure 2959 into the above solution, and stir until completely dissolved. Dissolve 0.1 g of sodium alginate SA into the above solution at room temperature. The resulting solution was transferred to a mold, and then irradiated with an ultraviolet lamp for 1 hour to obtain a PVA-PHEAA-SA hydrogel electrolyte.
[0036] 0.715 mL of 5 mg / ml graphene oxide GO solution and 0.275 mL of pyrrole Py were added to 10 mL of 0.5 mol / L sulfuric acid solution, and dissolved by ultrasound for 30 minutes. Cut the self-healing PVA-PHEAA-SA hydrogel into a cube with a length, width, and height of 2 cm, 2 cm, and 0.5 cm, put it into the obtained solution, and let it stand for 20 minutes. Dissolve 0.912g of ammonium persulfate into 10mL of 0.5mol / L sulfuric ac...
specific Embodiment approach 2
[0040] Dissolve 1g of polyvinyl alcohol PVA into 10mL of 1mol / L potassium chloride solution, and stir at 95°C for 2 hours, the solution becomes clear and transparent. Add 5g of N-hydroxyethylacrylamide HEAA and 0.097g of photocuring agent Irgacure 2959 into the above solution, and stir until completely dissolved. Dissolve 0.2 g of sodium alginate SA into the above solution at room temperature. The resulting solution was transferred to a mold, and then irradiated with an ultraviolet lamp for 2 hours to obtain a PVA-PHEAA-SA hydrogel electrolyte.
[0041] Add 1.25 mL of 5 mg / ml graphene oxide GO solution and 0.275 mL of pyrrole Py into 10 mL of 0.5 mol / L sulfuric acid solution, and dissolve for 30 minutes using ultrasound. Cut the self-healing PVA-PHEAA-SA hydrogel into a cube with a length, width, and height of 6 cm, 6 cm, and 0.5 cm, put it into the obtained solution, and let it stand for 20 minutes. Dissolve 0.912g of ammonium persulfate into 10mL of 0.5mol / L sulfuric acid ...
specific Embodiment approach 3
[0045] Dissolve 1g of polyvinyl alcohol PVA into 10mL of 1mol / L potassium chloride solution, and stir at 95°C for 2 hours, the solution becomes clear and transparent. Add 8g of N-hydroxyethylacrylamide HEAA and 0.156g of photocuring agent Irgacure 2959 into the above solution, and stir until completely dissolved. Dissolve 0.5 g of sodium alginate SA into the above solution at room temperature. The resulting solution was transferred to a mold, and then irradiated with an ultraviolet lamp for 3 hours to obtain a PVA-PHEAA-SA hydrogel electrolyte.
[0046] Add 2.5 mL of 5 mg / ml graphene oxide GO solution and 0.275 mL of pyrrole Py into 10 mL of 0.5 mol / L sulfuric acid solution, and dissolve for 30 minutes using ultrasound. Cut the self-healing PVA-PHEAA-SA hydrogel into a cube with a length, width, and height of 10 cm, 10 cm, and 0.5 cm, put it into the obtained solution, and let it stand for 20 minutes. Dissolve 0.912g of ammonium persulfate into 10mL of 0.5mol / L sulfuric acid...
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